99. S. Song, S. Wang, Z. Wang, H. Sun,* X. Wang,* C. Zhu* “Switchable Radical Polymerization of α-Olefins via Remote Hydrogen Atom or Group Transfer for Enhanced Battery Performance.” Angew. Chem. Int. Ed. 2024, e202418350.
https://doi.org/10.1002/anie.202418350
99. F. Chen, Z. Cao, C. Zhu* “Intramolecularly Remote Functional Group Migration Reactions Involving Free Radicals.” Chem. Commun., 2024, Advance Article.
https://doi.org/10.1039/D4CC05739B
99. Z. Cao,# Y. Xu,# Z. Wu,# X. Wu, C. Zhu* “Free Alcohol-Mediated Radical Alkynylation and Allylation of Unactivated C(sp3)-H Bonds.” Chem. Eur. J. 2024, e202403841.
https://doi.org/10.1002/chem.202403841
99. Z. Wang, Y. Chen, C. Zhu* “Radical Functionalization of 1,6-Diene via Transannular Cyano Migration: Synthesis of Polysubstituted Cyclopentanes.” Chin. J. Chem. 2025, 43, 437-442.
https://doi.org/10.1002/cjoc.202401072
99. Z. Cao, C. Zhu* “Intramolecular Alkene and Functional Group Translocation.” Nat. Chem. 2024, 16, 1576-1577.
https://doi.org/10.1038/s41557-024-01640-8
98. Y. Chen, Z. Cao, X. Wu, C. Zhu* “Docking-migration: a powerful tool for radical-mediated difunctionalization of alkenes.” SCIENTIA SINICA Chimica DOI: doi.org/10.1360/SSC-2022-0201
https://www.sciengine.com/SSC/doi/10.1360/SSC-2022-0201
97. Z. Ma, X. Wu C. Zhu* “Merging Fluorine Incorporation and Functional Group Migration.” Chem. Rec. 2022 DOI: doi.org/10.1002/tcr.202200221
https://onlinelibrary.wiley.com/doi/10.1002/tcr.202200221
96. Z. Cao, X. Wang, X. Wu, C. Zhu* “Iodobenzene-catalyzed photochemical heteroarylation of alcohols by rupture of inert C–H and C–C bonds.” Tetrahedron Chem. 2022, 4 DOI: https://doi.org/10.1016/j.tchem.2022.100031
https://www.tetrahedron-chem.com/article/S2666-951X(22)00027-4/fulltext
95. J. Yu, X. Zhang, X. Wu, T. Liu, Z. Zhang, J. Wu,* C. Zhu* “Metal-free radical difunctionalization of ethylene.” Chem. 2022 DOI: https://doi.org/10.1016/j.chempr.2022.10.020
https://www.cell.com/chem/fulltext/S2451-9294(22)00562-9
94. Y. Chen, X. Wu, Y. Shan, C. Zhu* “Asymmetric Radical Cyclization of Alkenes by Stereospecific Homolytic Substitution of Sulfinamides.” Angew. Chem. Int. Ed. 2022, e202201027
https://onlinelibrary.wiley.com/doi/10.1002/anie.202201027
93. Y. Wei, X. Wu, C. Zhu* “Radical Heteroarylation of Alkenes and Alkanes via Heteroaryl Migration.” (review) Synlett 2022, 33, 1017-1028
https://www.thieme-connect.de/products/ejournals/abstract/10.1055/a-1771-5037
92. X. Wang,# X. Shao,# Z. Cao, X. Wu, C. Zhu* “Metal-Free Photoinduced Deformylative Minisci-Type Reaction.” Adv. Synth. Catal. 2022, 364, 1200-1204.
https://onlinelibrary.wiley.com/doi/10.1002/adsc.202101447
91. T. Feng, C. Liu, Z. Wu, X. Wu,* C. Zhu* “Redox-Neutral Manganese-Catalyzed Synthesis of 1-Pyrrolines.” Chem. Sci. 2022, 13, 2669-2673.
https://pubs.rsc.org/en/Content/ArticleLanding/2022/SC/D2SC00015F
90. C. Chang, H. Zhang, X. Wu, C. Zhu* “Radical Trifunctionalization of Hexenenitrile by Remote Cyano Migration.” Chem. Commun. 2022, 58, 1005-1008.
https://pubs.rsc.org/en/content/articlehtml/2022/cc/d1cc06687k
89. B. Yue, X. Wu, C. Zhu* “Recent Advances in Vinyl Radical-Mediated Hydrogen Atom Transfer.” (review) Chin. J. Org. Chem. (有机化学) 2022, 42, 458-470.
http://sioc-journal.cn/Jwk_yjhx/EN/10.6023/cjoc202108027
88. X. Wu, Z. Ma, T. Feng, C. Zhu* “Radical-mediated rearrangements: past, present, and future” (review) Chem. Soc. Rev., 2021, 50, 11577-11613
https://pubs.rsc.org/en/content/articlelanding/2021/CS/D1CS00529D
87. Z. Cao, H. Zhang, X. Wu, Y. Li *, C. Zhu* “Radical heteroarylation of unactivated remote C(sp3)–H bonds via intramolecular heteroaryl migration” Org. Chem. Front., 2021, 8, 6395-6399.
https://pubs.rsc.org/en/Content/ArticleLanding/2021/QO/D1QO01209F#!divRelatedContent&articles
86. M. Ji, X. Wang, J. Liu, X. Wu, C. Zhu.* “Catalyst-free, radical-mediated intermolecular 1,2-arylheteroarylation of alkenes by cleaving inert C–C bond” Sci China Chem, 2021, 64: 1703–1708
https://link.springer.com/article/10.1007%2Fs11426-021-1077-4
85. M. Ji, C. Chang, X. Wu, C. Zhu.* “Photocatalytic intermolecular carboarylation of alkenes by selective C–O bond cleavage of diarylethers” Chem. Commun. 2021, 57, 9240-9243.
https://pubs.rsc.org/en/Content/ArticleLanding/2021/CC/D1CC04038C
84. Y. Wei, H. Zhang, X. Wu, C. Zhu.* “Alkene Difunctionalization Triggered by a Stabilized Allenyl Radical: Concomitant Installation of Two Unsaturated C-C Bonds” Angew. Chem. Int. Ed. 2021, 60, 20215–20219
https://onlinelibrary.wiley.com/doi/10.1002/anie.202106145
83. N. Tang, Y. Xu, T. Niu, S. Yang, H. Dong, X. Wu, C. Zhu.* “A Radical [3 + 2]-Cycloaddition Reaction for the Synthesis of Difluorocyclopentanones.” Org. Chem. Front. 2021, 8, 3118-3122.
https://pubs.rsc.org/en/content/articlelanding/2021/QO/D1QO00201E#!divAbstract
82. Y. Wei, Z. Chen, Z. Wu, Y. Xu, X. Wu, C. Zhu.* “Radical Carbosulfonylation of Propellane: Synthesis of Sulfonyl β-Ketobicyclo[1,1,1]pentanes.” Synthesis 2021, 53, 3325-3332.
https://www.thieme-connect.de/products/ejournals/abstract/10.1055/a-1484-1028
81. Z. Wang, C. Zhu* “Radical-Mediated 1,2-Brook Rearrangements.” (preview) Chem Catal. 2021, 1, 250-252.
https://www.sciencedirect.com/science/article/pii/S2667109321000270
80. J. Yu, H. Zhang, X. Wu, C. Zhu.* “Intermolecular Radical Fluoroalkylative Olefination of Unactivated Alkenes.” CCS Chem. 2021,3, 1426-1434.
https://www.chinesechemsoc.org/doi/10.31635/ccschem.021.202100944
79. Z. Wu, Y. Xu, H. Zhang, X. Wu, C. Zhu.* “Radical-Mediated Sulfonyl Alkynylation, Allylation, and Cyanation of Propellane.” Chem. Commun. 2021, 57, 6066-6069.
https://pubs.rsc.org/en/content/articlelanding/2021/CC/D1CC02249K#!divAbstract
78. H. Zhang, M. Wang, X. Wu, C. Zhu.* “Heterocyclization Reagents for Rapid Assembly of N-Fused Heteroarenes from Alkenes.” Angew. Chem. Int. Ed. 2021, 60, 3714-3719. (Highlighted by Synfacts 2021, 60, 3714)
https://onlinelibrary.wiley.com/doi/10.1002/anie.202013089
77. T. Niu, S. Yang, X. Wu, C. Zhu.* “Remote C(sp3)–H Vinylation via Radical-Mediated Consecutive Fission of C–H and C–C Bonds.” Org. Chem. Front. 2020, 7, 2981-2985.
https://pubs.rsc.org/en/content/articlelanding/2020/QO/D0QO00952K#!divAbstract
76. M. Ji, C. Zhu* “Iron-Catalyzed Fluoroalkylation of Arylborates with Sulfone Reagents: Beyond the Limitation of Reduction Potential.” Chin. J. Org. Chem. (有机化学) 2021, 41, 2914-2915.
http://sioc-journal.cn/Jwk_yjhx/EN/10.6023/cjoc202100049
75. Z. Wang, C. Zhu* “Electrochemical 1,2-Diarylation of Alkenes Enabled by Direct Dual C-H Functionalizations of Electron-Rich Aromatic Hydrocarbons.” Chin. J. Org. Chem. (有机化学) 2021, 41, 859-860.
http://sioc-journal.cn/Jwk_yjhx/EN/10.6023/cjoc202100010
74. C. Zhu,* X.-Y. Liu, “Cluster Preface: Radicals – by Young Chinese Organic Chemists.” (review) Synlett 2021, 32, 354-355.
https://www.thieme-connect.de/products/ejournals/abstract/10.1055/s-0040-1706715
73. H. Zhang, M. Ji, Y. Wei, H. Chen, X. Wu, C. Zhu.* “Radical-Mediated Hetaryl Functionalization of Nonactivated Alkenes through Distal ipso-Migration of O- or S-Hetaryls.” Synlett 2021, 32, 401-405.
https://www.thiemeconnect.de/products/ejournals/abstract/10.1055/s-0040-1705968
72. Y. Tang, C. Zhu* “Preface for Guo-Qiang Lin honour issue.” Tetrahedron 2021, 84, 132006.
https://www.sciencedirect.com/science/article/pii/S0040402021001058?via%3Dihub
71. Z. Wu, Y. Xu, X. Wu, C. Zhu.* “Synthesis of Selenoether and Thioether Functionalized Bicyclo[1.1.1]pentanes.” Tetrahedron 2020, 76, 131692.
https://www.sciencedirect.com/science/article/pii/S0040402020309054?via%3Dihub.
70. X. Shao, X. Wu, S. Wu, C. Zhu.* “Metal-Free Radical-Mediated C(sp3)-H Heteroarylation of Alkanes.” Org. Lett. 2020, 22, 7450-7454.
https://pubs.acs.org/doi/10.1021/acs.orglett.0c02475
69. C. Zhu. “Author Profile.” Angew. Chem. Int. Ed. 2020, 59, 21279.
https://onlinelibrary.wiley.com/doi/10.1002/anie.202010114
68. H. Zhang, L. Kou, D. Chen, M. Ji, X. Bao,* X. Wu, C. Zhu.* “Radical-Mediated Distal Ipso-Migration of O/S Containing Heteroaryls and DFT Studies for Migratory Aptitude.” Org. Lett. 2020, 22, 5947-5952.
https://pubs.acs.org/doi/10.1021/acs.orglett.0c02030
67. X. Wu, C. Zhu.* “Radical-Mediated Remote Functional Group Migration.” (review) Acc. Chem. Res. 2020, 53, 8, 1620-1636.
https://pubs.acs.org/doi/10.1021/acs.accounts.0c00306
66. H. Zhang, M. Wang, X. Wu, C. Zhu.* “Radical-Mediated Bromoalkylation of [1.1.1] Propellane: Synthesis of Bromo-substituted Bicyclo[1.1.1]pentane (BCP) De-rivatives.” Chin. J. Org. Chem. 2020, 40, 3431-3438.
http://sioc-journal.cn/Jwk_yjhx/CN/10.6023/cjoc202005001
65. Z. Wu, C. Zhu* “Synthesis of β-Difluoroalkyl Azides via 1,2-Azide Migration.” Chin. J. Org. Chem. (有机化学) 2020, 40, 808-809.
http://sioc-journal.cn/Jwk_yjhx/CN/10.6023/cjoc202000012
64. X. Wu, C. Zhu* “Radical Functionalization of Remote C(sp3)-H Bonds Mediated by Unprotected Alcohols and Amides.” (review) CCS Chem. 2020, 2, 813-828.
https://www.chinesechemsoc.org/doi/10.31635/ccschem.020.202000234
63. T. Niu, J. Liu, X.Wu, C. Zhu.* “Radical Heteroarylalkylation of Alkenes via Three‐Component Docking‐Migration Thioetheri-fication Cascade.” Chin. J. Chem. 2020, 38, 803-806.
https://onlinelibrary.wiley.com/doi/full/10.1002/cjoc.202000088
62. Z. Wu, Y. Xu, J. Liu, X. Wu, C. Zhu.* A “Practical Access to Fluoroalkylthio(seleno)Functionalizedbicyclo[1.1.1]pentanes.” Sci.China Chem. 2020, 63, 1025-1029.
https://link.springer.com/article/10.1007%2Fs11426-020-9733-y
61. J. Liu, S. Wu, J. Yu, C. Lu, Z. Wu, X. Wu, X.‐S. Xue, C. Zhu.* “Polarity Umpolung Strategy for the Radical Alkylation of Alkenes.” Angew. Chem. Int. Ed. 2020, 59, 8195-8202. (Highlighted by Chin. J. Org. Chem.)
https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201915837
60. M. Wang, M. Li, S. Yang, X.-S. Xue,* X. Wu, C. Zhu.* “Radical-Mediated C-C Cleavage of Unstrained Cycloketone and DFT Study for Unusual Regioselectivity.” Nat. Commun. 2020, 11, 672.
https://www.nature.com/articles/s41467-020-14435-5
59. J. Liu,# D. Chen,# M. Ji, X. Wu, C. Zhu* “Synthesis of γ-Lactams via Trifluoromethylative Aminocarbonylation of Unactivated Olefins.” Tetrahedron Lett. 2020, 61, 151479.
https://www.sciencedirect.com/science/article/pii/S004040391931278X?via%3Dihub
58. M. Wang, H. Zhang, J. Liu, X. Wu, C. Zhu.* “Radical Monofluoroalkylative Alkynylation of Olefins by Docking-Migration Strategy.” Angew. Chem. Int. Ed. 2019, 58, 17646-17650.
https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201910514
57. H. Zhang, X. Wu, Y. Wei, C. Zhu.* “Radical-Mediated Heck-Type Alkylation: Stereoconvergent Synthesis of Functionalized Polyenes.” Org. Lett. 2019, 21, 7568-7572.
https://pubs.acs.org/doi/10.1021/acs.orglett.9b02838
56. X. Wu, C. Zhu.* “Recent Advances in Alkoxy Radical-Promoted C-C and C-H Bond Functionalization Starting from Free Alcohols.” (review) Chem. Commun. 2019, 55, 9747-9756.
https://pubs.rsc.org/en/Content/ArticleLanding/2019/CC/C9CC04785A#!divAbstract
55. S. Wu, X. Wu, Z. Wu, C. Zhu.* “Regioselective Introduction of Vinyl Trifluoromethylthioether to Remote Unactivated C(sp3)-H Bonds via Radical Translocation Cascade.” Sci. China Chem. 2019, 62, 1507-1511.
https://link.springer.com/article/10.1007%2Fs11426-019-9527-5
54. D. Chen, M. Ji, C. Zhu.* “Intramolecular Nitration-Aminocarbonylation of Unactivated Olefins: Metal-Free Synthesis of γ-Lactams.” Chem. Commun. 2019, 55, 7796-7799.
https://pubs.rsc.org/en/content/articlelanding/2019/CC/C9CC03736E#!divAbstract
53. S. Yang, X. Wu, S. Wu, C. Zhu.* “Regioselective Sulfonylvinylation of the Unactivated C(sp3)–H Bond via a C-Centered Radical-Mediated Hydrogen Atom Transfer (HAT) Process.” Org. Lett. 2019, 21, 4837-4841.
https://pubs.acs.org/doi/10.1021/acs.orglett.9b01734
52. N. Tang, X. Wu, C. Zhu.* “Practical, Metal-Free Remote Heteroarylation of Amides via Unactivated C(sp3)-H Bond Functionalization.” Chem. Sci. 2019, 10, 6915-6919.
https://pubs.rsc.org/en/content/articlelanding/2019/SC/C9SC02564B#!divAbstract
51.C. Li, C. Zhu. “Organic Free Radical Chemistry.” Acta Chim. Sinica (化学学报) 2019, 77, 771-772.
http://sioc-journal.cn/Jwk_hxxb/CN/10.6023/A1909E001
50. N. Tang, X. Shao, M. Wang, X. Wu, C. Zhu.* “Sulfonyl Chlorides Mediated Alkynylation of Non-Activated Alkenes via Distal Alkynyl Group Migration.” Acta Chim. Sinica (化学学报) 2019, 77, 922-926.
http://sioc-journal.cn/Jwk_hxxb/CN/10.6023/A19050158
49. Y. Zhao, P. Wang, Y. Gao, C. Zhu,* W. Liu,* Y. Wang.* “Mechanistic Insights into Intermolecular Cyclization of Ring-Fused Benzocyclobutenols with Alkynes Catalyzed by [{Ir(OMe)COD}2].” Org. Chem. Front. 2019, 6, 791-795.
https://pubs.rsc.org/en/content/articlelanding/2019/QO/C8QO01371C#!divAbstract
48. M. Ji, Z. Wu, C. Zhu.* “Visible-Light-Induced Consecutive C-C Bond Fragmentation and Formation for the Synthesis of Elusive Unsymmetric 1,8-Dicarbonyl Compounds.” Chem. Commun. 2019, 55, 2368-2371.
https://pubs.rsc.org/en/content/articlelanding/2019/CC/C9CC00378A#!divAbstract
47. M. Wang, L. Huan, C. Zhu.* “Cyanohydrin-Mediated Cyanation of Remote Unactivated C(sp3)-H Bonds.” Org. Lett. 2019, 21, 821-825.
https://pubs.acs.org/doi/10.1021/acs.orglett.8b04104
46. S. Wu, X. Wu, D. Wang, C. Zhu.* “Regioselective Vinylation of Remote Unactivated C(sp3)-H Bonds: Access to Complex Fluoroalkylated Alkenes.” Angew. Chem. Int. Ed. 2019, 58, 1499-1503.
https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201812927
45. J. Yu, S. Yang, Z. Wu, C. Zhu.* “Annulation of Benzylic Alcohols with Alkynes for Rapid and Efficient Synthesis of Indenes and Spiroindenes.” Chin. J. Org. Chem.(有机化学) 2019, 39, 223-231.
http://www.ccspublishing.org.cn/article/doi/10.6023/cjoc201808009
44. X. Wu, C. Zhu.* “Recent Advances in Radical-Mediated C-C Bond Fragmentation of Non-Strained Molecules.” (review) Chin. J. Chem. 2019, 37, 171-182.
https://onlinelibrary.wiley.com/doi/abs/10.1002/cjoc.201800455
43. N. Tang, S. Yang, X. Wu, C. Zhu.* “Visible-Light-Induced Carbosulfonylation of Unactivated Alkenes via Remote Heteroaryl and Oximino Migration.” Tetrahedron 2019, 75, 1639-1646.
https://www.sciencedirect.com/science/article/pii/S0040402018314686?via%3Dihub
42. D. Chen, M. Ji, Y. Yao,* C. Zhu* “Difunctionalization of Unactivated Alkenes through SCF3 Radical-Triggered Distal Functional Group Migration.” Acta Chim. Sinica (化学学报) 2018, 76, 951-955.
http://sioc-journal.cn/Jwk_hxxb/CN/10.6023/A18080313
41. J. Yu, Z. Wu, C. Zhu.* “Efficient Docking–Migration Strategy for Selective Radical Difluoromethylation of Alkenes.” Angew. Chem. Int. Ed. 2018, 57, 17156-17160.
https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201811346
40. X. Wu, H. Zhang, N. Tang, Z. Wu, D. Wang, M. Ji, Y. Xu, M. Wang, C. Zhu.* “Metal-Free Alcohol-Directed Regioselective Heteroarylation of Remote Unactivated C(sp3)-H Bonds.” Nat. Commun. 2018, 9, 3343.
39. D. Chen, Z. Wu, Y. Yao,* C. Zhu.* “Phosphinoyl-Functionalization of Unactivated Alkenes through Phosphinoyl Radical-Triggered Distal Functional Group Migration.” Org. Chem.Front. 2018, 5, 2370-2374.
https://pubs.rsc.org/en/content/articlelanding/2018/QO/C8QO00558C#!divAbstract
38. D. Wang, J. Mao, C. Zhu.* “Visible Light-Promoted Ring-Opening Functionalization of Unstrained Cycloalkanols via Inert C-C Bond Scission.” Chem. Sci. 2018, 9, 5805-5809.
https://pubs.rsc.org/en/content/articlelanding/2018/SC/C8SC01763H#!divAbstract
37. M. Wang, Z. Wu, B. Zhang, C. Zhu.* “Azidoheteroarylation of Unactivated Olefins through Distal Heteroaryl Migration.” Org. Chem.Front. 2018, 5, 1896-1899.
https://pubs.rsc.org/en/content/articlelanding/2018/QO/C8QO00301G#!divAbstract
36. M. Ji, J. Yu, C. Zhu.* “Cyanotrifluoromethylthiolation of Unactivated Dialkyl-Substituted Alkynes via Cyano Migration: Synthesis of Trifluoromethylthiolated Acrylonitrile.” Chem. Commun. 2018, 54, 6812-6815.
https://pubs.rsc.org/en/content/articlelanding/2018/CC/C8CC01189C#!divAbstract
35. H. Zhang, X. Wu, Q. Zhao, C. Zhu.* “Copper-Catalyzed Heteroarylsilylation of Unactivated Olefins through Distal Heteroaryl Migration.” Chem. Asian J. 2018, 13, 2453-2457.
https://onlinelibrary.wiley.com/doi/full/10.1002/asia.201800150
34. X. Wu, S. Wu, C. Zhu.* “Radical-Mediated Difunctionalization of Unactivated Alkenes through Distal Migration of Functional Groups.” Tetrahedron Lett. 2018, 59, 1328-1336.
https://www.sciencedirect.com/science/article/pii/S0040403918302533?via%3Dihub
33. X. Wu, C. Zhu.* “Recent Advances in Ring-Opening Functionalization of Cycloalkanols by C-C σ-Bond Cleavage.” (review) Chem. Rec. 2018, 18, 587-598.
https://onlinelibrary.wiley.com/doi/full/10.1002/tcr.201700090
32. X. Wu, M. Wang, L. Huan, D. Wang, J. Wang, C. Zhu.* “Tertiary-Alcohol-Directed Functionalization of Remote C(sp3)-H Bonds by Sequential Hydrogen Atom and Heteroaryl Migrations.” Angew. Chem. Int. Ed. 2018, 57, 1640-1644.
https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201709025
31. J. Yu, D. Wang, Y. Xu, Z. Wu, C. Zhu.* “Distal Functional Group Migration for Visible-light Induced Carbo-difluoroalkylation/monofluoroalkylation of Unactivated Alkenes.” Adv. Synth. Catal. 2018, 360, 744-750.
https://onlinelibrary.wiley.com/doi/full/10.1002/adsc.201701229
30. W. Mao, C. Zhu.* “Rhodium-Catalyzed C-C Bond Olefination of Ring-Fused Benzocyclobutenols and Application in the Construction of Polycyclic Compounds.” Synlett. 2018, 29, 731-735.
https://www.thieme-connect.de/products/ejournals/abstract/10.1055/s-0036-1590830
29. R. Ren, Z. Wu, L. Huan, C. Zhu.* “Synergistic Strategies of Cyano Migration and Photocatalysis for Difunctionalization of Unactivated Alkenes: Synthesis of Di- and Mono-Fluorinated Alkyl Nitriles.” Adv. Synth. Catal. 2017, 359, 3052-3056.
https://onlinelibrary.wiley.com/doi/full/10.1002/adsc.201700591
28. W. Mao, C. Zhu.* “C-C Bond (Hetero)arylation of Ring-Fused Benzocyclobutenols and Application in the Assembly of Polycyclic Aromatic Hydrocarbons.” J. Org. Chem. 2017, 82, 9133-9143.
https://pubs.acs.org/doi/10.1021/acs.joc.7b01727
27. M. Ji, Z. Wu, J. Yu, X. Wan,* C. Zhu.* “Cyanotrifluoromethylthiolation of Unactivated Olefins through Intramolecular Cyano Migration.” Adv. Synth. Catal. 2017, 359, 1959-1962.
https://onlinelibrary.wiley.com/doi/full/10.1002/adsc.201700218
26. Y. Xu, Z. Wu, J. Jiang, Z. Ke, C. Zhu.* “Merging Distal Alkynyl Migration and Photoredox Catalysis for Radical Trifluoromethylative Alkynylation of Unactivated Olefins.” Angew. Chem. Int. Ed. 2017, 56, 4545-4548.
https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201700413
25. W. Mao, C. Zhu.* “Efficient Synthesis of Multiply Substituted Butenolides from Keto Acids and Terminal Alkynes Promoted by Combined Acids.” Org. Chem. Front. 2017, 4, 1029-1033.
https://pubs.rsc.org/en/content/articlelanding/2017/QO/C6QO00820H#!divAbstract
24. M. Wang, Z. Wu, C. Zhu.* “Ring-Opening Selenation of Cyclobutanols: Synthesis of γ-Selenylated Alkyl Ketones through C–C Bond Cleavage.” Org. Chem. Front. 2017, 4, 427-430.
https://pubs.rsc.org/en/content/articlelanding/2017/QO/C6QO00744A#!divAbstract
23. Z. Wu, D. Wang, Y. Liu, L. Huan, C. Zhu.* “Chemo- and Regioselective Distal Heteroaryl ipso-Migration: A General Protocol for Heteroarylation of Unactivated Alkenes.” J. Am. Chem. Soc. 2017, 139, 1388-1391.
https://pubs.acs.org/doi/10.1021/jacs.6b11234
22. H. Yan, C. Zhu.* “Recent Advances in Radical-Mediated Fluorination through C–H and C–C Bond Cleavage.” (review) Sci. China Chem. 2017, 60, 214-222.
https://link.springer.com/article/10.1007%2Fs11426-016-0399-5
21. L. Huan, C. Zhu.* “Manganese-Catalyzed Ring-Opening Chlorination of Cyclobutanols: Regiospecific Synthesis of γ-Chloroketones.” Org. Chem. Front. 2016, 3, 1467-1471.
https://pubs.rsc.org/en/content/articlelanding/2016/QO/C6QO00443A#!divAbstract
20. Z. Wu, R. Ren, C. Zhu.* “Combination of a Cyano Migration Strategy and Alkene Difunctionalization: The Elusive Selective Azidocyanation of Unactivated Olefins.” Angew. Chem. Int. Ed. 2016, 55, 10821-10824.
https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201605130
19. D. Wang, R. Ren, C. Zhu.* “Manganese-Promoted Ring-Opening Hydrazination of Cyclobutanols: Synthesis of Alkyl Hydrazines.” J. Org. Chem. 2016, 81, 8043-8049.
https://pubs.acs.org/doi/10.1021/acs.joc.6b01433
18. R. Ren, Z. Wu, C. Zhu.* “Manganese-Catalyzed Regiospecific sp3 C–S Bond Formation through C–C Bond Cleavage of Cyclobutanols.” Chem. Commun. 2016, 52, 8160-8163.
https://pubs.rsc.org/en/content/articlelanding/2016/CC/C6CC01843B#!divAbstract
17. W. Mao, C. Zhu.* “Synthesis of Highly Substituted γ-Hydroxybutenolides through the Annulation of Keto Acids with Alkynes and Subsequent Hydroxyl Transposition.” Chem. Commun. 2016, 52, 5269-5272.
https://pubs.rsc.org/en/content/articlelanding/2016/CC/C6CC01554A#!divAbstract
16. R. Ren, C. Zhu.* “Radical-Mediated Ring-Opening Functionalization of Cyclobutanols: A Shortcut to γ-Substituted Ketones.” (review) Synlett 2016, 27, 1139-1144.
https://www.thieme-connect.de/products/ejournals/abstract/10.1055/s-0035-1561351
15. R. Ren, Z. Wu, Y. Xu, C. Zhu.* “C-C Bond-Forming Strategy by Manganese-Catalyzed Oxidative Ring-Opening Cyanation and Ethynylation of Cyclobutanol Derivatives.” Angew. Chem. Int. Ed. 2016, 55, 2866-2869.
https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201510973
14. X. Fan, H. Zhao, J. Yu, X. Bao,* C. Zhu.* “Regiospecific Synthesis of Distally Chlorinated Ketones via C-C Bond Cleavage of Cycloalkanols.” Org. Chem. Front. 2016, 3, 227-232.
https://pubs.rsc.org/en/content/articlelanding/2016/QO/C5QO00368G#!divAbstract
13. H. Yan, C. Zhu.* “Ring Openings of tert-Cyclobutanols: New Strategy towards the Synthesis of γ-Substituted Ketones via C-C Bond Cleavage.” (review) Prog. Chem. (化学进展) 2016, 28, 1-8.
http://manu56.magtech.com.cn/progchem/CN/abstract/abstract11664.shtml
12. J. Yu, H. Yan, C. Zhu* “Synthesis of Multiply Substituted Polycyclic Aromatic Hydrocarbons by Iridium-Catalyzed Annulation of Ring-Fused Benzocyclobutenol with Alkyne through C-C Bond Cleavage.” Angew. Chem. Int. Ed. 2016, 55, 1143-1146.
https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201509973
11. X. Fan, H. Zhao, C. Zhu.* “Recent Advances in the Synthesis of Distal Fluorinated Ketones.” Acta Chim. Sinica (化学学报) (review) 2015, 73, 979-983.
http://sioc-journal.cn/Jwk_hxxb/CN/abstract/abstract345211.shtml
10. W. Mao, C. Zhu.* “Synergistic Acid-Promoted Synthesis of Highly Substituted Butenolides via the Annulation of Keto Acids and Tertiary Alcohols.” Org. Lett. 2015, 17, 5710-5713.
https://pubs.acs.org/doi/10.1021/acs.orglett.5b03026
9. R. Ren, H. Zhao, L. Huan, C. Zhu.* “Manganese-Catalyzed Oxidative Azidation of Cyclobutanols: Regiospecific Synthesis of Alkyl Azides by C-C Bond Cleavage.” Angew. Chem. Int. Ed. 2015, 54, 12692-12696.
https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201506578
8. J. Yu, H. Zhao, S. Liang, X. Bao,* C. Zhu.* “A Facile and Regioselective Synthesis of 1-Tetralones via Silver-Catalyzed Ring Expansion.” Org. Biomol. Chem. 2015, 13, 7924-7927.
https://pubs.rsc.org/en/content/articlelanding/2015/OB/C5OB01222H#!divAbstract
7. Z. Shen, Z. Xia, H. Zhao, J. Hu, X. Wan, Y. Lai,* C. Zhu,* W. Xie,* “Synthesis of Naked Amino-Pyrroloindoline via Direct Aminocyclization of Tryptamine.” Org. Biomol. Chem. 2015, 13, 5381-5384.
https://pubs.rsc.org/en/content/articlelanding/2015/OB/C5OB00546A#!divAbstract
6. D. Shi, H.-T. Qin, C. Zhu,* F. Liu.* “Selectfluor–Bu4NI-Mediated C(sp3)–H Oxidation in Aqueous Media: Synthesis of Δ2-Isoxazolines from Oximes.” Eur. J. Org. Chem. 2015, 5084-5088.
https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/ejoc.201500780
5. H. Zhao, X. Fan, J. Yu, C. Zhu.* “Silver-Catalyzed Ring-Opening Strategy for the Synthesis of β- and γ-Fluorinated Ketones.” J. Am. Chem. Soc. 2015, 137, 3490-3493.
https://pubs.acs.org/doi/10.1021/jacs.5b00939
4. C. Zhu, K. Saito, M. Yamanaka, T. Akiyama.* “Benzothiazoline: Versatile Hydrogen Donor for Organocatalytic Transfer Hydrogenation.” Acc. Chem. Res. 2015, 48, 388-398.
https://pubs.acs.org/doi/10.1021/ar500414x
3. K.-Y. Dong, H.-T. Qin, F. Liu,* C. Zhu.* “Oxime-Mediated Oxychlorination and Oxybromination of Unactivated Olefins.” Eur. J. Org. Chem. 2015, 1419-1422.
https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/ejoc.201403538
2. K.-Y. Dong, H.-T. Qin, X.-X. Bao, F. Liu,* C. Zhu.* “Oxime-Mediated Facile Access to 5-Methylisoxazoles and Applications in the Synthesis of Valdecoxib and Oxacillin.” Org. Lett. 2014, 16, 5266-5268.
https://pubs.acs.org/doi/10.1021/ol502246t
1. C. Zhu,* J. R. Falck. “Transition Metal-Free ipso-Functionalization of Arylboronic Acids and Derivatives.” Adv. Synth. Catal. 2014, 356, 2395-2410.
https://onlinelibrary.wiley.com/doi/full/10.1002/adsc.201400305
Before
22. J.-B. Xia, C. Zhu, C. Chen.* “Visible Light-Promoted Metal-Free sp3-C–H Fluorination.” Chem. Commun. 2014, 50, 11701-11704.
https://pubs.rsc.org/en/content/articlelanding/2014/CC/C4CC05650G
21. C. Zhu, J.-B. Xia, C. Chen.* “A Simple Method for the Electrophilic Cyanation of Secondary Amines.” Org. Lett. 2014, 16, 247-250.
https://pubs.acs.org/doi/10.1021/ol403245r
20. C. Zhu. J.-B. Xia, C. Chen.* “Vanadium-catalyzed Oxidative Strecker Reaction: α-C-H Cyanation of para-Methoxyphenyl (PMP)-protected Primary Amines.” Tetrahedron Lett. 2014, 55, 232-234.
https://www.sciencedirect.com/science/article/pii/S0040403913019485?via%3Dihub
19. J.-B. Xia, C. Zhu, C. Chen.* “Visible Light-Promoted Metal-Free C-H Activation: Diarylketone-Catalyzed Selective Benzylic Mono- and Difluorination.” J. Am. Chem. Soc. 2013, 135, 17494-17500.
https://pubs.acs.org/doi/10.1021/ja410815u
18. P. Bachu, C. Zhu, T. Akiyama.* “Molecular Iodine Catalyzed Transfer Hydrogenation: Reduction of Aldimines, Ketimines, and α-Imino Esters.” Tetrahedron Lett. 2013, 54, 3977-3981.
https://www.sciencedirect.com/science/article/pii/S0040403913008393?via%3Dihub
17. C. Zhu, G. Li, D. H. Ess, J. R. Falck, L. Kurti.* “Elusive Metal-Free Primary Amination of Arylboronic Acids: Synthetic Studies and Mechanism by Density Functional Theory.” J. Am. Chem. Soc. 2012, 134, 18253-18256. (Top 5 most read article in Nov. 2012; Highlighted in C& EN 2012, 90, 31; Highlighted in Angew. Chem. Int. Ed. 2013, 52, 5684; Highlighted by Organic Chemistry Portal)
https://pubs.acs.org/doi/10.1021/ja309637r
16. C. Zhu,* J. R. Falck. “Rhodium Catalyzed Synthesis of Isoindolinones via C-H Activation of N-Benzoylsulfonamides.” Tetrahedron 2012, 68, 9192-9199.
https://www.sciencedirect.com/science/article/pii/S0040402012013658?via%3Dihub
15. C. Zhu,* R. Wang, J. R. Falck. “Mild and Rapid Hydroxylation of Aryl/Heteroaryl Boronic Acids and Boronate Esters with N-Oxides.” Org. Lett. 2012, 14, 3494-3497. (Highlighted by Organic Chemistry Portal)
https://pubs.acs.org/doi/10.1021/ol301463c
14. C. Zhu,* R. Wang, J. R. Falck. “Amide-Directed Tandem C-C/C-N Bond Formation through C-H Activation.” Chem. Asian J. 2012, 7, 1502-1514. (Focus Review, invited)
https://onlinelibrary.wiley.com/doi/full/10.1002/asia.201200035
13. C. Zhu,* J. R. Falck. “Rhodium Catalyzed C-H Olefination of N-Benzoylsulfonamide with Internal Alkenes.” Chem. Commun. 2012, 48, 1674-1676. (Top 10 most accessed article in Dec. 2011)
https://pubs.rsc.org/en/content/articlelanding/2012/CC/C2CC16963K
12. C. Zhu, T. Akiyama.* “Transfer Hydrogenation of Imines with Carboxyl-tailed Benzothiazoline as Readily Removable Hydrogen Donor.” Tetrahedron Lett. 2012, 53, 416-418.
https://www.sciencedirect.com/science/article/pii/S0040403911020028?via%3Dihub
11. C. Zhu,* J. R. Falck. “Benzothiazoline: The Surrogate of Hantzsch Ester.” ChemCatChem 2011, 3, 1850-1851.
https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/cctc.201100241
10. C. Zhu,* W. Xie, J. R. Falck. “Rhodium-Catalyzed Annulation ofN-Benzoylsulfonamide with Isocyanide through C-H Activation.” Chem. Eur. J. 2011, 17, 12591-12595.
https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/chem.201102475
9. C. Zhu,* J. R. Falck. “Alternative Pathways for Heck Intermediates: Pd-catalyzed Oxy-arylation of Homoallylic Alcohols.” Angew. Chem. Int. Ed. 2011, 50, 6626-6629.
https://pubs.acs.org/doi/10.1021/ol200093f
8. C. Zhu,* J. R. Falck. “N-Acylsulfonamide Assisted Tandem C-H Olefination/ Annulation: Synthesis of Isoindolinones.” Org. Lett. 2011, 13, 1214-1217.
https://pubs.acs.org/doi/10.1021/ol200093f
7. C. Zhu, T. Akiyama.* “Brønsted Acid Catalyzed Reductive Amination with Benzothiazoline as a Highly Efficient Hydrogen Donor.” Synlett 2011, 1251-1254. (Cluster, Invited)
https://onlinelibrary.wiley.com/doi/abs/10.1002/chin.201146047
6. C. Zhu, T. Akiyama.* “Enantioselective Organocatalytic Transfer Hydrogenation of α-Imino Esters by Utilization of Benzothiazoline as Highly Efficient Reducing Agent.” Adv. Synth. Catal. 2010, 352, 1846-1850.
https://onlinelibrary.wiley.com/doi/full/10.1002/adsc.201000328
5. C. Zhu, T. Akiyama.* “One-Pot Tandem Approach for the Synthesis of Benzothiazoles from Benzyl Halides.” Synlett 2010, 2457-2460. (Highlighted by Organic Chemistry Portal)
https://www.thieme-connect.de/products/ejournals/abstract/10.1055/s-0030-1258046
4. W.-Y. Lu, X.-W. Sun, C. Zhu, J.-H. Xu, G.-Q. Lin.* “Expanding the application scope of glycosidases using click chemistry.” Tetrahedron 2010, 66, 750-757.
https://www.sciencedirect.com/science/article/pii/S0040402009017529?via%3Dihub
3. C. Zhu, T. Akiyama.* “Benzothiazoline: Highly Efficient Reducing Agent for the Enantioselective Organocatalytic Transfer Hydrogenation of Ketimines.” Org. Lett. 2009, 11, 4180-4183. (Highlighted by Synfacts 2009, 1282)
https://pubs.acs.org/doi/10.1021/ol901762g
2. C. Zhu, Y. Shi, M.-H. Xu, G.-Q. Lin.* “An Efficient and Versatile Approach for Optical Resolution of C2-Symmetric Axially Chiral Biaryl Dials. Synthesis of Enantiopure Biaryl-Derived Cyclic trans-1,2-Diols.” Org. Lett. 2008, 10, 1243-1246.
https://pubs.acs.org/doi/10.1021/ol800122x
1. T. Tang, C. Zhu, P.-Q. Huang.* “A Flexible Approach to (S)-3-Amino-2-Pyrrolidinone Derivatives.” Heterocycles, 2004, 64, 121-128.
https://www.heterocycles.jp/newlibrary/libraries/abst/01599
