Chemical Physics Letters ( IF 2.8 ) Pub Date : 2020-01-21 , DOI: 10.1016/j.cplett.2020.137136 Ruslan Khabibrakhmanov , Anna Shurukhina , Aida Rudakova , Dmitrii Barinov , Vladimir Ryabchuk , Alexei Emeline , Galina Kataeva , Nick Serpone
The UV-induced photocoloration of cubic zirconia (c-ZrO2) stabilized by Y2O3, Yb2O3 and Er2O3 and treated as a wide bandgap metal oxide (MO2) heavily doped with M3+ ions has been examined by diffuse reflectance spectroscopy. Using the narrow f-f absorption bands of optically labeled Yb3+ and Er3+ as the M3+ dopants, the interaction of these dopant ions with photocarriers is demonstrated spectroscopically against a non-resolved broadband background. The latter occurs as a result of an offset of specific f-f absorption bands following conversion of M3+ ions into optically silent M2+ ions by the trapping of photoelectrons or by a change of the local symmetry of the M3+ surroundings caused by the UV-induced formation of color centers.
中文翻译:
紫外线在立方ZrO 2中形成缺陷。Y,Yb和Er掺杂剂与光载流子相互作用的光学演示
UV诱导的Y 2 O 3,Yb 2 O 3和Er 2 O 3稳定的立方氧化锆(c-ZrO 2)的光致变色,并被视为重掺杂M 3+离子的宽带隙金属氧化物(MO 2)通过漫反射光谱法检查。使用光学标记的Yb 3+和Er 3+的窄f - f吸收带作为M 3+掺杂物,这些掺杂物离子与光载流子的相互作用在未解析的宽带背景下通过光谱证明。后者发生作为一个特定的偏移的结果˚F - ˚F以下M的转换吸收带3+离子进入光学无声中号2+通过光电子的俘获或由M的局部对称性的变化离子3+引起的周围由紫外线引起的色心形成。