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Organic light-Emitting diode based on bis(10-phenylanthracen-9-yl)benzene derivatives with a stable white emission
Journal of Photochemistry and Photobiology A: Chemistry ( IF 4.1 ) Pub Date : 2015-05-28 , DOI: 10.1016/j.jphotochem.2015.05.027
Young Seok Kim , Jhin-yeong Yoon , Hyun Woo Lee , Jwajin Kim , Song Eun Lee , Ho Won Lee , Young Kwan Kim , Seung Soo Yoon

In this work, we used the Suzuki cross-coupling reaction to synthesize the following two emitting materials: 1,3-bis(10-phenylanthracen-9-yl)benzene (1) and 2,6-bis(10-phenylanthracen-9-yl)pyridine (2). To investigate the electroluminescent (EL) properties of these materials, multilayered organic light-emitting diodes (OLEDs) devices were fabricated in the following sequence: indium-tin-oxide (ITO) (180 nm)/4,4′-bis(N-(1-naphthyl)-N-phenylamino)biphenyl (NPB) (50 nm)/emitting materials (1 and 2) (40 nm)/tris(8-hydroxyquinolinato)aluminium (Alq3) (15 nm)/lithium quinolate (Liq) (2 nm)/Al (100 nm). Of special significance, a device using 1 as an emitting material showed a white emission with maximum luminance, luminous, power, and external quantum efficiency values of 1727 cd/m2, 1.74 cd/A, 0.78 lm/W, and 0.67% at 20 mA/cm2, respectively, as well as CIE coordinates of (0.31, 0.44) at 7 V. Another device using 2 exhibited a sky-blue emission with maximum luminance, luminous, power, and external quantum efficiency values of 2279 cd/m2, 1.95 cd/A, 0.97 lm/W, and 0.93% at 20 mA/cm2, respectively as well as CIE coordinates of (0.24, 0.29) at 7 V.



中文翻译:

基于双(10-苯基蒽-9-基)苯衍生物的有机发光二极管,具有稳定的白色发射

在这项工作中,我们使用Suzuki交叉偶联反应合成了以下两种发光材料:1,3-双(10-苯基蒽-9-基)苯(1)和2,6-双(10-苯基蒽蒽-9) -基)吡啶(2)。为了研究这些材料的电致发光(EL)特性,按以下顺序制造了多层有机发光二极管(OLED)器件:氧化铟锡(ITO)(180 nm)/ 4,4'-bis(N -(1-萘基)-N-苯基氨基)联苯(NPB)(50 nm)/发光材料(12)(40 nm)/(8-羟基喹啉基)铝(Alq 3)(15 nm)/喹啉锂(Liq)(2 nm)/ Al(100 nm)。具有特殊意义的,使用设备1作为发光材料表现出与最大亮度,发光,功率和1727烛光/米的外部量子效率的值的一种白光发射2,1.74坎德拉/ A,0.78流明/瓦,而在0.67%分别为20 mA / cm 2以及7 V时的CIE坐标为(0.31,0.44)。另一种使用2的设备显示出天蓝色发射,其最大亮度,发光,功率和外部量子效率值为2279 cd /米2,1.95坎德拉/ A,0.97流明/瓦,在20毫安/平方厘米0.93%2,分别以及的CIE坐标(0.24,0.29)在7V

更新日期:2015-05-28
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