The applications of poly(N,N′-dichloro-N-ethylbenzene-1,3-disulfonamide) (PCBS) and N,N,N′,N′-tetrachlorobenzene-1,3-disulfonamide (TCBDA) as novel reagents for the preparation of N,N-dichloroamines, nitriles, and aldehydes from primary amines under various conditions are described. Also, a simple and effective procedure for the direct oxidative conversion of primary alcohols into nitriles was successfully carried out with TCBDA and PCBS in aqueous ammonia.

TCBDA - PCBS - dichloroamines - nitriles - alcohols

中文翻译：

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聚（N，N'-二氯-N-乙基苯-1,3-二磺酰胺）和N，N，N'，N'-四氯苯-1,3-二磺酰胺为合成N-氯胺，腈和四氢呋喃的新型试剂醛类

聚N，N'-二氯-N-乙基苯-1,3-二磺酰胺（PCBS）和N，N，N '，N'-四氯苯-1,3-二磺酰胺（TCBDA）作为新型试剂的应用描述了在各种条件下由伯胺制备N，N-二氯胺，腈和醛的方法。同样，在氨水中使用TCBDA和PCBS成功地进行了简单有效的伯醇直接氧化转化为腈的程序。

TCBDA-PCBS-二氯胺-腈-醇