Acylation of Aryl Halides and α-Bromo Acetates with Aldehydes Enabled by Nickel/TBADT Cocatalysis.,Organic Letters

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Acylation of Aryl Halides and α-Bromo Acetates with Aldehydes Enabled by Nickel/TBADT Cocatalysis.
Organic Letters ( IF 4.9 ) Pub Date : 2020-05-01 , DOI: 10.1021/acs.orglett.0c01121
Pei Fan ₁ , Chang Zhang ₁ , Linchuan Zhang ₁ , Chuan Wang _{1,

2}

Affiliation

In this protocol aryl halides and α-bromo acetates are efficiently cross-coupled with an array of (hetero)aromatic and aliphatic aldehydes under the cooperative catalysis of nickel and tetrabutylammonium decatungstate as a hydrogen-atom-transfer photocatalyst. This method provides a concise approach to a variety of ketones with high compatibility of various functional groups.

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