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A planar binuclear cobalt(ii) phthalocyanine as a highly efficient catalyst for the oxidation of a mercaptan.
Chemical Communications ( IF 4.3 ) Pub Date : 2020-04-15 , DOI: 10.1039/d0cc01653e Sergey G Makarov 1 , Sergey Yu Ketkov 1 , Dieter Wöhrle 2
Chemical Communications ( IF 4.3 ) Pub Date : 2020-04-15 , DOI: 10.1039/d0cc01653e Sergey G Makarov 1 , Sergey Yu Ketkov 1 , Dieter Wöhrle 2
Affiliation
This paper reports on a binuclear Co(ii)Pc which exhibits a previously unknown extremely high catalytic activity for the oxidation of a thiol to the corresponding disulfide. The high activity is explained by an electronic contact between the two Co centres in the complex.
中文翻译:
平面双核钴(ii)酞菁,可作为硫醇氧化的高效催化剂。
本文报道了一种双核Co(ii)Pc,它对硫醇氧化为相应的二硫键具有前所未有的极高催化活性。活性高的原因是大楼中两个Co中心之间的电子接触。
更新日期:2020-04-15
中文翻译:
平面双核钴(ii)酞菁,可作为硫醇氧化的高效催化剂。
本文报道了一种双核Co(ii)Pc,它对硫醇氧化为相应的二硫键具有前所未有的极高催化活性。活性高的原因是大楼中两个Co中心之间的电子接触。