This review focuses on the most recent advances in the field of transition‐metal‐catalyzed direct intermolecular C−H amidation and amination of arenes. The manuscript is divided into two parts according to whether or not external oxidants are required. The first part includes the cases of simple neutral amines, amides, or sulfonamides in combination with external oxidants. The second section contains the examples of preactivated amino sources in the absence of any external oxidants. In each part, the content is classified in line with the different types of transition‐metal catalysts used, including Rh, Ru, Ir, Pd, Cu, Ni, Co, and Fe. In addition, the substrate scope and limitations as well as catalytic mechanism are discussed.

中文翻译：

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指导基团辅助的过渡金属催化的直接分子间CH酰胺化和芳烃的胺化

这篇综述着重于过渡金属催化的直接分子间CH H酰胺化和芳烃胺化领域的最新进展。根据是否需要外部氧化剂，手稿分为两部分。第一部分包括简单的中性胺，酰胺或磺酰胺与外部氧化剂结合使用的情况。第二部分包含在没有任何外部氧化剂的情况下预活化氨基源的实例。在每个部分中，含量均根据所用过渡金属催化剂的不同类型进行分类，包括Rh，Ru，Ir，Pd，Cu，Ni，Co和Fe。此外，讨论了底物的范围和局限性以及催化机理。