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Homolytic reactions of perfluoroaromatic compounds. Part I. Arylation of hexafluorobenzene
J. Chem. Soc. C Pub Date : 1968 , DOI: 10.1039/j39680000341
P. A. Claret , Gareth H. Williams , Judith Coulson

The reactions between hexafluorobenzene and a series of diaroyl peroxides have been shown to give 2,3,4,5,6-pentafluorobiphenyl and appropriately substituted derivatives. The significance of the yields of the biaryls obtained and the nature of the other reaction products are discussed, and a mechanism for the reaction is suggested tentatively.

中文翻译:

全氟芳族化合物的均相反应。第一部分:六氟苯的芳基化

六氟苯与一系列二芳酰过氧化物之间的反应已显示出2,3,4,5,6-五氟联苯和适当取代的衍生物。讨论了所获得的联芳基收率的重要性以及其他反应产物的性质,并初步提出了反应机理。
更新日期:2017-01-31
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