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11,11-Dimethyl-11H-indeno[1,2-b]indolo[1,2,3-jk]carbazole: A Rigid Chromophore with Novel Amalgamation Strategy for Long Lifetime Blue Fluorescent Organic Light-Emitting Diodes
Chemical Engineering Journal ( IF 13.3 ) Pub Date : 2020-04-18 , DOI: 10.1016/j.cej.2020.125125
Vilas Venunath Patil , Kyung Hyung Lee , Jun Yeob Lee

In this work, we report a novel chromophore, 11,11-dimethyl-11H-indeno[1,2-b]indolo[1,2,3-jk]carbazole (IDFL), developed from a indenocarbazole building block and a blue fluorescent emitter, 11,11-dimethyl-N2,N2,N8,N8-tetraphenyl-11H-indeno[1,2-b]indolo[1,2,3-lm]carbazole-2,8-diamine (IDFL-2DPA), derived from the IDFL by diphenylamine functionalization. The device fabricated using the IDFL-2DPA emitter offered blue emission with a very small full-width at half maximum of 32 nm in addition to high external quantum efficiency above 5% and 4 times longer lifetime than that of pyrene-based blue device. Therefore, the IDFL-2DPA emitter was appropriate as the pure blue emitter with high color purity, high efficiency, and long device lifetime.



中文翻译:

11,11-二甲基-11 H-茚并[1,2- b ]吲哚[1,2,3- jk ]咔唑:具有长寿命蓝色荧光有机发光二极管的新型合并策略的刚性发色团。

在这项工作中,我们报告一个新的发色团,11,11-二甲基-11- ħ -茚并[1,2- b ]吲哚并[1,2,3 JK ]咔唑(IDFL),从茚并构建块和一个显影蓝色荧光发射体,11,11-二甲基-N 2N 2N 8N 8-四苯基-11 H-茚并[ 1,2- b ]吲哚[1,2,3- lm ]咔唑-2,8二胺(IDFL-2DPA) ,从派生IDFL由二苯胺的官能化。使用IDFL-2DPA制造的设备发射器提供的蓝光发射非常小,最大半峰宽仅为32 nm,此外还具有高于5%的高外部量子效率和比基于blue的蓝光器件长4倍的寿命。因此,IDFL-2DPA发射器适合作为具有高色纯度,高效率和长使用寿命的纯蓝色发射器。

更新日期:2020-04-20
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