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A multifunctional self-crosslinked chitosan/cationic guar gum composite hydrogel and its versatile uses in phosphate-containing water treatment and energy storage.
Carbohydrate Polymers ( IF 10.7 ) Pub Date : 2020-05-29 , DOI: 10.1016/j.carbpol.2020.116472
Lei Dai 1 , Yan Wang 2 , Zixiu Li 2 , Xiaowan Wang 2 , Chao Duan 2 , Wei Zhao 2 , Chuanyin Xiong 2 , Shuangxi Nie 3 , Yongjian Xu 2 , Yonghao Ni 4
Affiliation  

A new self-crosslinked composite hydrogel is prepared with chitosan (CS) and cationic guar gum (CGG), based on the imine and acetal chemistry for gelation. The CS/CGG hydrogel exhibits thermal/pH responsiveness, injectability, adhesiveness and good compressive strength. The hydrogel is effective in removing phosphate from wastewater through an adsorption process, during which KH2PO4 is used as a phosphate model. The adsorption complies with the Freundlich model, indicating that it is a multilayered process with complex adsorption mechanisms. Considering their porous structure and nitrogen/phosphorus heteroatoms doping, the phosphate-adsorbed hydrogels are made into porous N,P doped carbon aerogels that can be potentially used as electrodes for a supercapacitor. The results indicate that these carbon aerogels possess excellent capacitive performance (best specific capacitance of 302.2 ± 4.9 F/g), as well as good cycling stability after 5000 times of charging/discharging.



中文翻译:

多功能自交联的壳聚糖/阳离子瓜尔胶复合水凝胶及其在含磷酸盐的水处理和能量存储中的多功能用途。

基于壳聚糖(CS)和阳离子瓜尔胶(CGG),基于亚胺和缩醛化学凝胶化,制备了一种新的自交联复合水凝胶。CS / CGG水凝胶具有热/ pH响应性,可注射性,粘合性和良好的抗压强度。水凝胶通过吸附过程有效去除废水中的磷酸盐,在此过程中,KH 2 PO 4用作磷酸盐模型。吸附符合Freundlich模型,表明它是具有复杂吸附机制的多层过程。考虑到它们的多孔结构和氮/磷杂原子的掺杂,磷酸盐吸附的水凝胶被制成多孔的N,P掺杂的碳气凝胶,可以潜在地用作超级电容器的电极。结果表明,这些碳气凝胶具有出色的电容性能(最佳比电容为302.2±4.9 F / g),并且经过5000次充放电后具有良好的循环稳定性。

更新日期:2020-05-29
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