An expeditious synthesis of novel organoselenium compounds (2–5) incorporating benzo[d] [1,3]dioxole subunit has been reported. All these newly synthesized compounds have been characterized by elemental analysis and various spectroscopic techniques viz., multinuclear NMR (¹H, ¹³C and ⁷⁷Se), IR and mass spectrometry. Furthermore, single crystal X-ray crystallographic results and molecular geometry of 1-((benzo[d][1,3]dioxol-5-yl)methyl)-2-((benzo[d][1,3]dioxol-6-yl)methyl)diselane (2) are reported. Thermal decomposition behavior of compound (2) was studied by thermogravimetric analysis.

A direct and concise method is reported to furnish novel benzo[d][1,3]dioxole incorporated diselenide using stable and readily available starting material. 1-((benzo[d][1,3]dioxol-5-yl)methyl)-2-((benzo[d][1,3]dioxol-6-yl)methyl)diselane, thus synthesized was transformed into various synthetically important unsymmetrical monoselenides by cleavage of Se–Se bond with sodium borohydride or rongalite.

中文翻译：

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新型苯并[d] [1,3]二恶唑取代的有机硒化合物的合成与表征：1-（（苯并[d] [1,3]二恶酚-5-基）甲基] -2-（的X射线结构（苯并[d] [1,3]二恶酚-6-基）甲基）

新型有机硒化合物（的迅速合成2 - 5）将苯并[ d ] [1,3]二氧杂环戊烯亚基已经报道。所有这些新合成的化合物均已通过元素分析和各种光谱技术（即多核NMR（¹ H，¹³ C和⁷⁷ Se），红外光谱和质谱分析）进行了表征。此外，1-（（苯并[ d ] [1,3]二氧杂-5-基）甲基）-2-（（苯并[ d ] [1,3]二氧杂-的单晶X射线晶体学结果和分子几何报道了6-（基）甲基）二硒烷（2）。化合物（2的热分解行为通过热重分析研究。

据报道，一种直接，简捷的方法是使用稳定且易于获得的起始原料提供新型的并入苯并[ d ] [1,3]二恶唑的二硒化物。1-（（苯并[ d ] [1,3]二氧杂-5-基）甲基）-2-（（苯并[ d ] [1,3]二氧杂-6-基）甲基）二氢呋喃，因此合成为通过用硼氢化钠或水钠钙石裂解Se-Se键可合成各种重要的非对称单硒化物。