Metal-Organic Frameworks against Toxic Chemicals.,Chemical Reviews

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Metal-Organic Frameworks against Toxic Chemicals.
Chemical Reviews ( IF 51.4 ) Pub Date : 2020-03-24 , DOI: 10.1021/acs.chemrev.9b00828
Timur Islamoglu ₁ , Zhijie Chen ₁ , Megan C Wasson ₁ , Cassandra T Buru ₁ , Kent O Kirlikovali ₁ , Unjila Afrin ₁ , Mohammad Rasel Mian ₁ , Omar K Farha ₁

Affiliation

Materials capable of the safe and efficient capture or degradation of toxic chemicals, including chemical warfare agents (CWAs) and toxic industrial chemicals (TICs), are critically important in the modern age due to continuous threats of these chemicals to human life, both directly and indirectly. Metal–organic frameworks (MOFs), atomically precise hybrid materials that are synthesized via the self-assembly of metal cations or clusters and organic linkers, offer a unique solid adsorbent design platform due to their great synthetic versatility. This review will focus on recent advancements in MOF-based adsorbent design for protection against chemical warfare agents (organophosphorus nerve agents, blistering agents, and their simulants) and toxic industrial chemicals such as H₂S, NH₃, SO₂, CO, NO₂, and NO.

中文翻译：

针对有毒化学品的金属有机框架。

能够安全有效地捕获或降解有毒化学品的材料，包括化学战剂 (CWA) 和有毒工业化学品 (TIC)，由于这些化学品对人类生命的持续威胁，包括直接和间接地。金属有机骨架 (MOF) 是一种原子级精确的混合材料，通过金属阳离子或簇和有机连接体的自组装合成，由于其强大的合成多功能性，提供了独特的固体吸附剂设计平台。本综述将重点关注基于 MOF 的吸附剂设计的最新进展，以防止化学战剂（有机磷神经毒剂、起泡剂及其模拟物）和有毒工业化学品，如 H ₂ S、NH ₃、SO ₂、CO、NO ₂和NO。

更新日期：2020-03-24

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