Two thiophene-derived copolymers containing pyrene groups were synthesized using FeCl₃ as oxidizing agent. The 3-methyl-4-(4-(pyren-1-yl)butoxy)thiophene/3-dodecylthiophene (PyT/3DT) molar ratio was varied: P(PyT1-co-3DT25) (1/25) and P(PyT1-co-3DT40) (1/40). The polymers were characterized by Fourier-transform infrared spectroscopy (FTIR), proton nuclear magnetic resonance (¹H NMR), gel permeation chromatography (GPC), thermogravimetric analysis (TGA), ultraviolet–visible spectroscopy (UV-Vis), electric conductivity, cyclic voltammetry, and photoluminescence analysis (PL). P(PyT1-co-3DT25) and P(PyT1-co-3DT40) exhibited good thermal stability with T₁₀ (10 wt% loss temperature) values at 428 and 415 °C, and T_g values of 62 and 64 °C, respectively. The incorporation of pyrene-labeled thiophene units in poly(3-dodecylthiophene) (P3DT) generated a new absorption band at a lower wavelength than the absorption band corresponding to P3DT. The thermal effect was studied in the transmittance spectra, and compared with their analog P3DT. The transmittance spectra of the polymers showed a temperature dependence. For P(PyT1-co-3DT25), with a temperature change of 55 °C (from 25 to 80 °C), the maximum displacement of the transmittance spectrum was around 95 nm. P(PyT1-co-3DT25) showed a polydispersity (M_w/M_n ) of 2.8, similar to P3DT.

以FeCl ₃为氧化剂合成了两种含containing基噻吩的共聚物。改变3-甲基-4-（4-（苯并-1-基）丁氧基）噻吩/ 3-十二烷基噻吩（PyT / 3DT）的摩尔比：P（PyT 1 -co-3DT 25）（1/25）和P（PyT 1 -co-3DT 40）（1/40）。通过傅立叶变换红外光谱（FTIR），质子核磁共振（¹ H NMR），凝胶渗透色谱（GPC），热重分析（TGA），紫外可见光谱（UV-Vis），电导率，循环伏安法和光致发光分析（PL）。P（PyT 1 -co-3DT 25）和P（PyT 1-co-3DT 40）表现出良好的热稳定性，分别在428和415°C时的T ₁₀（失重温度为10 wt％）值和62和64°C的T _g值。在聚（3-十二烷基噻吩）（P3DT）中掺入pyr标记的噻吩单元会在比对应于P3DT的吸收带低的波长处产生新的吸收带。在透射光谱中研究了热效应，并将其与模拟P3DT进行了比较。聚合物的透射光谱显示出温度依赖性。对于P（PyT 1 -co-3DT 25），温度变化为55°C（从25到80°C）时，透射光谱的最大位移约为95 nm。P（PyT 1-co-3DT 25）的多分散度（M _w / M _n）为2.8，类似于P3DT。