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成果及论文

123.  Wang, X.-X.; Ke, J.; Zhu, Y.-L.; Deb, A.; Xu, Y.-J.; Zhang, X. P. “Asymmetric Radical Process for General Synthesis of Chiral Heteroaryl Cyclopropanes” J. Am. Chem. Soc. 2021, 10.1021/jacs.1c04655.

122.  Zhang, C.-Z.; Wang, D.-S.; Lee, W.-C. C.; McKillop, A. M.; Zhang, X. P. “Controlling Enantioselectivity and Diastereoselectivity in Radical Cascade Cyclization for Construction of Bicyclic Structures” J. Am. Chem. Soc. 2021, DOI: 10.1021/jacs.1c04719.

121.  Lee, W.-C. C. “Metalloradical Catalysis: A Radically Different Approach for Molecular Construction” Chem 2021, 7, 1402-1404.

120.  Lee, W.-C. C.; Wang, D.-S.; Zhang, C.-Z.; Xie, J.-J.; Li, B.; Zhang, X. P. “Asymmetric Radical Cyclopropanation of Dehydroaminocarboxylates: Stereoselective Synthesis of Cyclopropyl α-Amino Acids” Chem 2021, 7, 1588-1601.

119.  Magnuson, Z. L.; Cheng, Q.-G.; Zhang, W.-J.; Chen, Y.-S.; Wojtas, L.; Nafady, A.; Al-Enizi, A. M.; Larsen, R. W.; Zhang, X. P.; Ma, S.-Q. “Two Manganese Metalloporphyrin Frameworks Constructed from a Custom-Designed Porphyrin Ligand Exhibiting Selective Uptake of CO2 over CH4 and Catalytic Activity for CO2 Fixation” Cryst. Growth Des. 2021, 21, 2786–2792.

118.  Riart-Ferrer, X.; Sang, P.; Tao, J.-R.; Xu, H.; Jin, L.-M.; Lu, H.-J.; Cui, X.; Wojtas, L.; Zhang, X. P. “Metalloradical Activation of Carbonyl Azides for Enantioselective Radical Aziridination” Chem 2021, 7, 1120–1134.

117.  Lang, K.; Li, C.-Q.; Kim, I.; Zhang, X. P. “Enantioconvergent Amination of Racemic Tertiary C-H Bonds” J. Am. Chem. Soc. 2020142, 20902–20911.

116.  Jin, L.-M.; Xu, P.; Xie, J.-J.; Zhang, X. P. “Enantioselective Intermolecular Radical C−H Amination” J. Am. Chem. Soc. 2020142, 20828–20836.

115.  Hu, Y.; Lang, K.; Li, C.-Q.; Gill, J. B.; Kim, I.; Lu, H.-J.; Fields, K. B.; Marshall, M. K.; Cheng, Q.-G.; Cui, X.; Wojtas, L.; Zhang, X. P. “Enantioselective Radical Construction of 5-Membered Cyclic Sulfonamides by Metalloradical C−H Amination” J. Am. Chem. Soc. 2019141, 18160-18169.

114.  Lang, K.; Torker, S.; Wojtas, L.; Zhang, X. P. “Asymmetric Induction and Enantiodivergence in Catalytic Radical C–H Amination via Enantiodifferentiative H-Atom Abstraction and Stereoretentive Radical Substitution” J. Am. Chem. Soc. 2019141, 12388–12396.

113.  Hu, Y.; Lang, K.; Tao, J.-R.; Marshall, M. K.; Cheng, Q.-G.; Cui, X.; Wojtas, L.; Zhang, X. P. “Next-Generation D2-Symmetric Chiral Porphyrins for Cobalt(II)-Based Metalloradical Catalysis: Catalyst Engineering by Distal Bridging” Angew. Chem. Int. Ed. 201958, 2670–2674.

112.  Li, C.-Q.; Lang, K.; Lu, H,-J.; Hu, Y.; Cui, X.; Wojtas, L.; Zhang, X. P. “Catalytic Radical Process for Enantioselective Amination of C(sp3)-H Bonds” Angew. Chem. Int. Ed. 201857, 16837–16841.

111.  Wen, X.; Wang, Y.; Zhang, X. P. “Enantioselective Radical Process for Synthesis of Chiral Indolines by Metalloradical Alkylation of Diverse C(sp3)-H Bonds” Chem. Sci. 20189, 5082–5086.

110.  Wang, Y.; Wen, X.; Cui, X.; Zhang, X. P. “Enantioselective Radical Cyclization for Construction of 5-Membered Ring Structures by Metalloradical C-H Alkylation” J. Am. Chem. Soc. 2018140, 4792–4796.

109.  Wang, Y.; Zhang, X. P. “[Co(3,5-Di-t-Bu-QingPhyrin)]” e-EROS, John Wiley & Sons, 2018; DOI: 10.1002/047084289X.rn02204.

108.  Wang, Y.; Zhang, X. P. “[Co(3,5-Di-t-Bu-Xu(2'-Naph)Phyrin)]” e-EROS, John Wiley & Sons, 2018; DOI: 10.1002/047084289X.rn02203.

107.  Wang, Y.; Zhang, X. P. “[Co(3,5-Di-t-Bu-ChenPhyrin)]” e-EROS, John Wiley & Sons, 2018; DOI: 10.1002/047084289X.rn02202.

106.  Wang, Y.; Zhang, X. P. “[Co(3,5-Di-t-Bu-IbuPhyrin)]” e-EROS, John Wiley & Sons, 2018; DOI: 10.1002/047084289X.rn02201.

105.  Wang, Y.; Zhang, X. P. “[Co(2,6-DiMeO-ZhuPhyrin)]” e-EROS, John Wiley & Sons, 2018; DOI: 10.1002/047084289X.rn02200.

104.  Jiang, H.-L.; Lang, K.; Lu, H.-J.; Wojtas, L.; Zhang, X. P. “Asymmetric Radical Bicyclization of Allyl Azidoformates via Cobalt(II)-Based Metalloradical Catalysis” J. Am. Chem. Soc. 2017139, 9164–9167.

103.  Xu, X.; Wang, Y.; Cui, X.; Wojtas, L.; Zhang, X. P. “Metalloradical Activation of α-Formyldiazoacetates for Catalytic Asymmetric Radical Cyclopropanation of Alkenes” Chem. Sci. 20178, 4347–4351.

102.  Wang, Y.; Wen, X.; Cui, X.; Wojtas, L.; Zhang, X. P. “Asymmetric Radical Cyclopropanation of Alkenes with In Situ-Generated Donor-Substituted Diazo Reagents via Co(II)-Based Metalloradical Catalysis” J. Am. Chem. Soc. 2017139, 1049–1052.

101.  Pegis, M. L.; McKeown, B. A.; Kumar, N.; Lang, K.; Wasylenko, D. J.; Zhang, X. P.; Raugei, S.; Mayer, J. M. “Homogenous Electrocatalytic Oxygen Reduction Rates Correlate with Reaction Overpotential in Acidic Organic Solutions” ACS Cent. Sci. 20162, 850–856.

100.  Jiang, H.-L.; Lang, K.; Lu, H.-J.; Wojtas, L.; Zhang, X. P. “Intramolecular Radical Aziridination of Allylic Sulfamoyl Azides via Co(II)-Based Metalloradical Catalysis: Effective Construction of Strained heterobicyclic Structures” Angew. Chem. Int. Ed. 201655, 11604–11608.

99.  Lu, H.-J.; Lang, K.; Jiang, H.-L.; Wojtas, L.; Zhang, X. P. “Intramolecular 1,5-C(sp3)–H Radical Amination via Co(II)-Based Metalloradical Catalysis for Five-Membered Cyclic Sulfamides” Chem. Sci. 20167, 6934–6939.

98.  Liu, Q.-J.; Wang, L.-J.; Kang, Q.-K.; Zhang, X. P.; Tang, Y. “Cy-SaBOX/Copper(II)-Catalyzed Highly Diastereo- and Enantioselective Synthesis of Bicyclic N,O Acetals” Angew. Chem. Int. Ed. 201655, 9220–9223.

97.  Liu, Q.-J.; Yan, W.-G.; Wang, L.-J.; Zhang, X. P.; Tang, Y. “One-Pot Catalytic Asymmetric Synthesis of Tetrahydrocarbazoles” Org. Lett.201517, 4014–4017.

96.  Goswami, M.; Lyaskovskyy, V.; Domingos, S. R.; Buma, W. J.; Woutersen, S.; Troeppner, O.; Ivanovic-Burmazovic, I.; Lu, H.-J.; Cui, X.; Zhang, X. P.; Reijerse, E. J.; DeBeer S.; van Schooneveld, M. M.; Pfaff, F.; Ray, K.; de Bruin, B. “Characterization of Porphyrin-Co(III)-‘Nitrene Radical’ Species Relevant in Catalytic Nitrene Transfer Reactions” J. Am. Chem. Soc. 2015137, 5468–5479.

95.  Subbarayan, V.; Jin, L.-M., Cui, X.; Zhang, X. P. “Room Temperature Activation of Aryloxysulfonyl Azides by [Co(II)(TPP)] for Selective Radical Aziridination of Alkenes via Metalloradical Catalysis” Tetrahedron Lett. 201556, 3431–3434.

94.  Cui, X.; Xu, X.; Jin, L.-M.; Wojtas, L.; Zhang, X. P. “Stereoselective Radical C–H Alkylation with Acceptor/Acceptor-Substituted Diazo Reagents via Co(II)-Based Metalloradical Catalysis” Chem. Sci. 20156, 1219–1224.

93.  Jin, C.-Y., Decker, A. M.; Huang, X.-P.; Gilmour, B. P.; Blough, B. E.; Roth, B. L.; Hu, Y.; Gill, J. B.; Zhang, X. P. “Synthesis, Pharmacological Characterization, and Structure-Activity Relationship Studies of Small Molecular Agonists for the Orphan GPR88” ACS Chem. Neurosci. 2014,5, 576–587.

92.  Lu, H.-J.; Li, C.-Q.; Jiang, H.-L.; Lizardi, C. L.; Zhang, X. P. “Chemoselective Amination of Propargylic C(sp3)−H Bonds via Co(II)-Based Metalloradical Catalysis” Angew. Chem. Int. Ed. 2014, 53, 7028–7032.

91.  Tao, J.-R.; Jin, L.-M.; Zhang, X. P. “Synthesis of Chiral N-Phosphoryl Aziridines through Enantioselective Aziridination of Alkenes With Phosphoryl Azide via Co(II)-Based Metalloradical Catalysis” Beilstein J. Org. Chem. 201410, 1282–1289.

90.  Ruppel, J. V.; Cui, X.; Xu, X.; Zhang, X. P. “Stereoselective Intramolecular Cyclopropanation of alpha-Diazoacetates via Co(II)-Based Metalloradical Catalysis” Org. Chem. Front. 20141, 515–520.

89.  Jin, L.-M.; Lu, H.-J.; Cui, Y.; Lizardi, C. L.; Arzua, T. N.; Wojtas, L.; Cui, X.; Zhang, X. P. “Selective Radical Amination of Aldehydic C(sp2)‒H Bonds with Fluoroaryl Azides via Co(II)-Based Metalloradical Catalysis: Synthesis of N-Fluoroaryl Amides from Aldehydes under Neutral and Nonoxidative Conditions” Chem. Sci. 20145, 2422–2427.

88.  Paul, N. D.; Mandal, S.; Otte, M.; Cui, X.; Zhang, X. P.; de Bruin, B. “A Metalloradical Approach to 2H-Chromenes” J. Am. Chem. Soc. 2014136, 1090–1096.

87.  Cui, X.; Zhang, X. P. “Asymmetric C–H Functionalization by Transition Metal-Catalyzed Carbene Transfer Reactions” In Comprehensive Organic Synthesis II (Second Edition) Eds. Knochel, P.; Molander, G.; Amsterdam: Elsevier, 2014, Vol. 7, pp. 86–120.

86.  Maza, W. A.; Vetromile, G. M.; Kim, C.-S.; Xu, X.; Zhang, X. P.; Larsen, R. W. “Spectroscopic Investigation of the Noncovalent Association of the Nerve Agent Simulant Diisopropyl Methylphosphonate (DIMP) with Zinc(II)porphyrins” J. Phys. Chem. A. 2013, 117, 11308–11315.

85.  Xu, X.; Zhu, S.-F.; Cui, X.; Wojtas, L.; Zhang, X. P. “Cobalt(II)-Catalyzed Asymmetric Olefin Cyclopropanation with a-Ketodiazoacetates” Angew. Chem. Int. Ed. 2013, 52, 11857–11861.

84.  Paul, N. D.; Lu, H.-J.; Zhang, X. P.; de Bruin, B. “Carbene Radicals in Cobalt(II) Porphyrin-Catalyzed Carbene Carbonylation Reactions: A Catalytic Approach to Ketenes” Chem. Eur. J. 201319, 12953–12958.

83.  Liu, L.; Xie, H.; Bostic, H. E.; Jin, L.-M.; Best, D. B.; Zhang, X. P.; Zhan, W. “Effects of Oriented Surface Dipole on Photoconversion Efficiency in an Alkane/Lipid-Hybrid-Bilayer-Based Photovoltaic Model System” ChemPhysChem 201314, 2777–2785.

82.  Cui, X.; Zhang, X. P. “Cobalt-Mediated Carbene Transfer Reactions” In Contemporary Carbene Chemistry; eds. Moss, R. A.; Doyle, M. P.; John Wiley & Sons, 2013, Chapter 15, 491–525.

81.  Jin, L.-M.; Xu, X.; Lu, H.; Cui, X.; Wojtas, L.; Zhang, X. P. “Effective Synthesis of Chiral N-Fluoroaryl Aziridines via Enantioselective Aziridination of Alkenes with Fluoroaryl Azides” Angew. Chem. Int. Ed. 2013, 52, 5309–5313. 

80.  Cui, X.; Xu, X.; Wojtas, L.; Kim, M. M.; Zhang, X. P. “Regioselective Synthesis of Multisubstituted Furans via Metalloradical Cyclization of Alkynes with alpha-Diazocarbonyls: Construction of Functionalized alpha-Oligofurans” J. Am. Chem. Soc. 2012134, 19981–19984.

79.  Lu, H.-J.; Jiang, H.-L.; Hu, Y.; Wojtas, L.; Zhang, X. P. “Stereoselective Radical Amination of Electron-Deficient C(sp3)–H Bonds by Co(II)-Based Metalloradical Catalysis: Synthesis of alpha-Amino Acid Derivatives via alpha-C–H Amination of Esters and Amides” Org. Lett. 201214, 5158–5161.

78.  Meng, L.; Cheng, Q.; Kim, C.-S.; Gao, W.-Y.; Wojtas, L.; Chen, Y.-S.; Zaworotko, M. J.; Zhang, X. P.; Ma, S.-Q. “Crystal Engineering of a Microporous, Catalytically Active fcu Topology MOF Using a Custom-Designed Metalloporphyrin Linker” Angew. Chem. Int. Ed. 201251, 10082–10085.

77.  Jiang, H.-L.; Zhang, X. P. “Oxidation: C─N Bond Formation by Oxidation (Aziridines)” In Comprehensive Chirality; eds. Carreira, E. M.; Yamamoto, H.; Amsterdam: Elsevier, 2012, Vol. 5, pp. 168–182. 

76.  Wang, X.-S.; Chrzanowski, M.; Gao, W.-Y.; Kim, C.-S.; Wojtas, L.; Chen, Y.-S.; Zhang, X. P.; Ma, S.-Q. “Quest for Highly Porous Metal-Metalloporphyrin Framework Based upon A Custom-Designed Octatopic Porphyrin Ligand” Chem. Commun. 201248, 7173–7175.

75.  Hu, Y.; Zhang, X. P. “Selective Olefination of Carbonyl Compounds via Metal-Catalyzed Carbene Transfer from Diazo Reagents” Top. Curr. Res. 2012327, 147–162.

74.  Zhu, S.-F.; Cui, X.; Zhang, X. P. “Ligand Effect on Cobalt(II)-Catalyzed Asymmetric Cyclopropanation with Diazosulfones: Approaching High Stereoselectivity through Modular Design of D2-Symmetric Chiral Porphyrins” Eur. J. Inorg. Chem. 2012, 430–434.

73.  Burda, W. N.; Fields, K. B.; Gill, J. B.; Burt, R.; Shepherd, M.; Zhang, X. P.; Shaw, L. N. “Neutral Metallated and Meso-Substituted Porphyrins as Antimicrobial Agents Against Gram-Positive Pathogens” Eur. J. Clin. Microbiol. Infect. Dis. 201231, 327–335.

72.  Cui, X.; Zhang, X. P. “Iron(III) meso-Tetraphenylporphine Chloride” e-EROS, John Wiley & Sons, 2012; DOI: 10.1002/047084289X.rn01388.

71.  Wang, X.-S.; Meng, L.; Cheng, Q.-G.; Kim, C.-S.; Wojtas, L.; Chrzanowski, M.; Chen, Y.-S.; Zhang, X. P.; Ma, S.-Q. “A Three-Dimensional Porous Metal-Metalloporphyrin Framework Consisting of Nanoscopic Polyhedral Cages with a High Density of Open Metal Sites” J. Am. Chem. Soc. 2011133, 16322–16325.

70.  Lu, H.-J.; Jiang, H.-L.; Hu, Y.; Wojtas, L.; Zhang, X. P. “Chemoselective Intramolecular Allylic C–H Amination over C=C Aziridination through Co(II)-Based Metalloradical Catalysis” Chem. Sci. 20112, 2361–2366. 

69.  Xu, X.; Lu, H.-J.; Ruppel, J. V.; Cui, X.; de Mesa, S. L.; Wojtas, L.; Zhang, X. P. “Highly Asymmetric Intramolecular Cyclopropanation of Acceptor-Substituted Diazoacetates by Co(II)-Based Metalloradical Catalysis: Iterative Approach for Development of New Generation Catalysts” J. Am. Chem. Soc. 2011133, 15292–15295.

68.  Lyaskovskyy, V.; Suarez, A. I. O.; Lu, H.-J.; Jiang, H.-L.; Zhang, X. P.; de Bruin, B. “Mechanism of Cobalt(II) Porphyrin-Catalyzed C–H Amination with Organic Azides: Radical Nature and H-Atom Abstraction Ability of Cobalt(III)-Nitrene Key Intermediates” J. Am. Chem. Soc.2011133, 12264–12273.

67.  Lu, H.-J.; Dzik, W. I.; Xu, X.; Wojtas, L.; de Bruin, B.; Zhang, X. P. “Experimental Evidence for Cobalt(III)-Carbene Radicals: Key Intermediates in Cobalt(II)-Based Metalloradical Cyclopropanation” J. Am. Chem. Soc. 2011133, 8518–8521.

66.  Belof, J. L.; Cioce, C. R.; Xu, X.; Zhang, X. P.; Space, B.; Woodcock, H. L. “Characterization of Tunable Radical Metal-Carbenes: Key Intermediates in Catalytic Cyclopropanation”, Organometallics 201130, 2739–2746.

65.  Dzik, W. I.; Zhang, X. P.; de Bruin, B. “The Redox Non-Innocence of Carbene Ligands: Carbene Radicals in (Catalytic) C-C Bond Formation” Inorg. Chem.  201150, 9896–9903.

64.  Uygun, A.; Myjavcova, R.; Yavuz, A. G.; Ruppel. J. V.; Fields, K. B.; Frankhauser, A.; Zhang, X. P.; Bhethanbotla, V. R.; Bednar, P. “Electrochemical Polymerization and Investigation of Properties of Poly(5-(4’-aminophenylamino)-10,20-diphenylporphyrin)” Electroanalysis201123, 1158–1167.

63.  Suarez, A. I. O.; Jiang, H.-L.; Zhang, X. P.; de Bruin, B. “The Radical Mechanism of Cobalt(II) Porphyrin-Catalyzed Olefin Aziridination and the Importance of Cooperative H-Bonding” Dalton Trans.  201140, 5697–5705.

62.  Cui, X.; Xu, X.; Lu, H.-J.; Zhu, S.-F.; Wojtas, L.; Zhang, X. P. “Enantioselective Cyclopropenation of Alkynes with Acceptor/Acceptor-Substituted Diazo Reagents via Co(II)-Based Metalloradical Catalysis” J. Am. Chem. Soc. 2011133, 3304–3307. 

61.  Lu, H.-J.; Zhang, X. P. “Catalytic C–H Functionalization by Metalloporphyrins: Recent Development and Future Directions” Chem. Soc. Rev. 201140, 1899–1909.

60.  Fields, K. B.; Engle, J. T.; Sripothongnak, S.; Kim, C.-S.; Zhang, X. P.; Ziegler, C. J. “Cobalt Carbaporphyrin-Catalyzed Cyclopropanation” Chem. Commun. 201147, 749.  

59.  Lu, H.-J.; Jiang, H.-L.; Wojtas, L.; Zhang, X. P. “Selective Intramolecular C–H Amination via Metalloradical Activation of Azides: Synthesis of 1,3-Diamines under Neutral and Nonoxidative Conditions” Angew. Chem. Int. Ed. 201049, 10192–10196.

58.  Zhan, W.; Jiang, K.; Smith, M. D.; Bostic, H. E.; Best, M. D.; Auad, M. L.; Ruppel, J. V.; Kim, C.-S.; Zhang, X. P. “Photocurrent Generation from Porphyrin/Fullerene Complexes Assembled in a Tethered Lipid Bilayer” Langmuir 2010, 26, 15671–15679.

57.  Hilker, B.; Fields, K. B.; Stern, A.; Space, B.; Zhang, X. P.; Harmon, J. P. “Dielectric Analysis of Poly(methyl methacrylate) Zinc(II) Mono-pinacolborane Diphenylporphyrin Composites” Polymer 2010, 51, 4790–4805.

56.  Zhu, S.-F.; Xu, X.; Perman, J. A.; Zhang, X. P. “A General and Efficient Cobalt(II)-Based Catalytic System for Highly Stereoselective Cyclopropanation of Alkenes with a-Cyano-Diazoacetates” J. Am. Chem. Soc. 2010132, 12796–12799.

55.  Dzik, W. I.; Xu, X.; Zhang, X. P.; Reek, J. N. H.; de Bruin, B. “Carbene Radicals’ in CoII(por)-Catalyzed Olefin Cyclopropanation” J. Am. Chem. Soc. 2010132, 10891–10902.

54.  Lu, H.-J.; Tao, J.-R.; Jones, J. E.; Wojtas, L.; Zhang, X. P. “Co(II)-Catalyzed Intramolecular C–H Amination of Phosphoryl Azides: Formation of 6- and 7-Membered Cyclophosphoramidates” Org. Lett. 2010, 12, 1248–1251.

53.  Lu, H.-J.; Subbarayan, V.; Tao, J.; Zhang, X. P. “Cobalt-Catalyzed Intermolecular Benzylic C–H Amination with 2,2,2-Trichloroethoxycarbonyl Azide (TrocN3)” Organometallics 201029, 389–393.

52.  Ruppel, J. V.; Fields, K. B.; Snyder, N. L.; Zhang, X. P. “Metalloporphyrin-Catalyzed Asymmetric Atom/Group Transfer Reactions” In Handbook of Porphyrin Science; eds. Kadish, K. M.; Smith, K. M.; Guilard, R.; World Scientific, 2010, Vol. 10, Chapter 43, pp. 1–84.

51.  Fields, K. B.; Ruppel, J. V.; Snyder, N. L.; Zhang, X. P. “Porphyrin Functionalization via Carbon-Heteroatom Cross-Coupling Reactions” In Handbook of Porphyrin Science; eds. Kadish, K. M.; Smith, K. M.; Guilard, R.; World Scientific, 2010, Vol. 3, Chapter 13, pp. 367–428.

50.  Subbarayan, V.; Ruppel, J. V.; Zhu, S.-F.; Perman, J. A.; Zhang, X. P. “Highly Asymmetric Cobalt-Catalyzed Aziridination of Alkenes with Trichloroethoxysulfonyl Azide (TcesN3)” Chem. Commun. 2009, 4266–4268.

49.  Ruppel, J. V.; Gauthier, T. J.; Snyder, N. L.; Perman, J. A.; Zhang, X. P. “Asymmetric Cobalt-Catalyzed Cyclopropanation with Succinimidyl Diazoacetate: General Synthesis of Optically Active Cyclopropyl Carboxamides” Org. Lett. 200911, 2273–2276.

48.  Zhu, S.-F.; Zhang, X. P. “Cobalt(II) Acetate” e-EROS, John Wiley & Sons, 2009; DOI: 10.1002/047084289X.rc182.pub2.

47.  Zhu, S.-F.; Perman, J. A.; Zhang, X. P. “Acceptor/Acceptor-Substituted Diazo Reagents for Carbene Transfers: Cobalt-Catalyzed Asymmetric (Z)-Cyclopropanation of Alkenes with a-Nitro-Diazoacetates” Angew. Chem. Int. Ed. 2008, 47, 8460–8463.

46.  Jones, J. E.; Ruppel, J. V.; Gao, G.-Y.; Thomas, M. M.; Zhang, X. P. “Cobalt-Catalyzed Asymmetric Olefin Aziridination with Diphenylphosphoryl Azide” J. Org. Chem. 200873, 7260–7265.

45.  Gao, G.-Y.; Ruppel, J. V.; Fields, K. B.; Xu, X.; Chen, Y.; Zhang, X. P. “Synthesis of Diporphyrins via Palladium-Catalyzed C–O Bond Formation: Effective Access to Chiral Diporphyrins” J. Org. Chem. 200873, 4855–4858.

44.  Ruppel, J. V.; Jones, J. E.; Huff, C. A.; Kamble, R. M.; Chen, Y.; Zhang, X. P. “A Highly Effective Cobalt Catalyst for Olefin Aziridination with Azides: Hydrogen Bonding-Guided Catalyst Design” Org. Lett. 200810, 1995–1998.

43.  Zhu, S.; Ruppel, J. V.; Lu, H.; Wojtas, L.; Zhang, X. P. “Cobalt-Catalyzed Asymmetric Cyclopropanation with Diazosulfones: Rigidification and Polarization of Ligand Chiral Environment via Hydrogen Bonding and Cyclization” J. Am. Chem. Soc. 2008130, 5042–5043.

42.  Gao, G. Y.; Ruppel, J. V.; Allen, D. B.; Chen, Y.; Zhang, X. P. "Synthesis of beta-Functionalized Porphyrins via Palladium-Catalyzed Carbon–Heteroatom Bond Formations: Expedient Entry into beta-Chiral Porphyrins" J. Org. Chem. 200772, 9060–9066.

41.  Harden, J. D.; Ruppel, J. V.; Gao, G.-Y.; Zhang, X. P. “Cobalt-Catalyzed Intermolecular C–H Amination with Bromamine-T as Nitrene Source” Chem. Comm. 2007, 4644–4646.

40.  Ruppel, J. V.; Kamble, R. M.; Zhang, X. P. "Cobalt-Catalyzed Intramolecular C–H Amination with Arylsulfonyl Azides" Org. Lett. 20079, 4889–4892.

39.  Chen, Y.; Ruppel, J. V.; Zhang, X. P. “Cobalt-Catalyzed Asymmetric Cyclopropanation of Electron-Deficient Olefins” J. Am. Chem. Soc.2007129, 12074–12075.

38.  Chen, Y.; Zhang, X. P. "Asymmetric Cyclopropanation of Styrenes Catalyzed by Metal Complexes of D2-Symmetrical Chiral Porphyrin: Superiority of Cobalt over Iron" J. Org. Chem. 200772, 5931–5934.

37.  Gao, G.-Y.; Jones, J. E.; Vyas, R.; Harden, J. D.; Zhang, X. P. "Cobalt-Catalyzed Aziridination with Diphenylphosphoryl Azide (DPPA): Direct Synthesis of N-Phosphorous-Substituted Aziridines from Alkenes" J. Org. Chem. 200671, 6655–6658.

36.  Chen, Y.; Zhang, X. P. “Trans Effect on Cobalt Porphyrin Catalyzed Asymmetric Cyclopropanation” Synthesis 2006No.10, 1697–1700. (Invited Contribution to Special Topic)

35.  Gao, G.-Y.; Harden, J. D.; Zhang, X. P. “Cobalt-Catalyzed General and Efficient Aziridination of Alkenes” Org. Lett. 20057, 3191–3193.

34.  Chen, Y.; Gao, G.-Y.; Zhang, X. P. “Palladium-Mediated Synthesis of Novel meso-Chiral Porphyrins for Cobalt-Catalyzed Cyclopropanation” Tetrahedron Lett. 200546, 4965–4969.

33.  Baskaran, D.; Mays, J. W.; Zhang, X. P.; Bratcher, M. S. “Carbon Nanotubes with Covalently Linked Porphyrin Antennae: Photoinduced Electron Transfer” J. Am. Chem. Soc. 2005127, 6916–6917.

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