Development of metal-porphyrin based asymmetric metalloradical catalysis (MRC) Including: Design and Synthesis of Metal-porphyrin Based Catalysts; Application of Metalloradical Catalysis for Stereoselective Radical Cyclization, C-H Functionalization, Cascade processes, and Construction of Complex Molecules; Study the Structure and Nature of Active Intermediates by Electron Paramagnetic Resonance (EPR).