Journal of Solid State Chemistry ( IF 3.2 ) Pub Date : 2020-07-11 , DOI: 10.1016/j.jssc.2020.121569 Wenhui Shi , Jianshe Lian
The NiCo hydroxides nanosheets (NiCo–OH) decorated Cu(OH)2 nanotubes structure was fabricated via a facile solution-immersion and later solvothermal method. The internal 1D Cu(OH)2 nanotubes directly grown on current collector without binder using enhance conductivity, accelerating electron transport. The outer 2D NiCo–OH nanosheets provide large surface areas and considerable active sites, promoting the electrode/electrolyte contact. Beneficial from significant electrochemical synergy in conductivity and open structure, the Cu(OH)2@NiCo–OH exhibits an impressive capacity of 1.12 mAh cm−2 at 3 mA cm−2, and remarkable rate capability (71% capacity retention at 30 mA cm−2). When assembled Ni–Zn battery with Cu(OH)2@NiCo–OH as cathode and Zn plate as anode, the Cu(OH)2@NiCo–OH//Zn battery displays high energy density and power density (1.53 mWh cm−2, 31.6 mW cm−2). Therefore, the Cu(OH)2@NiCo–OH//Zn battery presents a tremendous charm in new-type energy-storage devices.
中文翻译:
蓬松相交的NiCo-OH纳米片在Cu泡沫上装饰的中空Cu(OH)2纳米管阵列,用于高性能Ni-Zn电池
NiCo氢氧化物纳米片(NiCo-OH)装饰的Cu(OH)2纳米管结构是通过方便的溶液浸没和随后的溶剂热法制备的。内部一维Cu(OH)2纳米管可在不使用粘合剂的情况下直接在集电器上生长,从而提高电导率,加速电子传输。外部2D NiCo-OH纳米片提供较大的表面积和大量的活性位,从而促进电极/电解质的接触。Cu(OH)2 @ NiCo-OH在电导率和开放结构方面具有明显的电化学协同作用,在3 mA cm -2时表现出1.12 mAh cm -2的令人印象深刻的容量,并且具有显着的倍率能力(71%的容量保持率30 cm厘米−2)。当组装以Cu(OH)2 @ NiCo-OH为阴极和Zn板为阳极的Ni-Zn电池时,Cu(OH)2 @ NiCo-OH // Zn电池显示出高能量密度和功率密度(1.53 mWh cm -2,31.6毫瓦厘米-2)。因此,Cu(OH)2 @ NiCo-OH // Zn电池在新型储能装置中具有巨大的魅力。