Deep Eutectic Supramolecular Polymers: Bulk Supramolecular Materials.,Angewandte Chemie International Edition

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Deep Eutectic Supramolecular Polymers: Bulk Supramolecular Materials.
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2020-04-14 , DOI: 10.1002/anie.202004104
Shuanggen Wu ₁ , Changyong Cai ₂ , Fenfang Li ₂ , Zhijian Tan ₃ , Shengyi Dong ₁

Affiliation

Application of new strategies for supramolecular self‐assembly can significantly impact the properties and/or functions of supramolecular polymers. To realize a facial strategy for the development of solvent‐free supramolecular polymers in bulk, “deep eutectic solvents” were employed. Cyclodextrins and natural acids were used to prepare deep eutectic supramolecular polymers (DESP s). Deep eutectic solvents have special characteristics that endow DESP s with unique macroscopic properties and excellent processability. DESP s exhibit supramolecular adhesion and temperature‐dependent behavior originating from the combined effects of deep eutectic solvents and supramolecular polymerization. Because DESP s are solvent‐free and display interesting macroscopic properties, they have potential as new adaptive materials.

中文翻译：

深共晶超分子聚合物：块状超分子材料。

超分子自组装新策略的应用会极大地影响超分子聚合物的性能和/或功能。为了实现开发无溶剂超分子聚合物本体的面部策略，采用了“深共晶溶剂”。环糊精和天然酸用于制备深共晶超分子聚合物（DESP）。深度共晶溶剂具有特殊的特性，赋予DESP独特的宏观性能和出色的加工性能。DESP表现出超分子粘附和温度依赖性行为，这是由于深共晶溶剂和超分子聚合作用的共同作用所致。因为DESPs是无溶剂的，并显示出令人感兴趣的宏观特性，它们具有作为新型适应性材料的潜力。

更新日期：2020-04-14

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