Molecular Vanadium Oxides for Energy Conversion and Energy Storage: Current Trends and Emerging Opportunities,Angewandte Chemie International Edition

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Molecular Vanadium Oxides for Energy Conversion and Energy Storage: Current Trends and Emerging Opportunities
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2020-09-03 , DOI: 10.1002/anie.202010577
Montaha Anjass _{1,

2} , Grace A Lowe ₁ , Carsten Streb _{1,

2}

Affiliation

Molecular vanadium oxides, or polyoxovanadates (POVs), have recently emerged as a new class of molecular energy conversion/storage materials, which combine diverse, chemically tunable redox behavior and reversible multielectron storage capabilities. This Review explores current challenges, major breakthroughs, and future opportunities in the use of POVs for energy conversion and storage. The reactivity, advantages, and limitations of POVs are explored, with a focus on their use in lithium and post‐lithium‐ion batteries, redox‐flow batteries, and light‐driven energy conversion. Finally, emerging themes and new research directions are critically assessed to provide inspiration for how this promising materials class can advance research in sustainable energy technologies.

中文翻译：

用于能量转换和能量存储的分子钒氧化物：当前趋势和新兴机遇

分子钒氧化物或多氧钒酸盐（POV）最近作为一类新型分子能量转换/存储材料出现，它结合了多种化学可调的氧化还原行为和可逆多电子存储能力。本综述探讨了使用 POV 进行能量转换和存储的当前挑战、重大突破和未来机遇。探讨了 POV 的反应性、优点和局限性，重点是它们在锂和后锂离子电池、氧化还原液流电池和光驱动能量转换中的应用。最后，对新兴主题和新研究方向进行严格评估，为这一有前途的材料类别如何推进可持续能源技术的研究提供灵感。

更新日期：2020-09-03

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