主要学术成绩
(1) 首次采用“固体润滑”方式解决了摩擦电材料易磨损问题,为高电荷密度、耐磨损摩擦电材料的设计提供了新思路;
(2) 采用自组装法在摩擦电材料表面引入功能基团提高了材料表面电荷密度和疏水性,首次设计了基于超疏水表面的可持续收集 360º 平面范围内风能的高效、超稳定的TENG,有效提高了器件输出性能和抗湿性,对 TENG 在高湿度环境下高效收集风能提供了可行方案;
(3) 基于二维纳米材料的压电及润滑特性,设计了具有高摩擦电荷密度、低摩擦系数、低磨损率的新型复合摩擦电材料,为高性能、长寿命 TENG 的开发提供了材料保障;
(4) 研发了基于摩擦起电效应的自充电锂离子电池、具有杀菌功能的自充电超级电容器,为基于能量收集-存储一体化器件设计提供了新方法,且多个能量存储单元在高效收集机械能的同时可为微电子器件供电, 保证了微电子器件的连续运行。 对基于 TENG 的集成化多功能量收集器件的设计提供了参考,为自驱动微电子系统提供了新型能量解决方案;
(5) 设计了植入固态锂离子电池的可穿戴 TENG、基于TENG-全固态锂离子电池的自驱动能源系统、可将其放置在鞋底收集人体运动的机械能并为可穿戴电子器件供电,具有集成度高、体积小、成本低的特点;
(6) 开发了基于多效应耦合的铁电陶瓷基自驱动智能传感系统并揭示了耦合机理。 在一个器件上实现了热能、光能和机械能的同时收集,显著提了器件输出性能,为复合纳米发电机的设计提供了参考,成功实现了光、热、力物理信号的相互调控,并为多效耦合自驱动传感器系统的开发提供了理论依据;
(7) 设计了柔性多功能摩擦电材料,构建了集成化、轻量化、高性能的摩擦-电磁复合纳米发电机,并开展了其在智能农业、自驱动微电子器件中的应用;
(8) 开展了 TENG 及复合纳米发电机在无线温度传感器、土壤温湿度传感器、电子表、 LED、pH计、水质仪、智能环境传感器、节能灯、铁电材料极化、染料降解、光电探测、人体运动状态、脉搏监测等方面的应用研究,为纳米发机的实际应用提供了参考。
代表性论文
[28] Kun Zhao*, Jiabei Zhang, Jiahao Zhou, Yuan Ye, Junhui Wu, Ming Zhong, Cheng Meng, Bing Zhang. High Surface Charge Density Bi2Ti2O7/PVC Triboelectric Composite Film-Based Highly-Efficient Metal Corrosion Prevention System.
[27] Yuan Ye, Jiahao Zhou, Jiabei Zhang, Chaohui Zhang, Yong Ding, Zhaofeng Wang, Junhong Guo*, Kun Zhao*. Mechanoluminescence ZnS/CaZnOS:Mn2+/PVC Composites-Based Triboelectric Nanogenerator for Rotational Energy Harvesting and Intelligent Sensing.
[26] Kun Zhao*, Jiahao Zhou, Zongqiang Gao, Jiabei Zhang, Yuan Ye, Cheng Meng, Bing Zhang*. High Surface Charge Density and Excellent Wear Resistance of MoS2 Nanosheets Doped PDMS Composite Based Triboelectric Nanogenerator for Energy Harvesting and Body Motion Sensing. (Submitted)
[25] Kun Zhao*, Jingke Meng, Ming Zhong, Zongqiang Gao, Yujia Liu, Hongjie Liu, Yu-Lun Chueh*. Triboelectric Nanogenerator Tntegrated with Ultra-Stable All-Solid-State Lithium-Ion Battery for Rotational Mechanical Energy Harvesting and Storage. (Submitted)
[24] Kun Zhao*, Zongqiang Gao, Jiahao Zhou, Yuan Ye, Jiabei Zhang, Chaohui Zhang, Bin Zhang*, Cheng Meng*. High-Performance and Ultra-Robust Triboelectric Nanogenerator with hBN Nanosheets/PVDF Composite Membranes for Scavenging Wind Energy. (Under Review)
[23] Kun Zhao*, Zhenhua Song, Wanru Sun, Wei Gao, Junhong Guo*, Kewei Zhang*. Flexible Neodymium Iron Boron/ Polyvinylchloride (Nd2Fe14B/PVC) Composite Film Based Hybrid Nanogenerator for Efficient Mechanical Energy Harvesting. Energy 2024, 300, 131656. (IF: 9.0, 中科院一区TOP)https://doi.org/10.1016/j.energy.2024.131656
[22] Kun Zhao*, Zhenhua Song, Zongqiang Gao, Wei Gao,Ming-Jin Liu, Bingni Gu, Junhong Guo*, Yu-Lun Chueh*. High-Performance Triboelectric–Electromagnetic Hybrid Nanogenerator using Dual-Functional Flexible Neodymium Iron Boron/Ethyl Cellulose (NdFeB/EC) Composite Films for Wind Energy Scavenging. Chem. Eng. J. 2024, 489, 150763. (IF: 15.1)https://doi.org/10.1016/j.cej.2024.150763
[21] Kun Zhao*, Zongqiang Gao, Jiabei Zhang, Jiahao Zhou, Faqi Zhan, Li Qiang, Ming-Jin Liu, Ruei-Hong Cyu, Yu-Lun Chueh*. Design of Strong-Performance, High-Heat Dissipation Rate, and Long-Lifetime Triboelectric Nanogenerator Based on Robust Hexagonal Boron Nitride (hBN) Nanosheets/Polyvinyl Chloride (PVC) Composite Films for Rotational Energy Harvesting. J. Power Sources 2024, 614, 234997.(IF: 9.2)https://doi.org/10.1016/j.jpowsour.2024.234997
[20] Jingke Meng, Cheng Meng*, Zongqiang Gao, Faqi Zhan, Zhijun Teng, Kun Zhao*. Triboelectric Nanogenerator Based on Polyvinyl Chloride Membranes Doped with Zirconium Carbide@Zirconia Core-Shell Nanoparticles. ACS Appl. Nano Mater. 2024, 7, 18841-18850. https://doi.org/10.1021/acsanm.4c02431
[19] Cheng Meng, Weihui Shu, Kun Zhao*,Chunpei Yan, Zuojia Li, Qianglin Wei, Minjia Wang, Yunhai Liu, Zhibin Zhang*. Modeling Uranyl Adsorption on MoS2/Mo2CTx Heterostructures Using DFT and BOMD Methods. Inorg. Chem. 2023, 62, 8969-8979.https://doi.org/10.1021/acs.inorgchem.3c00625
[18] Kun Zhao*, Hui Zhang, Jingke Meng, Chia-Chen Chung, Bing-Ni Gu, Ming-Jin Liu, Ding Zhang, Ming Zhong, Maocheng Liu, Na Liu, Chun-Jung Lin, Cheng Meng*, Yu-Lun Chueh*. Design of Self-Powered Sensors with Excellent Thermal and Ultraviolet (UV) Light Detection Based on 0.94(Bi0.5Na0.5)TiO3-0.06Ba(Zr0.25Ti0.75)O3 (BNT-BZT) Nanoparticles. Adv. Funct. Mater. 2022, 32, 2204234. (IF: 19.924) https://doi.org/10.1002/adfm.202204234
[17] Kun Zhao*, Jingke Meng, Ming Zhong, Suixin Li, Yunxia Niu, Hongjie Liu, Bing-Ni Gu, Ming-Jin Liu, Ding zhang, Lingbin Kong*, Yu-Lun Chueh*. Design of Self-powered System by Wind-Driven Triboelectric Nanogenerator Based on 0.94(Bi0.5Na0.5)TiO3-0.06Ba(Zr0.25Ti0.75)O3/ Polyvinylidene Fluoride (BNT-BZT/PVDF) Composites. Small 2022, 18, 2202792. (IF: 15.153) https://doi.org/10.1002/smll.202202792
[16] Kun Zhao*, Wanru Sun, Xueting Zhang, Jingke Meng, Ming Zhong, Li Qiang, Ming-Jin Liu, Bing-Ni Gu, Chia-Chen Chung, Maocheng Liu, Fucheng Yu*, Yu-Lun Chueh*. High-Performance and Long-cycle Life of Triboelectric Nanogenerator Using PVC/MoS2 Composite Membranes for Wind Energy Scavenging Application. Nano Energy 2022, 91, 106649. (IF: 19.069)https://doi.org/10.1016/j.nanoen.2021.106649
[15] Kun Zhao, Ya Yang*, Xi Liu, Zhong Lin Wang*. Triboelectrification-Enabled Self-Charging Lithium-Ion Batteries. Adv. Energy Mater. 2017, 1700103. (IF: 29.698) https://doi.org/10.1002/aenm.201700103
[14] Kun Zhao, Bangsen Ouyang, Chris R. Bowen, Zhong Lin Wang*, Ya Yang*. One-Structure-Based Multi-Effects Coupled Nanogenerators for Self-Powered Multi-Functions Coupled Sensor System. Nano Energy 2020, 71: 104632. (IF:19.069) https://doi.org/10.1016/j.nanoen.2020.104632
[13] Kun Zhao, Bangsen Ouyang, Chris R. Bowen, Ya Yang*. Enhanced Photocurrent via Ferro-Pyro-Phototronic Effect in Ferroelectric BaTiO3 Materials for a Self-Powered Flexible Photodetector System. Nano Energy 2020, 78: 105152.(IF: 19.069)https://doi.org/10.1016/j.nanoen.2020.105152
[12] Kun Zhao#, Qingqing Qin#, Haifeng Wang#, Ya Yang*, Jian Yan*, Xingmao Jiang*. Antibacterial Triboelectric Membrane-Based Highly-Efficient Self-Charging Supercapacitors. Nano Energy 2017, 36: 30-37.(IF: 19.069) https://doi.org/10.1016/j.nanoen.2017.04.029
[11] Kun Zhao, Zhong Lin Wang, Ya Yang*. Self-Powered Wireless Smart Sensor Node Enabled by an Ultrastable, Highly Efficient, and Superhydrophobic-Surface-Based Triboelectric Nanogenerator. ACS Nano 2016, 10: 9044-9052. (IF: 18.027) https://doi.org/10.1021/acsnano.6b05815
[10] Kun Zhao, Yuanhao Wang*, Lu Han, Yongfei Wang, Xudong Luo, Zhiqiang Zhang*, Ya Yang*. Nanogenerator‑Based Self‑Charging Energy Storage Devices. Nano-Micro Lett. 2019, 11(1): 19.(IF: 23.655) https://doi.org/10.1007/s40820‑019‑0251‑7
[9] Kun Zhao, Xue Wang, Ya Yang*. Ultra-Stable Electret Nanogenerator to Scavenge High-Speed Rotational Energy for Self-Powered Electronics. Adv. Mater. Technol. 2017, 2, 1600233. (IF: 8.856) https://doi.org/10.1002/admt.201600233
[8] Kun Zhao, Bangsen Ouyang, Ya Yang*. Enhancing Photocurrent of Radially Polarized Ferroelectric BaTiO3 Materials by Ferro-Pyro-Phototronic Effect. iScience 2018, 3: 208-216. (IF: 6.107) https://doi.org/10.1016/j.isci.2018.04.016
[7] Tiantian Gao#, Kun Zhao#, Xi Liu, Ya Yang*. Implanting a Solid Li-ion Battery into a Triboelectric Nanogenerator for Simultaneously Scavenging and Storing Wind Energy. Nano Energy 2017, 41: 210-216. (IF: 19.069)(共同第一) https://doi.org/10.1016/j.nanoen.2017.09.037
[6] Xi Liu, Kun Zhao, Zhong Lin Wang, Ya Yang*. Unity Convoluted Design of Solid Li-Ion Battery and Triboelectric Nanogenerator for Self-Powered Wearable Electronics. Adv. Energy Mater. 2017, 1701029.(IF:29.698) https://doi.org/10.1002/aenm.201701629
[5] Xi Liu, Kun Zhao, Ya Yang*. Effective Polarization of Ferroelectric Materials by Using a Triboelectric Nanogenerator to Scavenge Wind Energy. Nano Energy 2018, 53: 622-629.(IF: 19.069) https://doi.org/10.1016/j.nanoen.2018.09.026
[4] Weiqi Qian, Kun Zhao, Ding Zhang, Chris R. Bowen, Yuanhao Wang*,Ya Yang*. Piezoelectric Material-Polymer Composite Porous Foam for Efficient Dye Degradation via the Piezo-Catalytic Effect. ACS Appl. Mater. Interfaces 2019, 11: 27862-27869. (IF: 10.383) https://doi.org/10.1021/acsami.9b07857
[3] Kun Zhao*, Haoran Lv, Jingke Meng, Zhenhua Song, Cheng Meng, Maocheng Liu*, Ding Zhang*. Triboelectrification-Induced Electricity in Self-Healing Hydrogel for Mechanical Energy Harvesting and Ultra-sensitive Pressure Monitoring. ACS Omega 2022, 7: 18816-18825. https://doi.org/10.1021/acsomega.2c01743
[2] Kun Zhao*, Xueting Zhang, Haoran Lv, Wanru Sun, Ming Zhong, Maocheng Liu, Hongjie Liu*, Ding Zhang*. Boosting Performance of Triboelectric Nanogenerator via Polydimethylsiloxane Modified with Perovskite BiFeO3Nanoparticles. Mater. Technol. 2022, 37, 14: 3212-3221. https://doi.org/10.1080/10667857.2022.2138804
[1] Kun Zhao*, Wanru Sun, Suixin Li, Zhenhua Song, Ming Zhong, Ding Zhang, Bing-Ni Gu, Ming-Jin Liu, Hao Fu, Hongjie Liu, Cheng Meng, Yu-Lun Chueh*. Rational Design on High-Performance Triboelectric Nanogenerator Consisting of Silicon Carbide@Silicon Dioxide Nanowhiskers/ Polydimethylsiloxane (SiC@SiO2/PDMS) Nanocomposite Films. Discover Nano 2023, 18: 69. https://doi.org/10.1186/s11671-023-03822-8