成果及论文 - 前沿材料探索实验室

2019至2020年，连续两年郑永豪老师顺利完成的新生研讨课《新材料，新机遇》与研究生全英文课程《Organic Optoelectronics》，分别获评了5星与优秀。

2020级硕士毕业生赵海全同学获得国家级奖学金，并获得优秀毕业生称号。

2021年5月，王东升老师参加电子科技大学青教赛获得二等奖，同年三月，获得了电子科技大学光电科学与工程学院青教赛一等奖。

本科生薛国栋同学，2017年入学后不久，就进入了课题组学习，后以第一作者身份在《Chemical Communication》发表1篇论文，以共同作者身份在SCI一区期刊发表2篇论文，获得了成电杰出学生、国家奖学金、中国大学生自强之星奖学金、感恩中国近现代科学家奖学金等，目前即将前往北京大学继续他的科研道路。

2021年，张哲航等同学参加大学生创新创业比赛参与的《在空气中制备高性能全无机钙钛矿太阳能电池的研究》项目获得了校内优秀奖。

2021年4月，王东升老师指导组内研究生熊超越、毛礼俊、王真、熊晓瑜与本科生刘芷含、陈芝璇、卢伊杨、郑绮诗等同学设计了《基于水致变色材料制备的保密用“绿色”隐形墨水》，参加电子科技大学“挑战杯”大学生课外学术科技作品竞赛，荣获三等奖。

发表论文

2022

【63】.Xiong X., Sun, F., Gao A., Wang Z., Duan Y., Yao Z., He C., Han R., Deng X., Zheng Y., Wang D., Ester matters? Promoting photoisomerization of donor–acceptor Stenhouse adducts in the solid state and “burn after reading” encryption, CHEM ENG J, Volume 450, Part 2,2022,138090,

【62】.Wang K., Zhan Q., Han B., Sergio Moles Quintero. Huang W., Ji Y., Miao F., Chen H., Juan Casado., Zheng Y., The smallest oligothiophene diradicals by asymmetric substitution of quinoidal cores. J. Mater. Chem. C, 2022, Advance Article.

【61】. Sun, F., & Wang, D. . Toward real-world applications: promoting fast and efficient photoswitching in the solid state. J. Mater. Chem. C, 2022, Advance Article.

2021

【60】. Sun, F., Xiong X., Gao A., Duan Y., Mao L., Gu L., Wang Z., He C., Deng X., Zheng Y., Wang D., Fast photochromi sm in solid: Microenvironment in metal-organic frameworks promotes the isomerization of donor-acceptor Stenhouse adducts. Chem. Eng. J., Volume 427,2022,132037.

【59】. Xiong, C., Xue, G.; Mao, L.; Gu, L.; He, C.; Zheng, Y.; Wang, D., Carbon Spacer Strategy: Control the Photoswitching Behavior of Donor-acceptor Stenhouse Adducts. Langmuir 2021, 37, 802-809.

【58】. Shen, Y., Xue, G., Dai, Y. et al. Normal & reversed spin mobility in a diradical by electron-vibration coupling. Nat Commun 12, 6262 (2021).

【57】. Mao, L., Wang, Z., Duan, Y., Xiong, C., He, C., Deng, X., Zheng, Y., Wang, D., Designing of rewritable paper by hydrochromic donor-acceptor Stenhouse adducts. ACS Nano 2021, 15(6), 10384–10392. 2020.

【56】. Duan, Y., Zhao, H., Xiong, C., Mao, L., Wang, D. and Zheng, Y. (2021), Learning from Spiropyrans: How to Make Further Developments of Donor-Acceptor Stenhouse Adducts. Chin. J. Chem., 39: 985-998.

【55】. Miao, F. , H Chen, Quintero, S. M. , Xue, G. , Casado, J. , & Zheng, Y. . (2021). A nitrogen-doped asymmetric phenalenyl with a zwitterionic ground state. Chem. Commun., 2021,57, 8433-8436.

2020

【54】. Wang, Z., Gan, J., Liu, X., Shi, H., & Zheng, Y. (2020). Over 1 μm electron-hole diffusion lengths in cspbi2br for high efficient solar cells. J. Power Sources, Volume 454, 2020, 227913.

【53】. Zhao, H., Qin, X., Zhao, L., Dong, S., & Zheng, Y. (2020). Invisible inks for secrecy and anticounterfeiting: from single to double-encryption by hydrochromic molecules. ACS Appl. Mater. Interfaces 2020, 12, 7, 8952–8960.

【52】. Ji, Y., Long, L., & Zheng, Y. Recent advances of stable blatter radicals: synthesis, properties and applications. Materials Chemistry Frontiers. Mater. Chem. Front., 2020,4, 3433-3443.

【51】. Xue, G., Hu, X., Chen, H., Ge, L., Wang, W., & Xiong, J., et al. (2020). Understanding the nature of quinoidal and zwitterionic states in carbazole-based diradicals. Chem. Commun., 2020,56, 5143-5146.

【50】. Wang, Z., Wei, Q., Liu, X., Liu, L., Tang, X., Guo, J., Ren, S., Xing, G., Zhao, D., Zheng, Y., Spacer Cation Tuning Enables Vertically Oriented and Graded Quasi-2D Perovskites for Efficient Solar Cells. Adv. Funct. Mater. 2021, 31, 2008404.

【49】. Hu, X. , Chen, H., Xue, G., & Zheng, Y. (2020). Correlation between the strength of conjugation and spin–spin interactions in stable diradicaloids. J. Mater. Chem. C, 2020,8, 10749-10754.

【48】. Gu, L., Liu, X., Dong, S., Chen, Z., Han, R., & He, C., et al. (2020). Natural lignin nanoparticles: a promising nano-crosslinker for constructing fluorescent photoswitchable supramolecular hydrogels. Polym. Chem., 2020,11, 1871-1876.

【47】. Zhao, L., Liu, W., Yi, W., Hu, T., DalarKhodagholian, & FengLongGu, et al. Nano-makisu: highly anisotropic two-dimensional carbon allotropes made by weaving together nanotubes. Nanoscale, 2020,12, 347-355.

【46】. Wang, W., Ge, L., Xue, G., Miao, F., Chen, P., & Chen, H., et al. Fine-tune the diradical character of molecular systems via heteroatom effect. Chem. Commun., 2020,56, 1405-1408.

【45】. Yang, R., Yao, Y., Duan, Z., Yuan, Z., & Wang, D. (2020). Constructing electrically and mechanically self-healing elastomers by hydrogen bonded intermolecular network. Langmuir 2020, 36, 12, 3029–3037.

【44】. Lin, Y., Li, X., Liu, X., Liu, L., Wang, W., Wang, Z., Liao, Y., Tang, X., Zheng, Y.(2020). Quinonoid zwitterion: an amphiphilic cathode interlayer with initial thickness-insensitive and self-organizing properties for inverted polymer solar cells. ACS Appl. Mater. Interfaces 2020, 12, 3, 3792–3799.

2019

【43】. Hu, X., Chen, H., Zhao, L., Miao, M., & Zheng, Y. (2019). Observation of a solid-state-induced thermally populated spin-triplet state in radical regioisomers. Chem. Mater. 2019, 31, 24, 10256–10262.

【42】. Wang, D., Zhao, L., Zhao, H. et al. Inducing molecular isomerization assisted by water. Commun Chem 2, 118 (2019).

【41】. Dong, S., Sun, W., Wang, D., Zhao, H., Zu, G., Zheng, Y., Light-Switching Azo-Copolymers Self-Assembly in Multi-Stationary States. Macromol. Rapid Commun. 2019, 40, 1900058.

【40】. Hu, X., Chen, H., Zhao, L., Miao, M. S., Zheng, X., & Zheng, Y. (2019). Nitrogen-coupled blatter diradicals: the fused versus unfused bridges. J. Mater. Chem. C, 2019,7, 10460-10464.

【39】. Hu, X., Chen, H., Zhao, L., Miao, M., Han, J., & Wang, J., et al. (2019). Nitrogen analogues of chichibabin's and müller's hydrocarbons with small singlet–triplet energy gaps. Chem. Commun., 2019,55, 7812-7815.

【38】. Zhao, H., D Wang, Fan, Y., Ren, M., & Zheng, Y. (2018). Surface with reversible green-light-switched wettability by donor-acceptor stenhouse adducts. Langmuir 2018, 34, 50, 15537–15543.

【37】. Wang, Z., Liu, X., Lin, Y., Liao, Y., Qi, W., & Chen, H., et al. (2019). Hot-substrate deposition of all-inorganic perovskite films for low-temperature processed high-efficiency solar cells. J. Mater. Chem. A, 2019,7, 2773-2779.

【36】. Hu, X., Zhao, L., Chen, H., Ding, Y., Zheng, Y. Z., & Miao, M. S., et al. (2019). Air stable high-spin blatter diradicals: non-kekulé versus kekulé structures. J. Mater. Chem. C, 2019,7, 6559-6563.

2018

【35】. Wang, D.; Wang, Zhao W.; Wei, Q.; Zhao, C.; Zheng, Y. Photoswitchable Azobenzene/Cyclodextrin Host-Guest Complexes: From UV- to Visible/Near-IR-Light-Responsive Systems. ChemPhotoChem 2018, 2, 403.

【34】. Hu, X.; Wang, W.; Wang, D.; Zheng, Y. The electronic applications of stable diradicaloids: present and future. J. Mater. Chem. C 2018, 6, 11232– 11242,

【33】. Liu, X.; Lin, Y.; Liao, Y.; Wu, J.; Zheng, Y. Recent advances in organic near-infrared photodiodes. J. Mater. Chem. C 2018, 6, 3499– 3513.

【32】. Wu, J.; Li, X.; Liu, X.; Wu, S.; Lai, W.-Y.; Zheng, Y. Effects of Conjugated Bridges on the Photovoltaic Properties of Ortho-Functionalized Perylene Diimides for Non-Fullerene Polymer Solar Cells. J. Mater. Chem. C 2018, 6, 13171– 13178.

2017

【31】. Liu, X.; Guo, L.J. & Zheng, Y. 5-nm LiF as an Efficient Cathode Buffer Layer in Polymer Solar Cells Through Simply Introducing a C60 Interlayer. Nanoscale Res Lett 12, 543 (2017).

【30】. Liu, X.; Li, Y.; Huang, P.; Zhou, Y.; Jiang, Z., Song, B.; Li, Y.; Liao, L.; Zheng, Y. Highly efficient and thickness-tolerable bulk heterojunction polymer solar cells based on P3HT donor and a low-bandgap non-fullerene acceptor, J. Power Sources, Volume 364, 2017, Pages 426-431.

【29】. Li, X.; Wang, H.; Schneider, J. A.; Wei, Z.; Lai, W.-Y.; Huang, W.; Wudl, F.; Zheng, Y., Catalyst-free one-step synthesis of ortho-tetraaryl perylene diimides for efficient OPV non-fullerene acceptors. J. Mater. Chem. C 2017, 5 (11), 2781-2785.

【28】. Wang, D.; Wagner, M.; Saydjari, A. K.; Mueller, J.; Winzen, S.; Butt, H.-J.; Wu, S., A Photoresponsive Orthogonal Supramolecular Complex Based on Host–Guest Interactions. Chem. Eur. J. 2017, 23, 2628-2634.

2016

【27】. Wang, T.; Zheng, Y.; Raji, A. R.; Li, Y.; Sikkema, W. K.; Tour, J. M., Passive Anti-Icing and Active Deicing Films. ACS applied materials & interfaces 2016, 8, 14169-73.

【26】. Wang, D.; Wu, S., Red-Light-Responsive Supramolecular Valves for Photocontrolled Drug Release from Mesoporous Nanoparticles. Langmuir 2016, 32, 632-636.

【25】. Weis, P.; Wang, D.; Wu, S., Visible-Light-Responsive Azopolymers with Inhibited π–π Stacking Enable Fully Reversible Photopatterning. Macromolecules 2016, 49, 6368-6373.

【24】 . Liu, X.; Huang, P.; Dong, Q.; Wang, Z.; Zhang, K.; Yu, H.; Lei, M.; Zhou, Y.; Song, B.; Li, Y., Enhancement of the efficiency and stability of planar p-i-n perovskite solar cells via incorporation of an amine-modified fullerene derivative as a cathode buffer layer. Science China Chemistry 2016, 60, 136-143.

【23】. Li, Y.; Liu, X.; Wu, F.-P.; Zhou, Y.; Jiang, Z.-Q.; Song, B.; Xia, Y.; Zhang, Z.-G.; Gao, F.; Inganäs, O.; Li, Y.; Liao, L.-S., Non-fullerene acceptor with low energy loss and high external quantum efficiency: towards high performance polymer solar cells. J. Mater. Chem. A 2016, 4, 5890-5897.

2015

【22】. Zhou, Y.; Wang, D.; Huang, S.; Auernhammer, G.; He, Y.; Butt, H.-J.; Wu, S., Reversible Janus particle assembly via responsive host–guest interactions. Chem. Commun. 2015, 51, 2725-2727.

【21】. Zheng, Y.; Miao, M.-s.; Dantelle, G.; Eisenmenger, N. D.; Wu, G.; Yavuz, I.; Chabinyc, M. L.; Houk, K. N.; Wudl, F., A Solid-State Effect Responsible for an Organic Quintet State at Room Temperature and Ambient Pressure. Advanced materials 2015, 27, 1718-1723.

【20】. Zhang, Y.; Zheng, Y.; Zhou, H.; Miao, M. S.; Wudl, F.; Nguyen, T. Q., Temperature Tunable Self-Doping in Stable Diradicaloid Thin-Film Devices. Advanced materials 2015, 27, 7412-7419.

【19】. Wang, D.; Wagner, M.; Butt, H. J.; Wu, S., Supramolecular hydrogels constructed by red-light-responsive host-guest interactions for photo-controlled protein release in deep tissue. Soft Matter 2015, 11, 7656-62.

【18】. Liu, X.; Yu, H.; Yan, L.; Dong, Q.; Wan, Q.; Zhou, Y.; Song, B.; Li, Y., Triple cathode buffer layers composed of PCBM, C60, and LiF for high-performance planar perovskite solar cells. ACS applied materials & interfaces 2015, 7, 6230-6237.

【17】. Liu, X.; Lei, M.; Zhou, Y.; Song, B.; Li, Y., High performance planar p-i-n perovskite solar cells with crown-ether functionalized fullerene and LiF as double cathode buffer layers. Applied Physics Letters 2015, 107, 063901.

【16】. Liu, X.; Jiao, W.; Lei, M.; Zhou, Y.; Song, B.; Li, Y., Crown-ether functionalized fullerene as a solution-processable cathode buffer layer for high performance perovskite and polymer solar cells. J. Mater. Chem. A 2015, 3, 9278-9284.

2014

【15】. Zheng, Y.; Wudl, F., Organic spin transporting materials: present and future. J. Mater. Chem. A 2014, 2, 48-57.

【14】. Zheng, Y.; Miao, M. S.; Zhang, Y.; Nguyen, T. Q.; Wudl, F., Striking effect of intra- versus intermolecular hydrogen bonding on zwitterions: physical and electronic properties. J Am Chem Soc 2014, 136, 11614-11617.

【13】. Zheng, Y.; Miao, M.-s.; Kemei, M. C.; Seshadri, R.; Wudl, F., The Pyreno-Triazinyl Radical – Magnetic and Sensor Properties. Isr. J. Chem. 2014, 54, 774-778.

【12】. Zheng, Y.; Batsanov, A. S.; Fox, M. A.; Al-Attar, H. A.; Abdullah, K.; Jankus, V.; Bryce, M. R.; Monkman, A. P., Bimetallic Cyclometalated Iridium(III) Diastereomers with Non Innocent Bridging Ligands for High-Efficiency Phosphorescent OLEDs. Angew Chem 2014, 126, 11800-11803.

2013

【11】. Dou, L.; Zheng, Y.; Shen, X.; Wu, G.; Fields, K.; Hsu, W.-C.; Zhou, H.; Yang, Y.; Wudl, F., Single-Crystal Linear Polymers Through Visible Light–Triggered Topochemical Quantitative Polymerization. Science 2014, 343, 272-277.

【10】. Wang, D.; Xie, D.; Shi, W.; Sun, S.; Zhao, C., Designing a photoresponsive molecularly imprinted system on a silicon wafer substrate surface. Langmuir 2013, 29, 8311-9.

【9】. Liu, X.; Lee, J. Y.; Guo, L. J., Efficiency and stability enhancement of polymer solar cells using multi-stacks of C60/LiF as cathode buffer layer. Organic Electronics 2013, 14, 469-474.

【8】. Liu, X.; Kim, H.; Guo, L. J., Optimization of thermally reduced graphene oxide for an efficient hole transport layer in polymer solar cells. Organic Electronics 2013, 14, 591-598.

【7】. Kozhevnikov, V. N.; Zheng, Y.; Clough, M.; Al-Attar, H. A.; Griffiths, G. C.; Abdullah, K.; Raisys, S.; Jankus, V.; Bryce, M. R.; Monkman, A. P., Cyclometalated Ir(III) Complexes for High-Efficiency Solution-Processable Blue PhOLEDs. Chemistry of Materials 2013, 25, 2352-2358.

2012

【6】. Zheng, Y.; Batsanov, A. S.; Edkins, R. M.; Beeby, A.; Bryce, M. R., Thermally Induced Defluorination during amertofacTransformation of a Blue-Green Phosphorescent Cyclometalated Iridium(III) Complex. Inorganic Chemistry 2012, 51, 290-297.

【5】. Wang, D.; Zhang, X.; Nie, S.; Zhao, W.; Lu, Y.; Sun, S.; Zhao, C., Photoresponsive surface molecularly imprinted poly(ether sulfone) microfibers. Langmuir 2012, 28, 13284-13293.

2011

【4】. Zheng, Y.; Batsanov, A. S.; Jankus, V.; Dias, F. B.; Bryce, M. R.; Monkman, A. P., Bipolar Molecules with High Triplet Energies: Synthesis, Photophysical, and Structural Properties. The Journal of Organic Chemistry 2011, 76, 8300-8310.

【3】. Zheng, Y.; Batsanov, A. S.; Bryce, M. R., Unusual dinuclear and mononuclear cyclometalated iridium complexes of 2,5-diaryl-1,3,4-oxadiazole derivatives. Inorg Chem 2011, 50, 3354-3362.

【2】. Wang, D.; Zou, W.; Li, L.; Wei, Q.; Sun, S.; Zhao, C., Preparation and characterization of functional carboxylic polyethersulfone membrane. Journal of Membrane Science 2011, 374, 93-101.

2009

【1】. Wang, D.; Wei, Q.; Zhang, Y.; Zhao, C., Molecularly imprinted polyethersulfone microfibers for the binding and recognition of bisphenol A. Journal of Applied Polymer Science 2009, 114, 4036-4041.

授权专利

【1】一种含自由基的吡咯并吡咯类有机半导体材料、制备方法及其应用

【2】一种阴极修饰层材料及其制备方法以及太阳能电池及其制备方法

【3】有机酸和/或醇在制备太阳能电池界面调控剂中的应用、太阳能电池及制备方法

【4】一种共轭双自由基分子及其制备、自旋分布调控方法和应用

【5】一种具有可调控单分子电学特性大偶极矩有机内盐分子及其电导调控方法