Abstract The reaction of silver nitrate with (1e)-N′-hydroxy-2-(1H-1,2,4-triazol-1-yl) ethanimidamide (HTE) at room temperature affords a new 3D metal-organic frameworks, {[Ag3(HTE)2(NO3)2]·NO3}n (1). Single crystal X-ray diffraction analysis reveals that the three silver metal centers are bridged by two HTE ligands and Ag-Ag strong interactions in 1. The bridges provided through the nitrogen atoms on triazole-ring and the nitrogen atoms of the ethanimidamide resulted in a trinuclear units {Ag3(HTE)2} linked metal organic framework (MOF) structure. The MOF is displaying the trinuclear units that are connected via nitrates to give a 3D network. There are free nitrates incorporated in the channels of the MOF.

中文翻译：

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使用（1e）-N'-羟基-2-（1 H -1,2,4-三唑-1-基）乙酰亚胺和硝酸盐构建的新型三核Ag（I）-MOF作为潜在的含能材料

摘要 硝酸银与 (1e)-N'-hydroxy-2-(1H-1,2,4-triazol-1-yl) ethanimidamide (HTE) 在室温下的反应提供了一种新的 3D 金属有机骨架，{ [Ag3(HTE)2(NO3)2]·NO3}n (1)。单晶 X 射线衍射分析表明，三个银金属中心通过 1 中的两个 HTE 配体和 Ag-Ag 强相互作用桥接。通过三唑环上的氮原子和乙酰亚胺酰胺的氮原子提供的桥接导致三核单元 {Ag3(HTE)2} 连接的金属有机骨架 (MOF) 结构。MOF 正在显示通过硝酸盐连接以提供 3D 网络的三核单元。MOF 的通道中含有游离硝酸盐。