30. Enantioselective Cobalt-Catalyzed Hydroboration of Ketone-Derived Silyl Enol Ethers

Wenke Dong, Zhiyang Ye, and Wanxiang Zhao*, Angew. Chem. Int. Ed. 2022, 61, just accepted

29. Bing Zhang,^§ Xueying Guo,^§ Lei Tao, Ruolin Li, Zhenyang Lin,* and Wanxiang Zhao*, Rhodium-Catalyzed Regioselective and Chemoselective Deoxygenative Reduction of 1,3-Diketones, ACS Catal. 2022, 12, 4640-4647.

28. Kezhuo Zhang, Jiaxin Huang, and Wanxiang Zhao*, Rh-Catalyzed Coupling of Aldehydes with Allylboronates Enables Facile Access to Ketones, Chem. Eur. J. 2022, 28, e202103851, DOI: 10.1002/chem.202103851.

27. Pei Zhao,^‡ Jiaxin Huang,^‡ Jie Li, Kezhuo Zhang, Wen Yang,* and Wanxiang Zhao*, Ligand-controlled cobalt-catalyzed remote hydroboration and alkene isomerization of allylic siloxanes, Chem. Commun. 2022, 58, 302-305.

26. Jie Li, Pei Zhao, Ruoling Li, Wen Yang,* and Wanxiang Zhao*, Rhodium-Catalyzed β‑Dehydroborylation of Silyl Enol Ethers: Access to Highly Functionalized Enolates, Org. Lett. 2021, 23, 9580-9585.

25. Chenchen Li,^‡ Kezhuo Zhang,^‡ Minghao Zhang, Wu Zhang, and Wanxiang Zhao*, Phosphination of Phenol Derivatives and Applications to Divergent Synthesis of Phosphine Ligands, Org. Lett. 2021, 23, 8766-8771.

24. Yaqin Lei, Jiaxin Huang, and Wanxiang Zhao*, Cobalt-Catalyzed Remote Hydroboration of Alkenyl Amines, Org. Lett. 2021, 23, 7797-7802.

23. Lei Tao, Wen Yang,* and Wanxiang Zhao*, Synthesis of Carboxylic Acids, Esters, and Amides from 1,1-Dibromoalkenes via Oxidation of Alkynyl Boronate Intermediates, ChemistrySelect 2021, 6, 8532-8536.

22. Wenjing Pan, Chenchen Li, Haoyin Zhu, Fangfang Li,* Tao Li,* and Wanxiang Zhao*, A mild and practical method for deprotection of aryl methyl/benzyl/allyl ethers with HPPh₂ and ^tBuOK, Org. Biomol. Chem. 2021, 19, 7633-7640.

21. Wenke Dong,^# Xin Xu,^# Honghui Ma, Yaqin Lei, Zhenyang Lin, and Wanxiang Zhao*, Enantioselective Rh-Catalyzed Hydroboration of Silyl Enol Ethers, J. Am. Chem. Soc. 2021, 143, 10902-10909.

20. Bing Zhang,^§ Xin Xu,^§ Lei Tao, Zhenyang Lin,* and Wanxiang Zhao*, Rhodium-Catalyzed Regiodivergent Synthesis of Alkylboronates via Deoxygenative Hydroboration of Aryl Ketones: Mechanism and Origin of Selectivities, ACS Catal. 2021, 11, 9495-9505.

19. Zhaoyue Liu, Zhonghui Zhang, Tao Li,* and Wanxiang Zhao*, Three-Dimensional Diradical Metallacage with an Open-Shell Ground State, Organometallics 2021, 40, 2379-2383.

18. Minghao Zhang and Wanxiang Zhao*, Stereodefined tetraarylethylenes: Synthesis and applications, Aggregate. 2021;2:e60.

17. Ruoling Li, Chenchen Li, Wen Yang,* and Wanxiang Zhao*, Homogeneous Palladium-Catalyzed Selective Reduction of 2,2′-Biphenols Using HCO₂H as Hydrogen Source, Synthesis 2021, 53, 1605-1618.

16. Lei Tao,^∇ Xueying Guo,^∇ Jie Li, Ruoling Li, Zhenyang Lin,* and Wanxiang Zhao*, Rhodium-Catalyzed Deoxygenation and Borylation of Ketones: A Combined Experimental and Theoretical Investigation, J. Am. Chem. Soc. 2020, 142, 18118-18127.

15. Tao Li,^§ Qiao Zhang,^§ Doudou Li, Shengyi Dong,* Wanxiang Zhao,* and Peter J. Stang* , Rational Design and Bulk Synthesis of Water-Containing Supramolecular Polymers, ACS Appl. Mater. Interfaces 2020, 12, 38700-38707.

14. Minghao Zhang, Yisen Yao, Peter J. Stang* and Wanxiang Zhao*, Divergent and Stereoselective Synthesis of Tetraarylethylenes from Vinylboronates, Angew. Chem. Int. Ed. 2020, 59, 20090-20098.

13. Wu Zhang, Wen Yang,* and Wanxiang Zhao*, Lewis Acid Mediated Electrophilic Cyanation of 2,2′-Biphenols, J. Org. Chem. 2020, 85, 8702-8713.

12. Wu Zhang, Wen Yang,* and Wanxiang Zhao*, Lewis acid-promoted site-selective cyanation of phenols, Org. Biomol. Chem. 2020, 18, 4604-4609.

11. Hongxuan Yang, Wenke Dong, Wencan Wang, Tao Li,* and Wanxiang Zhao*, Stereoselective Rhodium-Catalyzed Isomerization of Stereoisomeric Mixtures of Arylalkenes, Synthesis 2020, 52, 2833-2840.

10. Doudou Li, Qiao Zhang, Wanxiang Zhao, Shengyi Dong, Tao Li,* and Peter J. Stang*, Thermo/Anion Dual-Responsive Supramolecular Organoplatinum- Crown Ether Complex, Org. Lett. 2020, 22, 4289-4293.

9. Chenchen Li, Pei Zhao, Ruoling Li, Bing Zhang, and Wanxiang Zhao*, Oxidation of Alkynyl Boronates to Carboxylic Acids, Esters and Amides,  Angew. Chem. Int. Ed. 2020, 59, 10913-10917.

8. Wenke Dong,^† Hongxuan Yang,^† Wen Yang,* and Wanxiang Zhao*, Rhodium-Catalyzed Remote Isomerization of Alkenyl Alcohols to Ketones, Org. Lett. 2020, 22, 1265-1269.

7. Jie Li, Shuanglin Qu, and Wanxiang Zhao*, Rhodium‐Catalyzed Remote C(sp³)−H Borylation of Silyl Enol Ethers, Angew. Chem. Int. Ed. 2020, 59, 2360-2364.

6. Wu Zhang, Tao Li, Qingli Wang*, and Wanxiang Zhao*, Lewis Acid-Mediated Cyanation of Phenols Using N-Cyano-N-phenyl-p-toluenesulfonamide, Adv. Synth. Catal. 2019, 361, 4914-4918.

5. Qiao Zhang,^⊥ Tao Li,^⊥ Abing Duan,^⊥ Shengyi Dong,* Wanxiang Zhao,* and Peter J. Stang*, Formation of a Supramolecular Polymeric Adhesive via Water-Participant Hydrogen Bonding Formation, J. Am. Chem. Soc. 2019, 141, 8058-8063.

4. Shenhuan Li, Jie Li, Tianlai Xia, and Wanxiang Zhao*, Stereoselective Synthesis of Vinylboronates by Rh-Catalyzed Borylation of Stereoisomeric Mixtures, Chin. J. Chem. 2019, 37, 462-468. 

3. Wanxiang Zhao and Jianwei Sun*, Triflimide (HNTf₂) in Organic Synthesis, Chem. Rev. 2018, 118, 10349-10392.

2. Xia Wang, Yue Tang, Cheng-Yu Long, Wen-Ke Dong, Chenchen Li, Xinhua Xu, Wanxiang Zhao* and Xue-Qiang Wang*, Nucleophilic Amination and Etherification of Aryl Alkyl Thioethers, Org. Lett. 2018, 20, 4749−4753.

1. Xueqiang Wang*, Chenchen Li, Xia Wang, Qingli Wang, Xiu-Qin Dong, Abing Duan* and Wanxiang Zhao*, Metal-Free Etherification of Aryl Methyl Ether Derivatives by C−OMe Bond Cleavage, Org. Lett. 2018, 20, 4267-4247.

Before Hunan University

6. Wanxiang Zhao, John Montgomery*,  Cascade Copper-Catalyzed 1,2,3-Trifunctionalization of Terminal Allenes, J. Am. Chem. Soc. 2016, 138, 9763–9766.

5. Wanxiang Zhao, John Montgomery*, Functionalization of Styrenes by Copper‐Catalyzed Borylation/ ortho‐Cyanation and Silver‐Catalyzed Annulation Processes, Angew. Chem. Int. Ed. 2015, 54, 12683 –12686.

4. Wanxiang Zhao, Hui Qian, Zigang Li,* and Jianwei Sun*, Catalytic Ring Expansion of Cyclic Hemiaminals for the Synthesis of Medium‐Ring Lactams, Angew. Chem. Int. Ed. 2015, 54, 10005 –10008.

3. Wanxiang Zhao, Zhaobin Wang, Boyang Chu, and Jianwei Sun*, Enantioselective Formation of All‐Carbon Quaternary Stereocenters from Indoles and Tertiary Alcohols Bearing A Directing Group, Angew. Chem. Int. Ed. 2015, 54, 1910 –1913.

2. Wanxiang Zhao, Zigang Li*, Jianwei Sun*, A New Strategy for Efficient Synthesis of Medium and Large Ring Lactones without High Dilution or Slow Addition, J. Am. Chem. Soc. 2013, 135,4680–4683.

1. Wanxiang Zhao, Zhaobin Wang, and Jianwei Sun*, Synthesis of Eight‐Membered Lactones: Intermolecular [6+2] Cyclization of Amphoteric Molecules with Siloxy Alkynes, Angew. Chem. Int. Ed. 2012, 51, 6209 –6213.