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成果及论文

独立工作后发表学术论文(至202403月)

[1]     Ruiqing Wang, Lingkai Kong, Xinyu Zong, Minghui Zhang, Wenyi Chen, Yaxin Liu, Lingjuan Ma*, Yulei Zhao*, Diazenylation of active methyne compounds via arylazo sulfones, Org. Chem. Front. 2024, 11, 2815-2820. (中科院SCI一区)

Highlighted by: Frontiers Journals: https://mp.weixin.qq.com/s/cz-4vi8_cj0X0QAssVKkWA 

[2]     Yuhang Fan, Zhanshuo Zhang, Yulei Zhao,* Self-detachable protecting group function of CO2 in the electrochemical reduction of aryl azides, Org. Chem. Front. 2024, 11, 1184-1191. (中科院SCI一区)

[3]     Yuhang Fan, Chao Chen, Zhanshuo Zhang, Xiaohan Meng, Xiaonuo Liu, Jun Cao, Yuan-Ye Jiang,* Yulei Zhao,* CO2 Transient Promotion Function Enabled the Selective Electrochemical Transformation of Imines, Org. Lett. 2023, 25, 9202–9206. (中科院SCI一区)

[4]     Xiaotong Dong, Xiaonuo Liu, Lei Wang, Yixuan Zhang, Jiale Li, Laijin Tian, Yulei Zhao,* Catalyst-Free gem-Difluorination/Spirocyclization of Indole-2-carboxamides: Synthesis of C2-Spiroindoline Derivatives, Org. Lett. 2023, 25, 8771–8776. (中科院SCI一区)

[5]     Yulei Zhao,* Shuai Li, Yuhang Fan, Jun Cao, Xiaotong Dong, Ruiqing Wang, Laijin Tian, Csp3–H Imination Using Arylazo Sulfone as a N Source: An Approach to Access Imines, Org. Lett. 2023, 25, 5911-5915. (中科院SCI一区)

Highlighted by: CBG资讯人物与科研栏目:https://mp.weixin.qq.com/s/q1IuasuuJI_jGVlSINyJDw

[6]     Yulei Zhao,* Shuai Li, Yuhang Fan, Chao Chen, Xiaotong Dong, Ruiqing Wang, Yuan-Ye Jiang,* Mild diazenylation of Csp2-H and Csp3-H bond via arylazo sulfones, Org. Chem. Front. 2023, 10, 5923-5932. (中科院SCI一区)

[7]     Yulei Zhao*, Xuqiang Guo, Shuai Li, Yuhang Fan, Guo-Cui Ji, Mengmeng Jiang, Yin Yang, Yuan-Ye Jiang*, Transient Stabilization Effect of CO2 in the Electrochemical Hydrogenation of Azo Compounds and the Reductive Coupling of α-Ketoesters, Angew. Chem. Int. Ed. 2022, 61, e202213636. (中科院SCI一区) (感谢蒋原野副教授(共同通讯作者)和研究生纪国翠提供的计算支持!感谢南开大学杨茵博士提供的EPR支持!感谢课题组硕士生郭旭强、李帅、范宇航和本科生蒋蒙蒙在实验方面的辛苦付出!)

Highlighted by:

CBG资讯人物与科研栏目:https://www.chembeango.com/zixun/57304c5

研之成理:https://mp.weixin.qq.com/s/-QO53jQy8UcswvhXA8hx2w

《化学与材料科学》:https://mp.weixin.qq.com/s/fAb9Q7jCY9_33-aV2r6xeQ

WileyChemhttps://mp.weixin.qq.com/s/g3FIWAtGQ5CsP8nSc7jfaw

《大众日报》:http://dzrb.dzng.com/articleContent/37_1068580.html

和曲阜师范大学主页:https://www.qfnu.edu.cn/info/1383/45436.htm等网络平台。

[8]     Yulei Zhao*, Huimin Wang, Xin Kang, Ruihua Zhang, Nan Feng, Qi Su, Controllable Methylenation with Ethylene Glycol as Methylene Source: Bridging Enaminones and Synthesis of Tetrahydropyrimidines, Org. Chem. Front. 2022, 9, 5935-5941. (中科院SCI一区)

[9]     Yulei Zhao*, Yuhang Fan, Xiaohan Meng, Xin Kang, Zhongyin Ji, Shina Yan, Laijin Tian, Electrochemical Cyclization of Alkynyl Enaminones: Controllable Synthesis of Indeno[1,2-c]pyrroles or Indanones, J. Org. Chem. 2022, 87, 11131-11140. (中科院SCI二区, TOP期刊)

[10] Yulei Zhao*, Shuai Li, Yuhang Fan, Huimin Wang, Xin Kang, Zhongyin Ji, Laijin Tian, Synthesis of Polycyclic 3,3ʹ-Biindoles via AgOTf-Catalyzed Nucleophilic Addition and Cycloisomerization, J. Org. Chem. 2022, 87, 6418-6425. (中科院SCI二区, TOP期刊)

[11] Yulei Zhao*, Shuai Li, Jinjie Cui, Huimin Wang, Xin Kang, Yan Wang, Laijin Tian, Selectfluor-Mediated Oxidative Dehydrogenation of Hydrazines: A Process for the Synthesis of Azo Compounds, Synthesis-Stuttgart 2022, 54, 5245-5252.(被选为封面文章,中科院SCI四区)

[12] Xuqiang Guo, Xuejun Sun, Mengmeng Jiang, Yulei Zhao*, Switchable Synthesis of Sulfoxides, Sulfones and Thiosulfonates through Selectfluor-Promoted Oxidation with H2O as O-Source, Synthesis-Stuttgart 2022, 54, 1996-2004. (中科院SCI四区)

[13] Yulei Zhao*, Xuqiang Guo, Shuai Li, Yuhang Fan, Xuejun Sun, Laijin Tian, PhB(OH)2 Promoted Electrochemical Sulfuration-Formyloxylation of Styrenes and Selectfluor Mediated Oxidation-Olefination, Org. Lett. 2021, 23, 9140–9145. (中科院SCI一区)

[14] Yulei Zhao*, Xuqiang Guo, Ruihua Zhang, Shuai Li, Tingting Chen, Xuejun Sun*, CF3CO2H-Catalyzed Synthesis of 3-Alkynylpyrrole Derivatives and Their Controlled Reduction, J. Org. Chem. 2021, 86, 15568-15576. (中科院SCI二区, TOP期刊)

[15] Yulei Zhao*, Shuai Li, Yuhang Fan, Xuqiang Guo, Xin Jiao, Laijin Tian, Xuejun Sun*, Synthesis of 10H-indolo[1,2-a]indole Derivatives via Intramolecular Cycloaddition and H-Migration, Eur. J. Org. Chem. 2021, 4358–4363. (中科院SCI三区)

[16] Xiao-Yuan Cui, Yu-Lei Zhao, Yan-Mei Chen, Su-Zhen Dong*, Feng Zhou, Hai-Hong Wu*, Jian Zhou*, Au-Catalyzed Formal Allylation of Diazo(thio)oxindoles: Application to Tandem Asymmetric Synthesis of Quaternary Stereocenters, Org. Lett. 2021, 23, 4864–4869. (中科院SCI一区)

[17] Duyi Shen*, Hongyan Wang, Yanan Zheng, Xinjing Zhu, Peiwei Gong, Bin Wang, Jinmao You, Yulei Zhao*, Mianran Chao*, Catalyst-Free and Transition-Metal-Free Approach to 1,2-Diketones via Aerobic Alkyne Oxidation, J. Org. Chem. 2021, 86, 5354-5361. (中科院SCI二区, TOP期刊)

[18] Yulei Zhao*, Xuqiang Guo, Xin Ding, Zheng Zhou, Man Li, Nan Feng, Bowen Gao, Xu Lu, Yunlin Liu, Jinmao You, Reductive CO2 Fixation via the Selective Formation of C−C Bonds: Bridging Enaminones and Synthesis of 1,4-Dihydropyridines, Org. Lett. 2020, 22, 8326−8331. (中科院SCI一区)

[19] Yulei Zhao*, Xuqiang Guo, Zhiyao Si, Yanan Hu, Ying Sun, Yunlin Liu, Zhongyin Ji, Jinmao You*, Hydrosilane-Assisted Synthesis of Urea Derivatives from CO2 and Amines, J. Org. Chem. 2020, 85, 13347−13353. (中科院SCI二区, TOP期刊)

[20] Yulei Zhao*, Xu Liu, Lijun Zheng, Yulan Du, Xinrui Shi, Yunlin Liu, Zhengquan Yan*, Jinmao You*, Yuanye Jiang*, One-Pot Methylenation−Cyclization Employing Two Molecules of CO2 with Arylamines and Enaminones, J. Org. Chem. 2020, 85, 912-923. (中科院SCI二区, TOP期刊)

[21] Yulei Zhao*, Xuqiang Guo, Yulan Du, Xinrui Shi, Shina Yan, Yunlin Liu, Jinmao You*, Synthesis of fused-tetrahydropyrimidines: one-pot methylenation-cyclization utilizing two molecules of CO2, Org. Biomol. Chem. 2020, 18, 6881–6888. (中科院SCI三区)

[22] Yuanyang Mu, Yang Yuan, Ye Wang, Murong Xu, Ye Feng, Yulei Zhao*, Yanzhong Li*, Synthesis of indoline-fused eight-membered azaheterocycles through Zn-catalyzed dearomatization of indoles and subsequent base-promoted C-C activation, Org. Biomol. Chem. 2020, 18, 6916–6926. (中科院SCI三区)

[23] Yulei Zhao*, Xuqiang Guo, Zongkang Wang, Duyi Shen*, Tingting Chen, Nan Wu, Shina Yan, Jinmao You, TBAF-Catalyzed Cyclization Reactions of o-(Alkynyl)phenyl Propargyl Alcohols with Malonate Esters: A Possible Cation–π Interaction as The Activation Approach, Eur. J. Org. Chem. 2020, 978–984. (中科院SCI三区)

[24] Yulei Zhao*, Zheng Zhang, Xu Liu, Zongkang Wang, Ziping Cao, Laijin Tian, Mingbo Yue, Jinmao You*, TBAF-Catalyzed ONucleophilic Cyclization of Enaminones: A Process for the Synthesis of Dihydroisobenzofuran Derivatives, J. Org. Chem. 2019, 84, 1379−1386. (中科院SCI二区, TOP期刊)

[25] Shu-Jie Chen, Guo-Shu Chen, Jia-Wei Zhang, Zhao-Dong Li, Yu-Lei Zhao, Yun-Lin Liu*, Phosphine-catalyzed [3+2] cycloadditions of trifluoromethyl enynes/enediynes with allenoates: access to cyclopentenes containing a CF3-substituted quaternary carbon center, Org. Chem. Front. 2020, 7, 3399-3405. (中科院SCI一区)

[26] Jian Luo, Guo-Shu Chen*, Shu-Jie Chen, Zhao-Dong Li, Yu-Lei Zhao, Yun-Lin Liu*, One-Pot Tandem Protocol for the Synthesis of 1,3-Bis(βaminoacrylate)-Substituted 2-Mercaptoimidazole Scaffolds, Adv. Synth. Catal. 2020, 362, 3635– 3643. (中科院SCI二区, TOP期刊)

[27] Jian Luo, Yu-Bo Fang, Xiang-Yu Mao, Meng Yang, Yu-Lei Zhao, YunLin Liu*, Guo-Shu Chen*, Yong-Fei Ji*, Organocatalytic Asymmetric Cyclization Reaction of 2-Alkynyl3,3-Difluoro-3H-Indoles and 2-Mercaptoimidazoles: Access to gem-Difluorinated C2-Spiro Indolines, Adv. Synth. Catal. 2019, 361, 1408-1413. (中科院SCI二区, TOP期刊)

[28] Zhengquan Yan*, Hua Yuan, Qi Zhao, Lin Xing, Xiaoyu Zheng, Weiguo Wang, Yulei Zhao, Yang Yu, Lei Hu* Wenli Yao, Recent developments of nanoenzyme-based colorimetric sensors for heavy metal detection and the interaction mechanism, Analyst 2020, 145, 3173-3187. (中科院SCI二区)

[29] Ling Zhu, Ling-Jun Liu, Yuan-Ye Jiang*, Peng Liu, Xia Fan, Qi Zhang, Yulei Zhao, Siwei Bi*, Mechanism and Origin of Ligand-Controlled Chemo- and Regioselectivities in Palladium-Catalyzed Methoxycarbonylation of Alkynes, J. Org. Chem. 2020, 85, 7136-7151. (中科院SCI二区, TOP期刊)

独立工作后的教学类论文

[30] 颜世娜,孙敏,许丽荣,孙学军,赵育磊*,师范院校有机化学实验教学改革探讨,《科技视界》,2022,第25期,100-112.

独立工作前部分研究论文

[31] Yulei Zhao, Murong Xu, Zhong Zheng, Yang Yuan, Yanzhong Li*, Tertiary amine self-catalyzed intramolecular Csp3-H functionalization with in situ generated allenes for the formation of 3-alkenyl indolines, Chem. Commun. 2017, 53, 3721-3724. (中科院SCI一区)

[32] Yu-Lei Zhao, Zhong-Yan Cao, Xing-Ping Zeng, Jia-Meng Shi, Yi-Hua Yu, Jian Zhou*, Asymmetric sequential Au(I)/chiral tertiary amine catalysis: an enone-formation/cyanosilylation sequence to synthesize optically active 3-alkenyloxindoles from diazooxindoles, Chem. Commun. 2016, 52, 3943-3946. (中科院SCI一区)

[33] Zhong-Yan Cao#, Yu-Lei Zhao#, Jian Zhou*, Sequential Au(I)/chiral tertiary amine catalysis: a tandem C–H functionalization of anisoles or a thiophene/asymmetric Michael addition sequence to quaternary oxindoles, Chem. Commun. 2016, 52, 2537-2540. (中科院SCI一区)

[34] Yulei Zhao, Yang Yuan, Xiaoyu Wang, Yanzhong Li*, Synthesis of Polycyclic Benzo[b]indolo[3,2,1-de]acridines via Sequential Allenylation, Diels−Alder Cyclization, and Hydrogen Migration Reaction, J. Org. Chem. 2017, 82, 11198-11205. (中科院SCI二区, TOP期刊)

[35] Yulei Zhao, Yang Yuan, Murong Xu, Zhong Zheng, Runhua Zhang, Yanzhong Li*, Selective synthesis of pyrrolo[1,2-a]azepines or 4,6-dicarbonyl indoles via tandem reactions of alkynones with pyrrole derivatives, Org. Biomol. Chem. 2017, 15, 6328-6332. (中科院SCI二区)

[36] Yulei Zhao, Yang Yuan, Lingkai Kong, Fangfang Zhang, Yanzhong Li*, Synthesis of 1-Alkyl-3-(2-oxo-2-aryl/alkyl-ethyl)indolin-2-ones through Gold/Brønsted Acid Relay Actions: Observation of Selective C=C Bond Cleavage of Enaminones, Synthesis-Stuttgart 2017, 49, 3609-3618. (中科院SCI三区)

[37] Yulei Zhao, Qizhao Duan, Yuanyuan Zhou, Qiyi Yao, Yanzhong Li*, Gold-catalyzed chemo- and diastereoselective C(sp2)–H functionalization of enaminones for the synthesis of pyrrolo[3,4-c]-quinolin-1-one derivatives, Org. Biomol. Chem. 2016, 14, 2177-2181. (中科院SCI二区)

[38] Yulei Zhao, Fangfang Zhang, Wenjun Yao, Chengyu Wang, Yuanyuan Liu*, Yanzhong Li*, Base-Promoted Approach to Highly Functionalized Conjugated Dienes through Enamine Migration, Eur. J. Org. Chem. 2015, 7984-7991. (中科院SCI三区)

[39] Yun-Lin Liu, Xin Wang, Yu-Lei Zhao, Feng Zhu, Xing-Ping Zeng, Long Chen, Cui-Hong Wang, Xiao-Li Zhao, Jian Zhou*, One-Pot Tandem Approach to Spirocyclic Oxindoles Featuring Adjacent Spiro-Stereocenters, Angew. Chem. Int. Ed. 2013, 52, 13735-13739. (中科院SCI一区)

[40] Wei-Ming Gao, Jin-Sheng Yu, Yu-Lei Zhao, Yun-Lin Liu, Feng Zhou, Hai-Hong Wu*, Jian Zhou*, Highly enantioselective Michael addition of 3-arylthio- and 3-alkylthiooxindoles to nitroolefins catalyzed by a simple cinchona alkaloid derived phosphoramide, Chem. Commun. 2014, 50, 15179-15182. (中科院SCI一区)

[41] Fangfang Zhang, Zhengchen Qin, Lingkai Kong, Yulei Zhao, Yuanyuan Liu, Yanzhong Li*, Metal/Benzoyl Peroxide (BPO)-Controlled Chemoselective Cycloisomerization of (oAlkynyl)phenyl Enaminones: Synthesis of αNaphthylamines and Indeno[1,2c]pyrrolones, Org. Lett. 2016, 18, 5150-5153. (中科院SCI一区)

[42] Yuanyuan Zhou, Xianghua Tao, Qiyi Yao, Yulei Zhao, Yanzhong Li*, Insertion of Isolated Alkynes into Carbon–Carbon s-Bonds of Unstrained Cyclic b-Ketoesters via Transition-Metal-Free Tandem Reactions: Synthesis of Medium-Sized Ring Compounds, Chem. Eur. J. 2016, 22, 17936-17939. (中科院SCI二区)

 

独立工作后代表性专利

【1】    赵育磊,刘旭,郑丽君,郭旭强,杜钰兰,师欣蕊,万竹婷,陈婷婷,丁鑫,周政,一种四氢嘧啶类衍生物的合成方法,专利号:ZL201910657604.6,授权号:CN110218190B,申请日:2019.07.20,授权日:2021.02.12

【2】    赵育磊,王宗康,郭旭强,陈婷婷,张瑞华,冯楠,吕梦,胡雅楠,孙莹,董永平,何梦瑶,刘振翠,一种异苯并呋喃双酯类衍生物及其合成方法,专利号:ZL201910882550.3,授权号:CN110669030B,申请日:2019.09.18,授权日:2021.05.18

【3】    赵育磊,司志姚,郭旭强,胡雅楠,孙莹,董永平,高博文,卢旭,武博翰,成倩倩,臧青,一种脲类衍生物及其合成方法,专利号:ZL201911069763.0,授权号:CN110683969B,申请日:2019.11.05,授权日:2022.05.17

【4】    赵育磊,张正,王宗康,司志姚,傅德斌,刘旭,郑丽君,李曼,李慧婷,孟占乾,刘璐,李瑞,吴楠,一种1,3-二氢异苯并呋喃衍生物及其合成方法和应用,专利号:ZL201810991246.8,授权号:CN108947945B,申请日:2018.08.28,授权日:2022.08.02

【5】    赵育磊,李曼,丁鑫,周政,冯楠,卢旭,高博文,郭旭强,杜钰兰,师欣蕊,陈婷婷,一种1,4-二氢吡啶类衍生物及其合成方法,专利号 ZL201911334044.7,授权号:CN110981790B,申请日:2019.12.23,授权日:2022.10.14

【6】    赵育磊,李帅,蒋蒙蒙,王慧敏,康欣,苏琦,崔金洁,焦鑫,孟晓含,纪淑欣,秦誉真,唐堉森,一种稠环3,3’-联吲哚衍生物及其合成方法,申请号:202210090490.3,申请日:2022.01.25

【7】    赵育磊,王慧敏,康欣,冯楠,张瑞华,苏琦,陈丽荟,陈文静,一种四氢嘧啶类衍生物及其制备方法,申请号:202210873953.3,申请日:2022.07.21