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Organic 2,5-dihydroxy-1,4-benzoquinone potassium salt with ultrahigh initial coulombic efficiency for potassium-ion batteries.
Chemical Communications ( IF 4.3 ) Pub Date : 2020-08-31 , DOI: 10.1039/d0cc05248e
Qijiu Deng 1 , Congcong Tian 1 , Zongbin Luo 1 , Yangyang Zhou 1 , Bo Gou 1 , Haixuan Liu 1 , Yingchun Ding 2 , Rong Yang 3
Affiliation  

Here, we propose a new organic 2,5-dihydroxy-1,4-benzoquinone potassium salt (K2C6H2O4) endowing an ultrahigh initial coulombic efficiency of 96% as an advanced anode for potassium-ion batteries. Theoretical calculations and experimental results suggest that K+ can reversibly insert into this organic compound due to the flexible and stable structure of the K2C6H2O4 molecule as well as fast K+ kinetics in the selected dimethyl ether-based electrolyte.

中文翻译:

具有超高初始库仑效率的有机2,5-二羟基-1,4-苯醌钾盐,用于钾离子电池。

在这里,我们提出了一种新型的有机2,5-二羟基-1,4-苯醌钾盐(K 2 C 6 H 2 O 4),具有96%的超高初始库仑效率,可作为钾离子电池的高级阳极。理论计算和实验结果表明,由于K 2 C 6 H 2 O 4分子的柔性和稳定结构以及所选二甲醚基电解质中的快速K +动力学,K +可以可逆地插入该有机化合物。
更新日期:2020-10-13
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