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Isolated Surface Hydrides: Formation, Structure, and Reactivity
Chemical Reviews ( IF 51.4 ) Pub Date : 2016-07-11 00:00:00 , DOI: 10.1021/acs.chemrev.6b00082
Christophe Copéret 1 , Deven P. Estes 1 , Kim Larmier 1 , Keith Searles 1
Chemical Reviews ( IF 51.4 ) Pub Date : 2016-07-11 00:00:00 , DOI: 10.1021/acs.chemrev.6b00082
Christophe Copéret 1 , Deven P. Estes 1 , Kim Larmier 1 , Keith Searles 1
Affiliation
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Surface hydrides are ubiquitous in catalysis. However, their structures and properties are not as well-understood as those of their molecular counterparts, which have been extensively studied for the past 70 years. Hydrides isolated on surfaces have been characterized as stable entities on oxide surfaces or in zeolites. They have also been proposed as reaction intermediates in numerous catalytic processes (hydrogenation, hydrogenolysis, etc.). They have also been prepared via surface organometallic chemistry. In this review, we describe their key structural features and spectroscopic signatures. We discuss their reactivity and stability and also point out unexplored areas.
中文翻译：
孤立的表面氢化物：形成，结构和反应性
表面氢化物在催化中无处不在。但是，它们的结构和性质不如过去70年来被广泛研究的分子类似物更好地理解。表面上分离出的氢化物已被表征为氧化物表面或沸石中的稳定实体。还已经提出它们在许多催化过程（氢化，氢解等）中作为反应中间体。它们也已经通过表面有机金属化学制备。在这篇综述中，我们描述了它们的关键结构特征和光谱特征。我们讨论了它们的反应性和稳定性，并指出了未探索的领域。
更新日期：2016-07-11
中文翻译：
孤立的表面氢化物：形成，结构和反应性
表面氢化物在催化中无处不在。但是，它们的结构和性质不如过去70年来被广泛研究的分子类似物更好地理解。表面上分离出的氢化物已被表征为氧化物表面或沸石中的稳定实体。还已经提出它们在许多催化过程（氢化，氢解等）中作为反应中间体。它们也已经通过表面有机金属化学制备。在这篇综述中，我们描述了它们的关键结构特征和光谱特征。我们讨论了它们的反应性和稳定性，并指出了未探索的领域。
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