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Homoadamatane methyl ketone, a novel re-arrangement product from the addition of 1-adamantyl cation to prop-2-ynyl alcohol
Journal of the Chemical Society D: Chemical Communications Pub Date : 1971 , DOI: 10.1039/c29710000556
Jiban K. Chakrabarti , Alec Todd

The addition reaction of the 1-adamantyl cation with prop-2-ynyl alcohol in conc. H2SO4 gives a rearranged product, homoadamantyl methyl ketone; evidence for its structure is presented.

中文翻译:

同金刚烷甲基酮,一种从1-金刚烷基阳离子加到丙-2-炔醇中的新型重排产物

1-金刚烷基阳离子与丙-2-炔醇在浓溶液中的加成反应。H 2 SO 4得到重排产物高金刚烷基甲基酮;提供了其结构的证据。
更新日期:2017-01-31
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