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Benzene-1,3,5-triyl triformate (TFBen): a convenient, efficient, and non-reacting CO source in carbonylation reactions
Tetrahedron Letters ( IF 1.5 ) Pub Date : 2016-06-17 , DOI: 10.1016/j.tetlet.2016.06.071 Li-Bing Jiang , Xinxin Qi , Xiao-Feng Wu
中文翻译:
1,2,3,5-三甲酸三苯酯(TFBen):羰基化反应中便捷,高效且不反应的CO源
更新日期:2016-06-17
Tetrahedron Letters ( IF 1.5 ) Pub Date : 2016-06-17 , DOI: 10.1016/j.tetlet.2016.06.071 Li-Bing Jiang , Xinxin Qi , Xiao-Feng Wu
Benzene-1,3,5-triyl triformate (TFBen) as a kind of convenient and efficient CO source has been prepared for the first time. The character of TFBen as potent and non-reacting CO source has been proven by the successful synthetic applications in carbonylation reactions. Phloroglucinol (1,3,5-trihydroxybenzene) is abundant and naturally occurring has been applied as the reusable material for TFBen synthesis.
中文翻译:
1,2,3,5-三甲酸三苯酯(TFBen):羰基化反应中便捷,高效且不反应的CO源
首次制备了1,3,5-三甲酸三苯甲酸乙酯(TFBen)作为一种便捷高效的CO源。通过在羰基化反应中成功的合成应用,已经证明了TFBen作为有效的非反应性CO源的特性。间苯三酚(1,3,5-三羟基苯)含量丰富,自然存在,已用作TFBen合成的可重复使用材料。