Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy ( IF 4.3 ) Pub Date : 2020-08-05 , DOI: 10.1016/j.saa.2020.118799
Yufeng Hu 1 , Fei Zhou 1 , Xiuying Tian 1 , Changyan Ji 1 , Zhi Huang 2 , Jin Wen 1 , Fei Luo 1 , Zhanjun Chen 1 , Xin Liu 1 , Yangxi Peng 1
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CaSnO3: Pr3+ phosphor for new application in temperature sensing was investigated. CaSnO3: 0.3%Pr3+ had distorted orthorhombic perovskite structure and Pr3+ occupied Ca2+ sites due to their similar ionic radii. CaSnO3: 0.3%Pr3+ had spherical particles with mean size of 0.816 μm. The electric dipole−dipole interaction could explain the concentration quenching mechanism. The chromaticity coordinates were (0.1324, 0.3847), located in greenish-blue region and the average afterglow decay time was 60.2 s for CaSnO3: 0.15%Pr3+, which had potential applications for LED and emergency lighting. CaSnO3: 0.3%Pr3+ had the activated energy of 0.380 eV. The maximum relative temperature sensitivity for CaSnO3: 0.3%Pr3+ was 7.57% K−1 at 298 K and relative sensitivity was as high as 6722.76/T2 K−1, which was better than that of most Pr3+ doped phosphors and had potential application in temperature sensing. Moreover, the possible luminescence and long afterglow mechanisms and thermal quenching process of 3P0 level through IVCT state were proposed.
中文翻译:

CaSnO3:Pr3 +荧光粉,用于温度传感的新应用。
研究了CaSnO 3:Pr 3+荧光粉在温度传感领域的新应用。CaSnO 3:0.3%Pr 3+具有畸变的正交晶钙钛矿结构,并且由于其相似的离子半径,Pr 3+占据了Ca 2+位点。CaSnO 3:0.3%Pr 3+具有球形颗粒,平均尺寸为0.816μm。电偶极-偶极相互作用可以解释浓度猝灭机理。色度坐标是(0.1324,0.3847),位于蓝绿色区域和平均余辉衰变时间为60.2 S代表CASNO 3:0.15%的Pr 3+,在LED和应急照明方面有潜在的应用。CaSnO 3:0.3%Pr 3+的活化能为0.380 eV。CaSnO 3:0.3%Pr 3+的最大相对温度灵敏度在298 K时为7.57%K -1,相对灵敏度高达6722.76 / T 2 K -1,比大多数掺Pr 3+的荧光粉更好并在温度感测方面有潜在的应用。此外,提出了通过IVCT状态可能的发光和长余辉机理以及3 P 0能级的热猝灭过程。