Transmetalation as Key Step in the Diastereo- and Enantioselective Synergistic Cu/Pd-Catalyzed Allylboration of Alkynes with Racemic Allylic Carbonates,Organometallics

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Transmetalation as Key Step in the Diastereo- and Enantioselective Synergistic Cu/Pd-Catalyzed Allylboration of Alkynes with Racemic Allylic Carbonates
Organometallics ( IF 2.5 ) Pub Date : 2020-02-19 , DOI: 10.1021/acs.organomet.0c00010
Jaime Mateos ₁ , Noelia Fuentes-Vara ₁ , Laura Fra ₁ , Eva Rivera-Chao ₁ , Nuria Vázquez-Galiñanes ₁ , Andrea Chaves-Pouso ₁ , Martín Fañanás-Mastral ₁

Affiliation

Cu/Pd-catalyzed alkyne allylboration with racemic allylic carbonates proceeds with total inversion of configuration. Preliminary studies show that this synergistic catalysis can be used to perform a dynamic asymmetric allylic alkenylation that provides enantioenriched carboboration products.

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