A series of new hybrid iodometallates [H₄Spiro-4-py]_n[Cu₇I₁₀]_n(I₃⁻)_n·0.5(I₂)_n·nH₂O (1), [Cu₂I₂(Spiro-3-py)]_n·0.75n(DMF)·0.25nH₂O (2), [H₂Spiro-4-py][H₃Spiro-4-py][Ag₁₀I₂₀]_0.5·H₂O (3) and [H₂Spiro-4-py]_n[H₃Spiro-4-py]_n[Ag₈I₁₃]_n·2.5H₂O (4) were hydrothermal synthesized. 1 contains 1-D chain [Cu₇I₁₀]_n based on new [Cu₇I₁₂] cluster, free I₃⁻ anions and I₂ molecules, which are interconnected by weak I⋯I interactions to generate a novel polyiodide {[Cu₇I₁₀](I₃⁻)·(I₂)}_n framework. 2 features a neutral sql layer [Cu₂I₂(Spiro-3-py)]_n constructed by the interconnection of the {Cu₂I₂} dimers and Spiro-3-py ligands. The anionic [Ag₁₀I₂₀]¹⁰⁻ framework of 3 can be described as an aggregation of two tetrameric [Ag₄I₈] clusters and one dimeric [Ag₂I₆] unit via sharing corner. The 1-D anionic chain [Ag₈I₁₃⁵⁻]_n of 4 is built up from the alternate connection of tetrameric [Ag₄I₈] units and rare larger [Ag₁₂I₂₀] clusters, which offers the only example of 1-D iodoargentates based on two types of iodoargentate clusters. The optical and photoelectronic properties of all compounds were also investigated.

一系列的新的混合iodometallates [H ₄螺-4-吡啶] _Ñ [铜₇我₁₀ ] _Ñ（I ₃ ^- ）_ñ ·0.5（I ₂）_ñ ·nH的₂ O（1），[铜₂我₂（ Spiro-3-py）] _n ·0.75n（DMF）·0.25nH ₂ O（2），[H ₂ Spiro-4-py] [H ₃ Spiro-4-py] [Ag ₁₀ I ₂₀ ] _0.5 ·H ₂ O（3）和[H ₂ Spiro-4-py]水热合成_n [H ₃ Spiro-4-py] _n [Ag ₈ I ₁₃ ] _n ·2.5H ₂ O（4）。1包含1-d链[铜₇我₁₀ ] _Ñ基于新的[铜₇我₁₂ ]簇，自由我₃ ^-阴离子和余_2点的分子，其通过弱我⋯我相互作用互连以生成一个新的多碘{[铜₇我₁₀ ]（I ₃ ^-）·（I ₂）} _ñ框架。2具有一个中性的sql层[Cu ₂ I ₂（Spiro-3-py）] _n，该层由{Cu ₂ I ₂ }二聚体和Spiro-3-py配体相互连接构成。阴离子将[Ag ₁₀余₂₀ ] ^10-的框架3可以被描述为两个四聚体的聚集将[Ag ₄我₈ ]簇和一个二聚体将[Ag ₂我₆ ]单元经由共用拐角。1-D阴离子链[Ag ₈ I ₁₃ ⁵⁻ ] _n of 4它是由四聚体[Ag ₄ I ₈ ]单元和稀有的较大[Ag ₁₂ I ₂₀ ]簇的交替连接构建而成的，这提供了基于两种类型的碘代文石簇的1-D碘代文石的唯一例子。还研究了所有化合物的光学和光电性能。