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SnO2 Quantum Dots@Graphene Framework as a High-Performance Flexible Anode Electrode for Lithium-Ion Batteries.
ACS Applied Materials & Interfaces ( IF 8.3 ) Pub Date : 2020-03-04 , DOI: 10.1021/acsami.9b22679
Li Gao 1 , Guisheng Wu 1 , Jian Ma 1 , Tiancai Jiang 2 , Bin Chang 1 , Yanshan Huang 1 , Sheng Han 1
Affiliation  

Three-dimensional (3D) layered tin oxide quantum dots/graphene framework (SnO2 QDs@GF) were designed through anchoring SnO2 QD on the graphene surface under the hydrothermal reaction. SnO2 QDs@GF have a 3D skeleton with a large number of mesopores and ultrasmall SnO2 QDs with a large surface area. The unique design of this structure improves the specific area and promotes ion transport. The mechanically strong SnO2 QDs@GF can directly be used as the anode of lithium-ion batteries (LIBs); it displays a high reversible capacity (1300 mA h g-1 at 100 mA g-1), excellent rate performance (642 mA h g-1 at 2000 mA g-1), and superior cyclic stability (when the current density is 10 A g-1, the capacity loss is less than 2% after 5000 cycles). This novel synthetic method can further be expanded for the production of other quantum dots/graphene composites with a 3D structure as high-performance electrodes for LIBs.

中文翻译:

SnO2 Quantum Dots @ Graphene框架可作为锂离子电池的高性能柔性阳极电极。

通过在水热反应下将SnO2 QD锚固在石墨烯表面上,设计了三维(3D)层状氧化锡量子点/石墨烯骨架(SnO2 QDs @ GF)。SnO2 QDs @ GF具有大量介孔的3D骨架和表面积较大的超小SnO2 QDs。这种结构的独特设计提高了比表面积并促进了离子传输。具有机械强度的SnO2 QDs @ GF可直接用作锂离子电池(LIB)的阳极;它显示出高可逆容量(在100 mA g-1时为1300 mA h g-1),出色的速率性能(在2000 mA g-1时为642 mA h g-1)和出色的循环稳定性(当电流密度为10时)一个g-1,经过5000次循环后,容量损失小于2%。
更新日期:2020-03-04
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