Ferrocene, the crown of metallocene family, is widely studied as a functional unit in electrochemical and catalytic applications due to its sandwich structure. Ferrocene moieties can be embedded into the polymer backbone, leading to main-chain ferrocenecontaining polymers. These polymeric materials combine the unique functionalities of iron center with the processabilities of polymers. As one of the choice polymerization techniques, acyclic diene metathesis (ADMET) polymerization serves as a versatile method to prepare main-chain ferrocene-containing polymers under mild conditions using α,ω-dienes as monomers. This paper overviews main-chain ferrocene-containing polymers prepared by ADMET polymerization. Advances in the design, synthesis and applications of this class of organometallic monomers and polymers are detailed.

二茂铁是茂金属家族的王冠，由于其夹心结构而被广泛用作电化学和催化应用中的功能单元。二茂铁部分可以嵌入聚合物主链中，从而形成含主链二茂铁的聚合物。这些聚合材料将铁心的独特功能与聚合物的可加工性结合在一起。作为一种选择的聚合技术，无环二烯复分解（ADMET）聚合可作为一种通用方法，在温和条件下使用α，ω-二烯作为单体制备含主链二茂铁的聚合物。本文概述了通过ADMET聚合制备的含主链二茂铁的聚合物。详细介绍了这类有机金属单体和聚合物在设计，合成和应用方面的进展。