Active Materials for Aqueous Zinc Ion Batteries: Synthesis, Crystal Structure, Morphology, and Electrochemistry.,Chemical Reviews

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Active Materials for Aqueous Zinc Ion Batteries: Synthesis, Crystal Structure, Morphology, and Electrochemistry.
Chemical Reviews ( IF 51.4 ) Pub Date : 2020-07-27 , DOI: 10.1021/acs.chemrev.9b00628
Xiaoxiao Jia ₁ , Chaofeng Liu ₁ , Zachary G Neale ₁ , Jihui Yang ₁ , Guozhong Cao ₁

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Aqueous zinc ion batteries (ZIBs) are truly promising contenders for the future large-scale electrical energy storage applications due to their cost-effectiveness, environmental friendliness, intrinsic safety, and competitive gravimetric energy density. In light of this, massive research efforts have been devoted to the design and development of high-performance aqueous ZIBs; however, there are still obstacles to overcome before realizing their full potentials. Here, the current advances, existing limitations, along with the possible solutions in the pursuit of cathode materials with high voltage, fast kinetics, and long cycling stability are comprehensively covered and evaluated, together with an analysis of their structures, electrochemical performance, and zinc ion storage mechanisms. Key issues and research directions related to the design of highly reversible zinc anodes, the exploration of electrolytes satisfying both low cost and good performance, as well as the selection of compatible current collectors are also discussed, to guide the future design of aqueous ZIBs with a combination of high gravimetric energy density, good reversibility, and a long cycle life.

中文翻译：

水性锌离子电池的活性材料：合成，晶体结构，形态和电化学。

水性锌离子电池（ZIBs）由于其成本效益，环境友好性，本质安全性和极具竞争力的重量能量密度，是未来大规模电能存储应用的真正有希望的竞争者。有鉴于此，已经对高性能水性ZIBs的设计和开发进行了大量研究工作。但是，在发挥其全部潜力之前，仍然有许多障碍需要克服。在此，对电流的发展，现有的局限性以及追求高电压，快速动力学和长循环稳定性的阴极材料的可能解决方案进行了全面的涵盖和评估，并对其结构，电化学性能和锌进行了分析。离子存储机制。

更新日期：2020-08-12

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