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The coordination chemistry of 1,3-dithiole-2-thione-4,5-dithiolate (dmit) and isologs
Coordination Chemistry Reviews ( IF 20.3 ) Pub Date : 1999 , DOI: 10.1016/s0010-8545(99)00031-4
Anthony E. Pullen , Ruth-Maria Olk

The 1,3-dithiole-2-thione-4,5-dithiolate (dmit) ligand and chalcogen atom substituted isologs have been extensively used in organic and coordination chemistry since their first reported synthesis in 1975. Over approximately the past 8 years a number of diverse and interesting dmit coordination complexes have been described. Also, dmit and isologs have been used in a variety of material applications, including in superconducting charge-transfer and radical anion salts. The synthesis, structures and properties of a selection of these compounds will be presented and discussed covering the literature from 1991 to approximately mid-1998.

中文翻译:

1,3-二硫代-2-硫酮-4,5-二硫代(dmit)和同系物的配位化学

自1975年首次报道合成以来,1,3-二硫代-2-硫酮-4,5-二硫代(dmit)配体和硫属元素原子取代的同系物已广泛用于有机和配位化学中。在大约8年的时间里,已经描述了多种有趣的dmit配合物。同样,dmit和同系物已用于多种材料应用中,包括超导电荷转移和自由基阴离子盐。这些化合物的合成,结构和性质将在1991年至1998年中期的文献中进行介绍和讨论。
更新日期:2017-01-31
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