O-Perfluoropyridin-4-yl Oximes: Iminyl Radical Precursors for Photo- or Thermal-Induced N-O Cleavage in C(sp2)-C(sp3) Bond Formation.,The Journal of Organic Chemistry

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O-Perfluoropyridin-4-yl Oximes: Iminyl Radical Precursors for Photo- or Thermal-Induced N-O Cleavage in C(sp2)-C(sp3) Bond Formation.
The Journal of Organic Chemistry ( IF 3.3 ) Pub Date : 2020-02-04 , DOI: 10.1021/acs.joc.9b03251
Peng-Ju Xia ₁ , Yuan-Zhuo Hu ₁ , Zhi-Peng Ye ₁ , Xu-Jie Li ₁ , Hao-Yue Xiang ₁ , Hua Yang _{1,

2}

Affiliation

O-Perfluoropyridin-4-yl group was first installed onto cycloketone oximes as a new electrophore, which was proven to be efficient iminyl radical precursors under photocatalytic and thermal conditions. A range of O-perfluoropyridin-4-yl oximes were successfully utilized in C(sp2)-C(sp3) bond formations of quinoxalin-2(1H)-ones and alkenes, providing facile accesses to a range of functionalized alkylnitriles.

中文翻译：

O-Perfluoropyridin-4-yl肟：亚胺基自由基前体的光或热诱导NO裂解C（sp2）-C（sp3）键的形成。

首先，将O-全氟吡啶-4-基作为一种新的电泳试剂安装在环酮肟上，事实证明该试剂是在光催化和热条件下有效的亚氨基自由基前体。一系列O-全氟吡啶-4-基肟已成功用于喹喔啉-2（1H）-一个和烯烃的C（sp2）-C（sp3）键形成中，提供了对一系列功能化烷基腈的便捷连接。

更新日期：2020-02-06

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