No Making Without Breaking: Nitrogen-Centered Carbonylation Reactions,ACS Catalysis

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No Making Without Breaking: Nitrogen-Centered Carbonylation Reactions
ACS Catalysis ( IF 11.3 ) Pub Date : 2020-05-13 , DOI: 10.1021/acscatal.0c01479
Zhiping Yin ₁ , Jian-Xing Xu ₂ , Xiao-Feng Wu _{2,

3}

Affiliation

Carbonylation, an efficient and straightforward approach for installing a carbonyl group into their parent compounds, is an important area in modern organic synthesis. This Review outlines the recent advances in the development of nitrogen-centered carbonylation reactions, which consists of two parts: nitrogen-center-directed carbonylation reactions and carbonylative C–N bonds activation. According to the reaction mechanisms, two-electron- and single-electron-mediated carbonylation reactions were systematically classified and discussed in detail. Different inert bonds such as C(sp²)–H, C(sp³)–H, C–C, C(sp³)–N, and C(sp²)–N bonds can be activated and ready for a carbonylative transformation toward the synthesis of the corresponding carbonyl-containing compounds.

中文翻译：

不间断的制造：以氮为中心的羰基化反应

羰基化是将羰基安装到其母体化合物中的一种有效而直接的方法，是现代有机合成中的重要领域。这篇综述概述了以氮为中心的羰基化反应发展的最新进展，该进展包括两部分：以氮为中心的羰基化反应和羰基化的C–N键活化。根据反应机理，系统地对两电子和单电子介导的羰基化反应进行了分类和详细讨论。不同的惰性键，例如C（sp ²）–H，C（sp ³）–H，CC–C，C（sp ³）–N和C（sp ²）–N键可以被激活，并准备进行羰基化转化，以合成相应的含羰基化合物。

更新日期：2020-05-13

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