MOE Laboratory of Bioinorganic and Synthetic ChemistryLehn Institute of Functional Materials, School of ChemistrySun Yat-Sen University Guangzhou 510275 China
Institut Charles Gerhardt Montpellier UMR 5253 CNRSUniversité de Montpellier Place E. Bataillon 34095 Montpellier Cedex 05 France
State Key Laboratory of Applied Organic ChemistryLanzhou University Lanzhou 730000 China
Cover Feature: Dynamic Coordination Chemistry of Fluorinated Zr‐MOFs: Synthetic Control and Reassembly/Disassembly Beyond de Novo Synthesis to Tune the Structure and Property (Chem. Eur. J. 37/2020)
Zr4+ metal‐organic frameworks (Zr‐MOFs) , known for excellent stability and functionality, meet the synthetic challenge in tuning the strength of a Zr−Ocarboxylate linkage. This work explores the unusual coordination dynamics of a family of fluorinated Zr‐MOFs. The low‐connecting kinetic Zr‐MOFs possess dynamic behavior, thus opening a post‐synthetic pathway to sequential reassembly/disassembly. The factors, such as ligand geometry, etc., have been studied. Their stability, hydrophobicity and gas adsorption/separation properties are explored. More information can be found in the Full Paper by Z.‐W. Wei, G. Maurin, C.‐Y. Su, et al. on page 8254.
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