Two-Dimensional MOF and COF Nanosheets: Synthesis and Applications in Electrochemistry.,Chemistry - A European Journal

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Two-Dimensional MOF and COF Nanosheets: Synthesis and Applications in Electrochemistry.
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2020-04-15 , DOI: 10.1002/chem.202000294
Ji Wang ₁ , Nan Li ₁ , Yuxia Xu ₂ , Huan Pang ₁

Affiliation

Metal-organic framework (MOF) and covalent organic framework (COF) nanosheets are a new type of two-dimensional (2D) materials with unique design principles and various synthesis methods. They are considered ideal electrochemical devices due to the ultrathin thickness, easily tunable molecular structure, large porosity and other unique properties. There are two common methods to synthesize 2D MOF/COF nanosheets: bottom-up and top-down. The top-down strategy mainly includes ultrasonic assisted exfoliation, electrochemical exfoliation and mechanical exfoliation. Another strategy mainly includes interface synthesis, modulation synthesis, surfactant-assisted synthesis. In this Review, the development of ultrathin 2D nanosheets in the field of electrochemistry (supercapacitors, batteries, oxygen reduction, and hydrogen evolution) is introduced, and their unique dimensional advantages are highlighted.

中文翻译：

二维MOF和COF纳米片：电化学的合成与应用。

金属有机骨架（MOF）和共价有机骨架（COF）纳米片是一种新型的二维（2D）材料，具有独特的设计原理和多种合成方法。由于其超薄的厚度，易于调节的分子结构，大孔隙率和其他独特的性能，它们被认为是理想的电化学装置。合成2D MOF / COF纳米片的常用方法有两种：自下而上和自上而下。自上而下的策略主要包括超声辅助剥离，电化学剥离和机械剥离。另一种策略主要包括界面合成，调制合成，表面活性剂辅助合成。在这篇综述中，介绍了电化学领域（超级电容器，电池，氧还原和析氢）中超薄二维纳米片的开发，

更新日期：2020-03-06

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