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Energetic Derivatives of 8-Nitropyrazolo[1,5-a][1,3,5]triazine-2,4,7-triamine: Achieving Balanced Explosives by Fusing Pyrazole with Triazine.
Organic Letters ( IF 4.9 ) Pub Date : 2020-01-30 , DOI: 10.1021/acs.orglett.9b04642 Jinchao Ma 1, 2 , Yongxing Tang 1, 2 , Guangbin Cheng 2 , Gregory H Imler 3 , Damon A Parrish 3 , Jean'ne M Shreeve 1
Organic Letters ( IF 4.9 ) Pub Date : 2020-01-30 , DOI: 10.1021/acs.orglett.9b04642 Jinchao Ma 1, 2 , Yongxing Tang 1, 2 , Guangbin Cheng 2 , Gregory H Imler 3 , Damon A Parrish 3 , Jean'ne M Shreeve 1
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Using the triazine ring as the stabilizing factor, a series of energy-safety balanced fused ring compounds were successfully studied. Compounds 1, 7, and 9·H2O were further confirmed by single-crystal X-ray diffraction analysis. The detonation performance and safety parameters associated with impact and friction sensitivities were investigated by using EXPLO5 (version 6.01) and BAM methods, respectively. Based on their good detonation properties and high thermal and mechanical stabilities, these materials are potentially high performance insensitive explosives.
中文翻译:
8-Nitropyrazolo [1,5-a] [1,3,5] triazine-2,4,7-triamine的高能衍生物:通过将吡唑与三嗪融合获得平衡炸药。
以三嗪环为稳定因子,成功研究了一系列能量安全平衡的稠环化合物。通过单晶X射线衍射分析进一步确认了化合物1、7和9·H 2O。分别使用EXPLO5(6.01版)和BAM方法研究了与冲击和摩擦敏感性相关的爆震性能和安全参数。基于其良好的爆炸特性以及高的热稳定性和机械稳定性,这些材料可能是高性能的不敏感炸药。
更新日期:2020-01-31
中文翻译:
![](https://scdn.x-mol.com/jcss/images/paperTranslation.png)
8-Nitropyrazolo [1,5-a] [1,3,5] triazine-2,4,7-triamine的高能衍生物:通过将吡唑与三嗪融合获得平衡炸药。
以三嗪环为稳定因子,成功研究了一系列能量安全平衡的稠环化合物。通过单晶X射线衍射分析进一步确认了化合物1、7和9·H 2O。分别使用EXPLO5(6.01版)和BAM方法研究了与冲击和摩擦敏感性相关的爆震性能和安全参数。基于其良好的爆炸特性以及高的热稳定性和机械稳定性,这些材料可能是高性能的不敏感炸药。