Materials Today Energy ( IF 9.0 ) Pub Date : 2020-08-19 , DOI: 10.1016/j.mtener.2020.100502 Jihun Kang , Jinwook Min , Sun-I. Kim , Sung-Wook Kim , Ji-Hyun Jang
Capacitive deionization (CDI) has attracted immense attention in recent years due to its simple energy efficient and eco-friendly desalination process. In capacitive deionization research, limited scale of fabrication for active materials and improving desalination efficiency have been the major challenges. Herein, micro-meso-macroporous three-dimensional graphene (MMM-3DG) with a high surface area (1492.8 m2 g−1) was fabricated in gram-scale production (>1.0 g per one time) as an effective active material for CDI. MMM-3DG exhibited a high electrosorption capacity (9.37 mg g−1) and a fast electrosorption rate (2.79 mg g−1 min−1). Furthermore, MMM-3DG delivered an outstanding rate constant value of 0.071 by a pseudo-second-order kinetic model, and thus low energy consumption value per desalinating ion (33.17 kJ mol−1) during the adsorption process.
中文翻译:
三级微介孔宏三维石墨烯,用于快速电容去离子
电容去离子(CDI)近年来因其简单的节能和环保脱盐工艺而备受关注。在电容去离子研究中,活性材料的有限制造规模和提高脱盐效率已成为主要挑战。在此,以克级生产(每一次> 1.0 g)的方式制造了具有高表面积(1492.8 m 2 g -1)的微介孔三维石墨烯(MMM-3DG )作为有效的活性材料。 CDI。MMM-3DG表现出高电吸附容量(9.37 mg g -1)和快速电吸附速率(2.79 mg g -1 min -1)。此外,MMM-3DG通过拟二阶动力学模型提供了出色的速率常数0.071,因此在吸附过程中每个脱盐离子的能量消耗值较低(33.17 kJ mol -1)。