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Multi-addressable fluorescence switch based on a new photochromic diarylethene with two rhodamine B units
Tetrahedron ( IF 2.1 ) Pub Date : 2016-07-01 11:52:21
Yongjuan Tang, Shiqiang Cui, Shouzhi Pu

A novel diarylethene derivative with two rhodamine B units has been synthesized successfully. The diarylethene could be effectively controlled by the stimulation of light, proton, and metal ions. The fluorescence intensity of the diarylethene was enhanced upon addition of TFA, Al3+, Cr3+, and Fe3+, which was assigned to the blocked FRET process by the protonation of the rhodamine or complexation with Al3+, Cr3+, and Fe3+. The results indicated that the diarylethene could act as a multi-addressable fluorescence switch with the light, proton, and metal ions stimulus. Moreover, two logic circuits were constructed with the fluorescence intensity as the output signal responding to the light and chemical species as the inputs.

中文翻译:

基于具有两个若丹明B单元的新型光致变色二芳基乙烯的多址荧光开关

已经成功合成了具有两个若丹明B单元的新型二芳基乙烯衍生物。可以通过刺激光,质子和金属离子有效地控制二芳基乙烯。加入TFA,Al 3+,Cr 3+和Fe 3+可以提高二芳基乙烯的荧光强度,TFA,Al 3+,Cr 3+和Fe 3+可以通过罗丹明的质子化或与Al 3+,Cr 3+的络合作用分配给封闭的FRET过程。和Fe 3+。结果表明,在光,质子和金属离子的刺激下,二芳基乙烯可以作为多重寻址的荧光开关。此外,构建了两个逻辑电路,其中荧光强度作为输出信号,响应于光和化学物质作为输入。
更新日期:2016-07-01
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