当前位置: X-MOL 学术Inorg. Chem. Commun. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Synthesis of Pd nanoparticles supported on molecular porous materials by using polyoxovanadate-based metal organic polyhedra as reducing agent
Inorganic Chemistry Communications ( IF 4.4 ) Pub Date : 2020-08-01 , DOI: 10.1016/j.inoche.2020.108028
Jie Zhou , Zhuxiu Zhang , Jihai Tang , Xu Qiao

Abstract Thermal treatment of the mechanical mixture of VMOP-12 and PdCl2 enabled the reduction of PdII to Pd0 nanoparticles via VMOP-12 without any external reducing agents. The resulting Pd0/VMOP-12 exhibited permanent porosities and well-dispersed Pd nanoparticles with average diameter of 10 nm. The improved catalytic activity of Pd0/VMOP-12 over palladium black were observed in the context of methanolysis of ammonia borane.

中文翻译:

以聚氧钒酸盐基金属有机多面体为还原剂合成负载在分子多孔材料上的钯纳米粒子

摘要 VMOP-12 和 PdCl2 的机械混合物的热处理能够通过 VMOP-12 将 PdII 还原为 Pd0 纳米粒子,而无需任何外部还原剂。所得的 Pd0/VMOP-12 表现出永久的孔隙率和分散良好的 Pd 纳米粒子,平均直径为 10 nm。在氨硼烷甲醇分解的背景下,观察到 Pd0/VMOP-12 对钯黑的催化活性提高。
更新日期:2020-08-01
down
wechat
bug