Alkenylation of Arenes and Heteroarenes with Alkynes,Chemical Reviews

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Alkenylation of Arenes and Heteroarenes with Alkynes
Chemical Reviews ( IF 51.4 ) Pub Date : 2016-04-25 00:00:00 , DOI: 10.1021/acs.chemrev.5b00514
Vadim P. Boyarskiy ₁ , Dmitry S. Ryabukhin _{1,

2} , Nadezhda A. Bokach ₁ , Aleksander V. Vasilyev _{1,

2}

Affiliation

This review is focused on the analysis of current data on new methods of alkenylation of arenes and heteroarenes with alkynes by transition metal catalyzed reactions, Bronsted/Lewis acid promoted transformations, and others. The synthetic potential, scope, limitations, and mechanistic problems of the alkenylation reactions are discussed. The insertion of an alkenyl group into aromatic and heteroaromatic rings by inter- or intramolecular ways provides a synthetic route to derivatives of styrene, stilbene, chalcone, cinnamic acid, various fused carbo- and heterocycles, etc.

中文翻译：

芳烃和杂芳烃与炔烃的烯基化

这篇综述的重点是对通过过渡金属催化反应，布朗斯台德/路易斯酸促进的转化等方法对芳烃和杂芳烃与炔烃进行烯基化新方法的最新数据的分析。讨论了烯基化反应的合成潜力，范围，局限性和机理问题。通过分子间或分子内方式将烯基插入芳族和杂芳族环中，为苯乙烯，to，查尔酮，肉桂酸，各种稠合的碳环和杂环等的衍生物提供了合成途径。

更新日期：2016-04-25

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