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Lanthanum borate synthesis via the solid-state method from a La 2 O 3 precursor: Electrical and optical properties
Materials Chemistry and Physics ( IF 4.3 ) Pub Date : 2017-10-01 , DOI: 10.1016/j.matchemphys.2017.07.056
Selda Sari , Fatma Tugce Senberber , Meral Yildirim , Azmi Seyhun Kipcak , Sureyya Aydin Yuksel , Emek Moroydor Derun

Abstract In this study, three different types of lanthanum borates, which have the structural formulas of La3BO6, LaBO3 and La(BO2)3, were synthesized, such as diphasic and triphasic, by using the lanthanum source of La2O3 and boron sources of both H3BO3 and B2O3 via a solid-state route. The effects of reactant molar ratio, reaction temperature, time and atmosphere on the production of lanthanum borates were studied. X-ray diffraction (XRD), Fourier transform infrared (FTIR) and Raman Spectroscopy techniques were applied to the synthesized minerals for characterization, and the scanning electron microscopy (SEM) technique was used for the determination of surface morphologies and particle sizes. In addition, the optical and electrical characteristics of synthesized lanthanum borates with the highest XRD scores were investigated.

中文翻译:

通过固态法从 La 2 O 3 前体合成硼酸镧:电学和光学特性

摘要 本研究利用 La2O3 的镧源和 H3BO3 的硼源,合成了双相和三相三种不同类型的硼酸镧,其结构式分别为 La3BO6、LaBO3 和 La(BO2)3。和 B2O3 通过固态途径。研究了反应物摩尔比、反应温度、反应时间和气氛对硼酸镧生产的影响。X 射线衍射 (XRD)、傅里叶变换红外 (FTIR) 和拉曼光谱技术应用于合成矿物进行表征,并使用扫描电子显微镜 (SEM) 技术测定表面形貌和粒度。此外,研究了具有最高 XRD 分数的合成硼酸镧的光学和电学特性。
更新日期:2017-10-01
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