Carboxylation of Alkenyl Boronic Acids and Alkenyl Boronic Acid Pinacol Esters with CO2 Catalyzed by Cuprous Halide,European Journal of Organic Chemistry

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Carboxylation of Alkenyl Boronic Acids and Alkenyl Boronic Acid Pinacol Esters with CO2 Catalyzed by Cuprous Halide
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2020-04-16 , DOI: 10.1002/ejoc.202000288
Junting Hong ₁ , Onkar S. Nayal ₁ , Fanyang Mo _{1,

2}

Affiliation

Three kinds of alkenyl boron compounds were effectively transformed into the corresponding α, β‐unsaturated carboxylic acids in moderate to high yields through a cuprous halide catalyzed carboxylation with CO₂. The advantages of this method include low cost, mild conditions, simple operation, broad scope, and external ligand free.