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Synthesis and characterization of 1,3,5-tris((1/2 H -tetrazol-5-yl)methyl)-1,3,5-triazinane-2,4,6-trione
Chemical Papers ( IF 2.1 ) Pub Date : 2017-01-12 , DOI: 10.1007/s11696-016-0018-2
Yadollah Bayat , Fatemeh Hajighasemali

2,2′,2″-(2,4,6-Trioxo-1,3,5-triazinane-1,3,5-triyl) triacetonitrile (or tris-(cyanomethyl)-isocyanurate) and 1,3,5-tris((1/2H-tetrazol-5-yl)methyl)-1,3,5-triazinane-2,4,6-trione (or tris-(5-tetrazolylmethyl)-isocyanurate) were synthesized with new methods. High yields, simple methodology, and cheapness are advantages of the methods. Furthermore, 1,3,5-tris((1/2H-tetrazol-5-yl)methyl)-1,3,5-triazinane-2,4,6-trione was synthesized in the less hazardous condition. The compounds were characterized by elemental analysis, IR, 1HNMR, 13CNMR and mass spectroscopic analysis. In addition, DSC/TGA measurements were carried out to determine the thermal behavior of the final product.

中文翻译:

1,3,5-三((1/2 H-四唑-5-基)甲基)-1,3,5-三嗪烷-2,4,6-三酮的合成与表征

2,2',2''-(2,4,6-Trioxo-1,3,5-triazinane-1,3,5-triyl)三乙腈或tris-(cyanomethyl)-isocyanurate)和1,3,5用新方法合成了-tris((1/2 H -tetrazol-5-yl)methyl)-1,3,5-triazinane-2,4,6-trione(或tris-(5-tetrazolylmethyl)-isocyanurate) 。该方法的优点是高产率,简单的方法和廉价。此外,在危险性较低的条件下合成了1,3,5-三((1/2 H-四唑-5-基)甲基)-1,3,5-三嗪烷-2,4,6-三酮。通过元素分析,IR,1 HNMR,13 CNMR和质谱分析对化合物进行表征。另外,进行DSC / TGA测量以确定最终产品的热行为。
更新日期:2017-01-12
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