当前位置: X-MOL 学术Chem. Eur. J. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Long-Range Chiral Induction by a Fully Noncovalent Approach in Supramolecular Porphyrin-Calixarene Assemblies.
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2020-01-28 , DOI: 10.1002/chem.202000126
Massimiliano Gaeta 1 , Giuseppe Sortino 1 , Rosalba Randazzo 1 , Ilenia Pisagatti 2 , Anna Notti 2 , Maria Elena Fragalà 1 , Melchiorre F Parisi 2 , Alessandro D'Urso 1 , Roberto Purrello 1
Affiliation  

The hierarchical assembly, in aqueous solution, of a new multi-metalloporphyrin/calixarene aggregate has been accomplished. In this supramolecular system transfer of chirality, from the outermost components to the central porphyrin reporter, takes place as a result of favorable and fully noncovalent long-range electronic communication.

中文翻译:

在超分子卟啉-Calixarene组装物中通过完全非共价方法进行远距离手性诱导。

已经完成了新的多金属卟啉/杯芳烃聚集体在水溶液中的分级组装。在这种超分子系统中,由于有利的和完全非共价的远程电子通讯,发生了手性从最外层组分到中心卟啉报道分子的转移。
更新日期:2020-02-19
down
wechat
bug