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Oxidation of N-aminoquinazolones in the presence of alkenes: evidence against involvement of N-nitrenes
Journal of the Chemical Society, Chemical Communications Pub Date : 1987 , DOI: 10.1039/c39870001362 Robert S. Atkinson , Brian J. Kelly
Journal of the Chemical Society, Chemical Communications Pub Date : 1987 , DOI: 10.1039/c39870001362 Robert S. Atkinson , Brian J. Kelly
Solutions of 2-ethyl-3-acetoxyamino-4(3H)-quinazolone (6) have been obtained by oxidation of the corresponding 3-aminoquinazolone (4) with lead tetra-acetate at –20 °C; (6) brings about aziridination of alkenes by a mechanism that does not involve N-nitrene or N-nitrenium ion intermediates.
中文翻译:
N-氨基喹唑酮在烯烃存在下的氧化:反对N-硝烯类化合物参与的证据
解2-乙基-3- acetoxyamino-4(3 ħ) -喹唑酮(6)具有由相应的3- aminoquinazolone(氧化而得到4)与铅四乙酸在-20℃下; (6)通过不涉及N-硝烯或N-硝鎓离子中间体的机理引起烯烃的叠氮化。
更新日期:2017-01-31
中文翻译:
N-氨基喹唑酮在烯烃存在下的氧化:反对N-硝烯类化合物参与的证据
解2-乙基-3- acetoxyamino-4(3 ħ) -喹唑酮(6)具有由相应的3- aminoquinazolone(氧化而得到4)与铅四乙酸在-20℃下; (6)通过不涉及N-硝烯或N-硝鎓离子中间体的机理引起烯烃的叠氮化。