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Preparation 2-(anthracen-9-yl)-1,3-dithiolane as a novel dual-channel AIE-active fluorescent probe for mercury (II) ion with excellent performance
Journal of Photochemistry and Photobiology A: Chemistry ( IF 4.1 ) Pub Date : 2019-04-21 , DOI: 10.1016/j.jphotochem.2019.04.019
Jie Ma , Cuihong Zhang , Yao Xiao , Manman Zhang , Qingyang Wang , Weiguo Zheng , Shuping Zhang

A novel fluorescent probe molecule, 2-(anthracen-9-yl)-1,3-dithiolane (AADT), is designed and synthesized for Hg2+ detection successfully, based on a good aggregation induced emission (AIE) fluorescent mechanism and a specific reaction type. DMF-H2O mixed solvent (Fw 80% V/V) is suitable to disperse AADT for forming 1 × 10−5 mol L−1 solution with an AIE-active fluorescence probe system. Meanwhile, 9-Anthraldehyde also presents good fluorescence at same condition. With the increase of trace Hg (II), the AADT probe shows dual-channel, (turn-off at 429 nm, and turn–on at 511 nm) fluorescence probe character. (R2 > 0.994), which does not interfere each other. The probe demonstrates excellent selectivity, anti-inference properties, and several metal ions and acid ions hardly affect its performance. The LOD of the AADT probe is lower than 2.34 × 10−8 mol L−1, and proper to many common AIE-active probes.



中文翻译:

制备2-(蒽-9-基)-1,3-二硫杂环戊烷作为具有优异性能的新型双通道AIE活性汞(II)离子荧光探针

基于良好的聚集诱导发射(AIE)荧光机理和良好的荧光光谱,设计并合成了新型的荧光探针分子2-(蒽-9-基)-1,3-二硫杂环戊烷(AADT),用于Hg 2+的成功检测。具体的反应类型。DMF-H 2 O混合溶剂(F w 80%V / V)适用于分散AADT,以使用AIE活性荧光探针系统形成1×10 -5 mol L -1溶液。同时,9-蒽在相同条件下也显示出良好的荧光。随着痕量汞(II)的增加,AADT探针显示出双通道荧光探针特性(在429 nm处关闭,在511 nm处开启)。(R 2 > 0.994),这不会互相干扰。该探针具有出色的选择性,抗干扰性,几种金属离子和酸性离子几乎不会影响其性能。AADT探针的LOD低于2.34×10 -8  mol L -1,适用于许多常见的AIE活性探针。

更新日期:2019-04-21
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