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Dimerization of styrene to 1,3-diphenyl-1-butene catalyzed by palladium–Lewis acid in ionic liquid
Journal of Molecular Catalysis A: Chemical Pub Date : 1 August 2006 , DOI: 10.1016/j.molcata.2006.03.058
Jiajian Peng , Jiayun Li , Huayu Qiu , Jianxiong Jiang , Kezhi Jiang , Jianjiang Mao , Guoqiao Lai

Dimerization of styrene was investigated in ionic liquids and organic solvents with the catalysis of several palladium–Lewis acids catalyst systems. Pd(OAc)2/Cu(OTf)2 and Pd(OAc)2/In(OTf)3 in 1-butyl-3-methylimidazolium hexafluorophosphate were found to be effective catalyst systems towards the dimerization of styrene to 1,3-diphenyl-1-butene at room temperature.

中文翻译:

钯-路易斯酸在离子液体中将苯乙烯二聚为1,3-二苯基-1-丁烯

研究了苯乙烯在离子液体和有机溶剂中的二聚反应,并催化了几种钯-路易斯酸催化剂体系。发现六氟磷酸1-丁基-3-甲基咪唑鎓中的Pd(OAc)2 / Cu(OTf)2和Pd(OAc)2 / In(OTf)3是将苯乙烯二聚为1,3-二苯基的有效催化剂体系室温下-1-丁烯。
更新日期:2017-01-31
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